Skip to main content
Log in

Nanostructure of the nanopores in anodic aluminum oxide films used as template to fabricate Ag nanowires

  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Well-ordered nanoporous anodic aluminum oxide (AAO) templates have been prepared on aluminum substrates by a two-step anodization process. A voltage-controlled branching method was successfully used to thin the barrier layer of the AAO template. The nanostructures of the pores, the branched subpores, and the barrier layer in the AAO template were studied in association with the anodization process and barrier layer thinning methods. Results demonstrate the voltage-controlled branching method is a facile and effective way to thin the barrier layer. Uniform silver nanowires can be easily fabricated using alternating current (ac) electrodeposition into the pores of AAO after redressing the barrier layer.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. Pacholski, A. Kornowski, and H. Weller: Self-assembly of ZnO: From nanodots to nanorods. Angew. Chem., Int. Ed. Engl. 41, 1188 (2002).

    Article  CAS  Google Scholar 

  2. B.R. Martin, D.J. Dermody, B.D. Reiss, M. Fang, L.A. Lyon, M.J. Natan, and T.E. Mallouk: Orthogonal self-assembly on colloidal gold-platinum nanorods. Adv. Mater. 11, 1021 (1999).

    Article  CAS  Google Scholar 

  3. R. Inguanta, S. Piazza, and C. Sunseri: Influence of electrodepo-sition techniques on Ni nanostructures. Electrochim. Acta 53, 5766 (2008).

    Article  CAS  Google Scholar 

  4. Y. Li, D. Xu, Q. Zhang, D. Chen, F. Huang, Y. Xu, G. Guo, and Z. Gu: Preparation of cadmium sulfide nanowire arrays in anodic aluminum oxide templates. Chem. Mater. 11 (12), 3433 (1999).

    Article  CAS  Google Scholar 

  5. J.T. Chen, M. Zhang, and T.P. Russell: Instabilities in nanoporous media. Nano Lett. 7 (1), 183 (2007).

    Article  CAS  Google Scholar 

  6. Z.H. Wen, Q. Wang, and J.H. Li: Template synthesis of aligned carbon nanotube arrays using glucose as a carbon source: Pt decoration of inner and outer nanotube surfaces for fuel-cell catalysts. Adv. Fund. Mater. 18, 959 (2008).

    Article  CAS  Google Scholar 

  7. L. Liu, W. Zhou, S. Xie, L. Song, S. Luo, D. Liu, J. Shen, Z. Zhang, Y. Xiang, W. Ma, Y. Ren, C. Wang, and G. Wang: Highly efficient direct electrodeposition of Co–Cu alloy nano-tubes in an anodic alumina template. J. Phys. Chern. C 112 (7), 2256 (2008).

    Article  CAS  Google Scholar 

  8. H. Masuda and K. Fukuda: Ordered metal nanohole arrays made by a two-step replication of honeycomb structures of anodic alumina. Science 268, 1466 (1995).

    Article  CAS  Google Scholar 

  9. A.P. Li, F. Muller, A. Birner, K. Nielsch, and U. Gosele: Self-organized formation of hexagonal pore arrays in anodic alumina. J. Appl. Phys. 84, 6023 (1998).

    Article  CAS  Google Scholar 

  10. W. Lee, M. Alexe, K. Nielsch, and U. Gosele: Metal membranes with hierarchically organized nanotube arrays. Chern. Mater. 17 (3), 3325 (2005).

    Article  CAS  Google Scholar 

  11. H. Chik and J.M. Xu: Nanometric superlattices: Non-lithographic fabrication, materials, and prospects. Mater. Sci. Eng., R 43, 103 (2004).

    Article  Google Scholar 

  12. J.P. O’Sullivan and G.C. Wood: The motphology and mechanism of formation of porous anodic films on aluminium. Proc. R. Soc. London, Ser. A 317, 511 (1970).

    Article  Google Scholar 

  13. F. Keller, M.S. Hunter, and D.L. Robinson: Structural features of anodic oxide films on aluminum. J. Electrochem. Soc. 100, 411 (1953).

    Article  CAS  Google Scholar 

  14. G.W. Meng, A.Y. Cao, J.Y. Cheng, A. Vijayaraghavan, Y.J. Jung, M. Shima, and P.M. Ajayan: Ordered Ni nanowire tip arrays sticking out of the anodic aluminum oxide template. J. Appl. Phys. 97, 064303 (2005).

    Article  Google Scholar 

  15. J.H. Jeong, S.H. Kim, Y. Choi, and S.S. Kim: Microstructure of nanopores in AAO templates favoring the growth of nickel nano-wires by electrodeposition. Phys. Status Solidi C 4 (12), 4429 (2007).

    Article  CAS  Google Scholar 

  16. A.Y.Y. Ho, H. Gao, Y.C. Lam, and I. Rodriguez: Controlled fabrication of multitiered three-dimensional nanostructures in porous alumina. Adv. Funct. Mater. 18, 2057 (2008).

    Article  CAS  Google Scholar 

  17. O. Jessensky, F. Müller, and U. Gösele: Self-organized formation of hexagonal pore arrays in anodic alumina. Appl. Phys. Lett. 72 (10), 1173 (1998).

    Article  CAS  Google Scholar 

  18. G.A. Gelves, Z.T.M. Murakami, M.J. Krantz, and J.A. Haber: Multigram synthesis of copper nanowires using ac electrodeposition into porous aluminium oxide templates. J. Mater. Chem. 16, 3075 (2006).

    Article  CAS  Google Scholar 

  19. H.H. Wang, C.Y. Han, G.A. Willing, and Z.L. Xiao: Nanowire and nanotube syntheses through self-assembled nanoporous AAO templates, in Self-Assembled Nanostructured Materials, edited by Y. Lu, J. Brinker, M. Antonietti, and C. Ba (Mater. Res. Soc. Symp. Proc. 775, Warrendale, PA, 2003), P4.8, pp. 481–486.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to David L. Carroll.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, J., Kielbasa, J.E. & Carroll, D.L. Nanostructure of the nanopores in anodic aluminum oxide films used as template to fabricate Ag nanowires. Journal of Materials Research 24, 1735–1740 (2009). https://doi.org/10.1557/jmr.2009.0206

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2009.0206

Navigation