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Improved critical current densities in ex situ processed MgB2 tapes fabricated with chemically treated powder

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Abstract

Fe-sheathed MgB2 tapes were fabricated using powder chemically treated through an ex situ process employing a powder-in-tube (PIT) technique. The treatment of MgB2 powder in a benzene solution of benzoic acid caused the pulverization and disappearance of large grains. Compared with the pristine powder without treatment, the tape made from this powder showed a fivefold increase in critical current density (Jc) in 10 T. This was due to the pulverization of grains by the chemical treatment and the removal of surface MgO layers from MgB2 grains by dissolution in the acid solution. The removal of MgO layers was effective in promoting substitution of carbon from the solvent for boron.

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References

  1. J. Nagamatsu, N. Nakagawa, T. Muranaka, Y. Zenitani, and J. Akimitsu: Superconductivity at 39 K in magnesium diboride. Nature 410, 63 (2001).

    Article  CAS  Google Scholar 

  2. H. Fujii, K. Togano, and H. Kumakura: Enhancement of critical current densities of powder-in-tube processed MgB2 tapes by using MgH2 as a precursor powder. Supercond. Sci. Technol. 15, 1571 (2002).

    Article  CAS  Google Scholar 

  3. H. Fujii, K. Togano, and H. Kumakura: Fabrication of MgB2 tapes sheathed with carbon steels by ex situ and in situ methods. IEEE Trans. Appl. Supercond. 13, 3217 (2003).

    Article  CAS  Google Scholar 

  4. S. Jin, H. Mavoori, and R.B. van Dover: High critical currents in iron-clad superconducting MgB2 wires. Nature 411, 563 (2001).

    Article  CAS  Google Scholar 

  5. H.L. Suo, C. Beneduce, M. Dhallé, N. Musolino, J.Y. Genoud, and R. Flükiger: Large transport critical currents in dense Fe- and Ni-clad MgB2 superconducting tapes. Appl. Phys. Lett. 79, 3116 (2001).

    Article  CAS  Google Scholar 

  6. H. Fujii, H. Kumakura, and K. Togano: Improved critical current in MgB2 tapes sheathed with carbon steels. J. Mater. Res. 17, 2339 (2002).

    Article  CAS  Google Scholar 

  7. H. Fujii, H. Kumakura, and K. Togano: Influence of MgB2 powder quality on the transport properties of Cu-sheathed MgB2 tapes. Physica C 363, 237 (2001).

    Article  CAS  Google Scholar 

  8. T. Nakane, H. Kitaguchi, and H. Kumakura: Improvement in the critical current density of ex situ powder in tube processed MgB2 tapes by utilizing powder prepared from an in situ processed tape. Appl. Phys. Lett. 88, 022513 (2006).

    Article  Google Scholar 

  9. H. Fang, S. Padmanabhan, Y.X. Zhou, and K. Salama: High critical current density in iron-clad MgB2 tapes. Appl. Phys. Lett. 82, 4113 (2003).

    Article  CAS  Google Scholar 

  10. C. Fisher, C. Rodig, W. Hassler, O. Perner, J. Eckert, K. Nenkov, G. Fuchs, H. Wendrock, B. Holzapfel, and L. Schultz: Preparation of MgB2 tapes using a nanocrystalline partially reacted precursor. Appl. Phys. Lett. 83, 1803 (2003).

    Article  Google Scholar 

  11. T. Takenobu, T. Ito, D.H. Chi, K. Prassides, and Y. Iwasa: Intralayer carbon substitution in the MgB2 superconductor. Phys. Rev. B 64, 134513 (2001).

    Article  Google Scholar 

  12. A. Bharathi, S.J. Balaselvi, S. Kalavathi, G.L.N Reddy, V.S. Sastry, Y. Hariharan, and T.S. Radhakrishnan: Carbon solubility and superconductivity in MgB2. Physica C 370, 211 (2002).

    Article  CAS  Google Scholar 

  13. S. Lee, T. Masui, A. Yamamoto, H. Uchiyama, and S. Tajima: Carbon-substituted MgB2 single crystals. Physica C 397, 7 (2003).

    Article  CAS  Google Scholar 

  14. R.H.T Wilke, S.L. Bud’ko, P.C. Canfield, D.K. Finnemore, R.J. Suplinskas, and S.T. Hannahs: Systematic effects of carbon doping on the superconducting properties of Mg(B1-xCx)2. Phys. Rev. Lett. 92, 217003 (2004).

    Article  CAS  Google Scholar 

  15. S.X. Dou, S. Soltanian, J. Horvat, X.L. Wang, S.H. Zhou, M. Ionescu, H.K. Liu, P. Monroe, and M. Tomsic: Enhancements of the critical current density and flux pinning of MgB2 superconductor by nanoparticle SiC doping. Appl. Phys. Lett. 81, 3419 (2002).

    Article  CAS  Google Scholar 

  16. H. Yamada, M. Hirakawa, H. Kumakura, and H. Kitaguchi: Effect of aromatic hydrocarbon addition on in situ powder-in-tube processed MgB2 tapes. Supercond. Sci. Technol. 19, 175 (2006).

    Article  CAS  Google Scholar 

  17. P. Kováč, I. Hušek, T. Melišek, C.R.M Grovenor, S. Haigh, and H. Jones: Improvement of the current carrying capability of ex situ MgB2 wires by normal particle additions. Supercond. Sci. Technol. 17, 1225 (2004).

    Article  Google Scholar 

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Fujii, H., Togano, K. & Ozawa, K. Improved critical current densities in ex situ processed MgB2 tapes fabricated with chemically treated powder. Journal of Materials Research 22, 1281–1285 (2007). https://doi.org/10.1557/jmr.2007.0159

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  • DOI: https://doi.org/10.1557/jmr.2007.0159

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