Skip to main content

Advertisement

Log in

Irradiation-induced defect clustering and amorphization in silicon carbide

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Previous computer simulations of multiple 10 keV Si cascades in 3C-SiC demonstrated that many damage-state properties exhibit relatively smooth, but noticeably different, dose dependencies. A more recent analysis of these damage-state properties, which includes additional data at low and intermediate doses, reveals more complex relationships between system energy, swelling, energy per defect, relative disorder, elastic modulus, and elastic constant, C11. These relationships provide evidence for the onset of both defect clustering and solid-state amorphization, which appear to be driven by local energy and elastic instabilities from the accumulation of defects. The results provide guidance on experimental approaches to reveal the onset of these processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C.R. Eddy, Jr. and D.K. Gaskill: Silicon carbide as a platform for power electronics. Science 324, 1398 (2009).

    CAS  Google Scholar 

  2. J.J. Sumakeris, J.R. Jenny, and A.R. Powell: Bulk crystal growth, epitaxy, and defect reduction in silicon carbide materials for microwave and power devices. MRS Bull. 30, 280 (2005).

    CAS  Google Scholar 

  3. R.H. Jones, L. Giancarli, A. Hasegawa, Y. Katoh, A. Kohyama, B. Riccardi, L.L. Snead, and W.J. Weber: Promise and challenges of SiCf/SiC composites for fusion energy applications. J. Nucl. Mater. 307-311, 1057 (2002).

    CAS  Google Scholar 

  4. L.L. Snead, T. Nozawa, Y. Katoh, T-S. Byun, S. Kondo, and D.A. Petti: Handbook of SiC properties for fuel performance modeling. J. Nucl. Mater. 371, 329 (2007).

    CAS  Google Scholar 

  5. H. Inui, H. Mori, and H. Fujita: Electron-irradiation-induced crystalline to amorphous transition in a-SiC single crystals. Philos. Mac. B 61, 107 (1990).

    CAS  Google Scholar 

  6. H. Inui, H. Mori, T. Sakata, and H. Fujita: Electron-irradiation-induced crystalline-to-amorphous transition in ß-SiC single crystals. Philos. Mag. B 65, 1 (1992).

    CAS  Google Scholar 

  7. E. Wendler, A. Heft, and W. Wesch: Ion-beam induced damage and annealing behaviour in SiC. Nucl. lustrum. Methods Phys. Res., Sect. B 141, 105 (1998).

    CAS  Google Scholar 

  8. Y. Zhang, F. Gao, W. Jiang, D.E. McCready, and W.J. Weber: Damage accumulation and defect relaxation in 4H-SiC. Phys. Rev. B 70, 125203 (2004).

    Google Scholar 

  9. W. Jiang, H. Wang, I. Kim, I-T. Bae, G. Li, P. Nachimuthu, Z. Zhu, Y. Zhang, and W.J. Weber: Response of nanocrystalline 3C silicon carbide to heavy-ion irradiation. Phys. Rev. B 80, 161301 (2009).

    Google Scholar 

  10. L.L. Snead and J.C. Hay: Neutron irradiation induced amorphization of silicon carbide. J. Nucl. Mater. 273, 213 (1999).

    CAS  Google Scholar 

  11. R. Devanathan, W.J. Weber, and F. Gao: Atomic scale simulation of defect production in irradiated 3C-SiC. J. Appl. Phys. 90, 2303 (2001).

    CAS  Google Scholar 

  12. D.E. Farrell, N. Bernstein, and W.K. Liu: Thermal Effects in 10 keV Si PKA cascades in 3C-SiC. J. Nucl. Mater. 385, 572 (2009).

    CAS  Google Scholar 

  13. N. Swaminathan, P.J. Kamenski, D. Morgan, and I. Szlufarska: Effects of grain size and grain boundaries on defect production in nanocrystalline 3C-SiC. Acta Mater. 58, 2843 (2010).

    CAS  Google Scholar 

  14. F. Gao, D. Chen, W. Hu, and W.J. Weber: Energy dissipation and defect generation in nanocrystalline silicon carbide. Phys. Rev. B 81, 184101 (2010).

    Google Scholar 

  15. L. Malerba and J.M. Perlado: Molecular dynamics simulation of irradiation-induced amorphization of cubic silicon carbide. J. Nucl. Mater. 289, 57 (2001).

    CAS  Google Scholar 

  16. W.J. Weber, L.M. Wang, N. Yu, and N.J. Hess: Structure and properties of ion-beam-modified (6H) silicon carbide. Mater. Sci. Em.. A 253, 62 (1998).

    Google Scholar 

  17. F. Gao and W.J. Weber: Atomic-scale simulations of multiple ion-solid interactions and structural evolution in silicon carbide. J. Mater. Res. 17, 259 (2002).

    CAS  Google Scholar 

  18. F. Gao and W.J. Weber: Cascade overlap and amorphization in 3C-SiC: Defect accumulation, topological features, and disorder. Phys. Rev. B 66, 024106 (2002).

    Google Scholar 

  19. F. Gao, W.J. Weber, and R. Devanathan: Defect production, multiple ion-solid interactions and amorphization in SiC. Nucl. lustrum. Methods Phys. Res., Sect. B 191, 487 (2002).

    CAS  Google Scholar 

  20. F. Gao and W.J. Weber: Atomic-scale simulations of cascade overlap and damage evolution in silicon carbide. J. Mater. Res. 18, 1877 (2003).

    CAS  Google Scholar 

  21. F. Gao and W.J. Weber: Mechanical properties and elastic constants due to damage accumulation and amorphization is SiC. Phys. Rev. B 69, 224108 (2004).

    Google Scholar 

  22. J-P. Crocombette, G. Dumazer, N.Q. Hoang, F. Gao, and W.J. Weber: Molecular dynamics modeling of the thermal conductivity of SiC as a function of cascade overlap. J. Appl. Phys. 101, 023527 (2007).

    Google Scholar 

  23. N.Q. Lam, P.R. Okamoto, and M. Li: Disorder-driven amorphization. J. Nucl. Mater. 251, 89 (1997).

    CAS  Google Scholar 

  24. R. Devanathan, W.J. Weber, and T. Diaz de la Rubia: Computer simulation of a 10 keV Si displacement cascade in SiC. Nucl. lustrum. Methods Phys. Res., Sect. B 141, 118 (1998).

    CAS  Google Scholar 

  25. F. Gao, E.J. Bylaska, W.J. Weber, and L.R. Corrales: Native defect properties in ß-SiC: Ab initio and empirical potential calculations. Nucl. lustrum. Methods Phys. Res., Sect. B 180, 286 (2001).

    CAS  Google Scholar 

  26. R. Devanathan and W.J. Weber: Displacement energy surface in 3C and 6H SiC. J. Nucl. Mater. 278, 258 (2000).

    CAS  Google Scholar 

  27. F. Gao and W.J. Weber: Atomic-scale simulation of 50 keV Si displacement cascades in P-SiC. Phys. Rev. B 63, 054101 (2000).

    Google Scholar 

  28. F. Gao, W.J. Weber, and W. Jiang: Primary damage states produced by Si and Au recoils in SiC: A molecular dynamics and experimental investigation. Phys. Rev. B 63, 214106 (2001).

    Google Scholar 

  29. R.W. Cahn and W.L. Johnson: Review: The nucleation of disorder. J. Mater. Res. 1, 724 (1986).

    CAS  Google Scholar 

  30. D. Wolf, P.R. Okomoto, S. Yip, J.F. Lutsko, and M. Kluge: Thermodynamic parallels between solid-state amorphization and melting. J. Mater. Res. 5, 286 (1990).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to William J. Weber.

Additional information

This author was an editor of this journal during the review and decision stage. For the JMR policy on review and publication of manuscripts authored by editors, please refer to http://www.mrs.org/jmr_policy

Rights and permissions

Reprints and permissions

About this article

Cite this article

Weber, W.J., Gao, F. Irradiation-induced defect clustering and amorphization in silicon carbide. Journal of Materials Research 25, 2349–2353 (2010). https://doi.org/10.1557/jmr.2010.0292

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2010.0292

Navigation