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Improved wettability of Sn-based solder over the Cu60Zr30Ti10 bulk metallic glass surface

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Abstract

The wettability of Pb-free Sn-based solder over the Cu-based Cu60Zr30Ti10 bulk metallic glass surface was investigated. We observed that the as-polished surface was nonwetting for the solder, which was due to the surface oxide layer of ZrOx formed in air. After complete removal of the oxide layer, a thin layer of Ag was deposited on the clean Cu60Zr30Ti10 surface. The Ag-covered Cu60Zr30Ti10 surface showed relatively high resistivity to the reoxidation even in air, and thus the wettability of the Cu60Zr30Ti10 surface for the Sn-based solder was greatly improved.

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References

  1. A. Inoue: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 297 (2000)

    Google Scholar 

  2. A. Inoue: Bulk amorphous and nanocrystalline alloys with high functional properties. Mater. Sci. Eng., A 304, 1 (2001)

    Article  Google Scholar 

  3. H.S. Chen: Glassy metals. Rep. Prog. Phys. 43, 353 (1980)

    Google Scholar 

  4. A. Inoue, W. Zhang, T. Zhang and K. Kurosaka: High-strength Cu-based bulk glassy alloys in Cu–Zr–Ti and Cu–Hf–Ti ternary systems. Acta Mater. 49, 2645 (2001)

    CAS  Google Scholar 

  5. J.P. Carini, S.R. Nagel, L.K. Varga and T. Schmidt: Electronic transport in amorphous Ni1–xPx alloys. Phys. Rev. B 27, 7589 (1983)

    CAS  Google Scholar 

  6. C.J. Gilbert, R.O. Ritchie and W.L. Johnson: Fracture toughness and fatigue-crack propagation in a Zr–Ti–Ni–Cu–Be bulk metallic glass. Appl. Phys. Lett. 71, 476 (1997)

    Article  CAS  Google Scholar 

  7. S.R. Nagel: Thermoelectric power and resistivity in a metallic glass. Phys. Rev. Lett. 41, 990 (1978)

    CAS  Google Scholar 

  8. H. Nishikawa, K.W. Piromsarn, H. Abe, T. Takemoto, M. Fukuhara, T. Wada and A. Inoue: Wetting characteristics of Sn–Ag–Cu solder on Pd-based metallic glass. Mater. Sci. Eng., B 148, 124 (2008)

    CAS  Google Scholar 

  9. Y. Matsumoto, T. Obata, M. Hiraoka and M. Katayama: Development of a variable temperature UHV-laser microscope combined with a pulsed laser deposition for in situ studies of ceramics/metallics glass interfaces. Ceram. Trans. 198, 15 (2007)

    CAS  Google Scholar 

  10. C.Y. Tam and C.H. Shek: Oxidation-induced copper segregation in Cu60Zr30Ti10 bulk metallic glass. J. Mater. Res. 21, 851 (2006)

    Article  CAS  Google Scholar 

  11. Y. Matsumoto, Y. Aibara, K. Mukai, K. Moriwaki, Y. Okawa, B.E. Neiuwenhuys and K. Tanaka: STM studies of oxygen-induced reconstruction on a Pt-Rh (100) alloy surface. Surf. Sci. 377, 32 (1997)

    Article  Google Scholar 

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Imai, A., Katayama, M., Maruyama, S. et al. Improved wettability of Sn-based solder over the Cu60Zr30Ti10 bulk metallic glass surface. Journal of Materials Research 24, 2931–2934 (2009). https://doi.org/10.1557/jmr.2009.0343

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  • DOI: https://doi.org/10.1557/jmr.2009.0343

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