Abstract
We have investigated the compression stress–strain behaviors of Ti40Zr25Cu12Ni3Be20 bulk metallic glasses prepared by Cu mold casting from various melt temperatures. Plastic strain was found to vary sensitively on the temperature of melts and subsequent annealing conditions. To understand the origin of the plasticity change, the microstructures were characterized using transmission electron microscopy and a laser-assisted three-dimensional atom probe. The fully amorphous sample cast from 1273 K showed 0.6% plastic strain, and it was enhanced to 1.3% after isothermal annealing at 573 K. The sample cast from 1423 K showed 3.0% plastic strain, from which the presence of nanocrystals with a volume fraction of about 12% was confirmed. The sample cast from a higher temperature (1573 K) contained a larger fraction of crystals, which showed limited plastic strain. The effect of the volume fraction of the nanocrystals on the plasticity of bulk metallic glasses is discussed based on the experimental results.
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References
A. Inoue: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 (2000).
C.C. Hays, C.P. Kim, and W.L. Johnson: Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys. Rev. Lett. 84, 2901 (2000).
A. Inoue, W. Zhang, T. Zhang, and K. Kurosaka: High-strength Cu-based bulk glassy alloys in Cu–Zr–Ti and Cu–Hf–Ti ternary systems. Acta Mater. 49, 2645 (2001).
J.Z. Jiang, J. Saida, H. Kato, T. Ohsuna, and A. Inoue: Is Cu60Ti10Zr30 a bulk glass-forming alloy? Appl. Phys. Lett. 82, 4041 (2003).
A. Inoue, W. Zhang, and J. Saida: Synthesis and fundamental properties of Cu-based bulk glassy alloys in binary and multi-component systems. Mater. Trans. 45, 1153 (2004).
D. Nagahama, T. Ohkubo, T. Mukai, and K. Hono: Characterization of nanocrystal dispersed Cu60Zr30Ti10 metallic glass. Mater. Trans. 46, 1264 (2005).
M. Calin, J. Eckert, and L. Schultz: Improved mechanical behavior of Cu–Ti-based bulk metallic glass by in situ formation of nanoscale precipitates. Scripta Mater. 48, 653 (2003).
A. Inoue, T. Zhang, J. Saida, M. Matsushita, M.W. Chen, and T. Sakurai: High strength and good ductility of bulk quasicrystalline base alloys in Zr65Al7.5Ni10Cu17.5−xPdx system. Mater. Trans., JIM 40, 1137 (1999).
J.M. Park, H.J. Chang, K.H. Han, W.T. Kim, and D.H. Kim: Enhancement of plasticity in Ti-rich Ti–Zr–Be–Cu–Ni bulk metallic glasses. Scripta Mater. 53, 1 (2005).
A. Leonhard, L.Q. Xing, M. Heilmaier, A. Gebert, J. Eckert, and L. Schultz: Effect of crystalline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys. Nanostruct. Mater. 10, 805 (1998).
W.J. Wright, R.B. Schwarz, and W.D. Nix: Localized heating during serrated plastic flow in bulk metallic glasses. Mater. Sci. Eng., A 319–321, 229 (2001).
F. Guo, H.J. Wang, S.J. Poon, and G.J. Shiflet: Ductile titanium-based glassy alloy ingots. Appl. Phys. Lett. 86, 091907 (2005).
D. Blavette, B. Deconihout, A. Bostel, J.M. Sarrau, M. Bouet, and A. Menad: The tomographic atom probe: A quantitative three-dimensional nanoanalytical instrument on an atomic scale. Rev. Sci. Instrum. 64, 2911 (1993).
J.J. Lewandowski, W.H. Wang, and A.L. Greer: Intrinsic plasticity or brittleness of metallic glasses. Philos. Mag. Lett. 85, 77 (2005).
J. Schroers and W.L. Johnson: Ductile bulk metallic glass. Phys. Rev. Lett. 93, 255506 (2004).
R. Zallen: The Physics of Amorphous Solids (John Wiley & Sons, New York, 1983).
J. Basu, N. Nagendra, Y. Li, and U. Ramamurty: Microstructure and mechanical properties of a partially crystallized La-based bulk metallic glass. Philos. Mag. 83, 1747 (2003).
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Ohkubo, T., Nagahama, D., Mukai, T. et al. Stress–strain behaviors of Ti-based bulk metallic glass and their nanostructures. Journal of Materials Research 22, 1406–1413 (2007). https://doi.org/10.1557/jmr.2007.0180
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DOI: https://doi.org/10.1557/jmr.2007.0180