Abstract
We review recent advances in the growth of Si1−xGex islands and Ge dots on (001) Si. We first discuss the evolution of the island morphology with Si1−xGex coverage and the effect of growth parameters or post-growth annealing on the shape of the islands and dots. We outline some of the structural and optical properties of Si1−xGex islands and assess progress in the determination of their composition and strain distribution. Finally, we discuss various approaches currently being investigated to engineer Si1−xGex quantum dots and in particular to control their size, density, and spatial distribution. For example, we show how C pre-deposition on Si (001) can influence the nucleation and growth of Ge islands.
Similar content being viewed by others
References
D.J. Eaglesham and M. Cerullo: Dislocation-free Stranski–Krastanow growth of Ge on Si(100). Phys. Rev. Lett. 64 1943 (1990).
Y.W. Mo D.E. Savage B.S. Swartzentruber and M.G. Lagally: Kinetic pathway in Stranski–Krastanov growth of Ge on Si(001). Phys. Rev. Lett. 65 1020 (1990).
R.J. Asaro and W.A. Tiller: Interface morphology development during stress-corrosion cracking I. Via surface diffusion. Metall. Trans. A 3 1789 (1972).
M.A. Grinfeld: Instability of the separation boundary between a non-hydrostatically stressed elastic body and a melt. Dokl. Akad. Nauk SSSR. 290 1358 (1986).
B. Teichert: Self-organization of nanostructures in semiconductor heteroepitaxy. Phys. Rep. 365 335 (2002).
Z. Zhang and M.G. Lagally: Morphological organization in epitaxial growth and removal in Series on Directions in Condensed Matter Physics Vol. 14 edited by Z. Zhang and M.G. Lagally (World Scientific Singapore 1998) p. 498.
K. Brunner: Si/Ge nanostructures. Rep. Prog. Phys. 65 27 (2002).
J.M. Baribeau N.L. Rowell and D.J. Lockwood: Self-assembled Si1-xGex dots and islands in Self-Organized Nanoscale Materials edited by M. Adachi and D.J. Lockwood (Kluwer/Plenum New York 2005) p. 1.
A. Stangl Holý V. and G. Bauer: Structural properties of self-organized semiconductor nanostructures. Rev. Mod. Phys. 76 725 (2004).
J. Drucker and S. Chapparo: Diffusional narrowing of Ge on Si(100) coherent island quantum dot size distributions. Appl. Phys. Lett. 71 614 (1997).
X.Z. Liao J. Zou D.J.H. Cockayne Z.M. Jiang and X. Wang: Extracting composition and alloying information of coherent Ge(Si)/Si(001) islands from [001] on-zone bright-field diffraction contrast images. J. Appl. Phys. 90 2725 (2001).
X.Z. Liao J. Zou D.J.H. Cockayne J. Wan Z.M. Jiang G. Jin and K.L. Wang: Annealing effects on the microstructure of Ge/Si(001) quantum dots. Appl. Phys. Lett. 79 1258 (2001).
B. Cho T. Schwarz-Selinger K. Ohmori D.G. Cahill and J.E. Greene: Effect of growth rate on the spatial distributions of dome-shaped Ge islands on Si(001). Phys. Rev. B 66 195407 (2002).
M.M. Rzaev T.M. Burbaev V.A. Kurbatov N.N. Melnik M. Muhlberger A.O. Pogosov F. Schäffler N.N. Sibeldin V.A. Tsvetkov P. Werner N.D. Zakharov and T.N. Zavaritskaya: Photoluminescence of self-assembled Ge islands grown by Si MBE at low temperatures. Phys. Status Solidi 4 1262 (2003).
F. Boscherini G. Capellini Di L. Gaspare De M. Seta F. Rosei A. Sgarlata N. Motta and S. Mobilio: Ge–Si intermixing in Ge quantum dots on Si. Thin Solid Films 380 173 (2000).
D. Dentel L. Vescan O. Chrétien and B. Holländer: Influence of molecular hydrogen on Ge island nucleation on Si(001). J. Appl. Phys. 88 5113 (2000).
T.I. Kamins E.C. Carr R.S. Williams and S.J. Rosner: Deposition of three-dimensional Ge islands on Si(001) by chemical vapor deposition at atmospheric and reduced pressures. J. Appl. Phys. 81 211 (1997).
M.D. Seta G. Capellini F. Evangelisti and C. Spinella: Intermixing-promoted scaling of Ge/Si(100) island sizes. J. Appl. Phys. 92 614 (2002).
W.T. Huang N. Deng P.Y. Chen G.L. Luo and P.X. Qian: Self-organized growth of Ge quantum dots by UHV-CVD. Microelectron. Technol. 41 17 (2004).
S.W. Lee L.J. Chen P.S. Chen M.J. Tsai C.W. Liu T.Y. Chien and C.T. Chia: Self-assembled nanorings in Si-capped Ge quantum dots on (001). Appl. Phys. Lett. 83 283 (2003).
A. Rastelli M. Kummer and H. Känel v.: Reversible shape evolution of Ge islands on Si(001). Phys. Rev. Lett. 87 256101 (2001).
A. Vailionis B. Cho G. Glass P. Desjardins D.G. Cahill and J.E. Greene: Pathway for the strain-driven two-dimensional to three-dimensional transition during growth of Ge on Si(001). Phys. Rev. Lett. 85 3672 (2000).
C.P. Liu J.M. Gibson D.G. Cahill T.I. Kamins D.P. Basile and R.S. Williams: Strain evolution in coherent Ge/Si islands. Phys. Rev. Lett. 84 1958 (2000).
F.M. Ross R.M. Tromp and M.C. Reuter: Transition states between pyramids and domes during Ge/Si island growth. Science 286 1931 (1999).
Medeiros-G. Ribeiro M. Bratkovski T.I. Kamins D.A.A. Ohlberg and R.S. Williams: Shape transition of germanium nanocrystals on silicon (001) surface from pyramids to domes. Science 279 353 (1998).
R.E. Rudd G.A.D. Briggs A.P. Sutton Medeiros-G. Ribeiro and R.S. Williams: Equilibrium model of bimodal distributions of epitaxial island growth. Phys. Rev. Lett. 90 146101 (2003).
J. Tersoff and F.K. LeGoues: Competing relaxation mechanisms in strained layers. Phys. Rev. Lett. 72 3570 (1994).
Y.W. Zhang and A.F. Bower: Three-dimensional analysis of shape transitions in strained-heteroepitaxial islands. Appl. Phys. Lett. 78 2706 (2001).
V.A. Shchukin N.N. Ledentsov Kop’P.S. ev and D. Bimberg: Spontaneous ordering of arrays of coherent strained islands. Phys. Rev. Lett. 75 2968 (1995).
O.E. Shklyaev M.J. Beck M. Asta M.J. Miksis and P.W. Voorhees: Role of strain-dependent surface energies in Ge/Si(100) island formation. Phys. Rev. Lett. 94 176102 (2005).
G.H. Lu and F. Liu: Towards quantitative understanding of formation and stability of Ge hut islands on Si(001). Phys. Rev. Lett. 94 176103 (2005).
G. Costantini A. Rastelli C. Manzano R. Songmuang O.G. Schmidt K. Kern and H.V. Känel: Universal shapes of self-organized semiconductor quantum dots: Striking similarities between InAs/GaAs(001) and Ge/Si(001). Appl. Phys. Lett. 85 5673 (2004).
G. Costantini A. Rastelli C. Manzano Acosta-P. Diaz G. Katsaros R. Songmuang O.G. Schmidt H. Kanel v. and K. Kern: Pyramids and domes in the InAs/GaAs(0 0 1) and Ge/Si(0 0 1) systems. J. Cryst. Growth 278 38 (2005).
E. Sutter P. Sutter and J.E. Bernard: Extended shape evolution of low mismatch Si1-xGex alloy islands on Si(100). Appl. Phys. Lett. 84 2262 (2004).
N. Deng P.Y. Chen and Z.J. Li: Self-assembled SiGe islands with uniform shape and size by controlling Si concentration in islands. J. Cryst. Growth 263 21 (2004).
J.A. Floro E. Chason R.D. Twesten R.Q. Hwang and L.B. Freund: SiGe coherent islanding and stress relaxation in the high mobility regime. Phys. Rev. Lett. 79 3946 (1997).
T. Walther A.G. Cullis D.J. Norris and M. Hopkinson: Nature of the Stranski-Krastanow transition during epitaxy of InGaAs on GaAs. Phys. Rev. Lett. 86 2381 (2001).
A.G. Cullis D.J. Norris T. Walther M.A. Migliorato and M. Hopkinson: Stranski–Krastanow transition and epitaxial island growth. Phys. Rev. B 66 081305 (2002).
Y. Tu and J. Tersoff: Origin of apparent critical thickness for island formation in heteroepitaxy. Phys. Rev. Lett. 93 216101 (2004).
X.Z. Liao J. Zou D.J.H. Cockayne J. Qin Z.M. Jiang X. Wang and R. Leon: Strain relaxation by alloying effects in Ge islands grown on Si(001). Phys. Rev. B 60 15605 (1999).
P. Sonnet and P.C. Kelires: Physical origin of trench formation in Ge/Si(100) islands. Appl. Phys. Lett. 85 203 (2004).
S.A. Chaparro Y. Zhang J. Drucker D. Chandrasekhar and D.J. Smith: Evolution of Ge/Si(100) islands: Island size and temperature dependence. J. Appl. Phys. 87 245 (2000).
Y. Zhang and J. Drucker: Annealing-induced Ge/Si(100) island evolution. J. Appl. Phys. 93 9583 (2003).
J.A. Floro M.B. Sinclair E. Chason L.B. Freund R.D. Twesten R.Q. Hwang and G.A. Lucadamo: Novel SiGe island coarsening kinetics: Ostwald ripening and elastic interactions. Phys. Rev. Lett. 84 701 (2000).
P. Liu Y.W. Zhang and C. Lu: Coarsening kinetics of heteroepitaxial islands in nucleationless Stranski–Krastanov growth. Phys. Rev. B 68 035402 (2003).
T.I. Kamins Medeiros-G. Ribeiro D.A.A. Ohlberg and R.S. Williams: Evolution of Ge islands on Si(001) during annealing. J. Appl. Phys. 85 1159 (1999).
G. Capellini M.D. Seta and F. Evangelisti: Ge/Si(100) islands: Growth dynamics versus growth rate. J. Appl. Phys. 93 291 (2003).
G. Capellini De M. Seta and F. Evangelisti: Influence of the growth parameters on self-assembled Ge islands on Si(100). Mater. Sci. Eng. B 89 184 (2002).
A. Rastelli E. Muller and H. Känel v.: Shape preservation of Ge/Si(001) islands during Si capping. Appl. Phys. Lett. 80 1438 (2002).
I. Daruka and J. Tersoff: Existence of shallow facets at the base of strained epitaxial islands. Phys. Rev. B 66 132104 (2002).
I. Daruka J. Tersoff and A.L. Barabási: Shape transition in growth of strained islands. Phys. Rev. Lett. 82 2753 (1999).
U. Denker A. Rastelli M. Stoffel J. Tersoff G. Katsaros G. Costantini K. Kern Jin-N.Y. Phillipp D.E. Jesson and O.G. Schmidt: Lateral motion of SiGe islands driven by surface-mediated alloying. Phys. Rev. Lett. 94 216103 (2005).
M.A. Grinfeld and D.J. Srolovitz: Stress driven morphological instabilities and islanding of epitaxial films in Properties of Strained and Relaxed Silicon Germanium Vol. 12 edited by E. Kasper (INSPEC London U.K. 1995) pp. 3–16.
H. Gao: Some general properties of stress-driven surface evolution in a heteroepitaxial thin film structure. J. Mech. Phys. Solids 42 741 (1994).
K.N. Tu J.W. Mayer and L.C. Feldman: Electronic Thin Film Science for Electrical Engineers and Materials Scientists (Macmillan New York 1992) Appendix E.
J.M. Baribeau A. Delâge S. Janz H. Lafontaine D.J. Lockwood J.P. McCaffrey S. Moisa N.L. Rowell and D.X. Xu: Wavy SiGe/Si superlattices: Structural and optical properites and application to near infrared light detection in Advanced Luminescent Materials and Quantum Confinement edited by M. Cahay S. Bandyopadhyay D.J. Lockwood J.P. Leburton N. Koshida M. Meyyappan and T. Sakamoto (The Electrochemical Society Pennington NJ 1999) p. 45.
O.G. Schmidt N.Y. Jin-Phillipp C. Lange U. Denker K. Eberl R. Schreiner H. Grabeldinger and H. Schweizer: Long-range ordered lines of self-assembled Ge islands on a flat Si (001) surface. Appl. Phys. Lett. 77 4139 (2000).
J. Stangl T. Roch G. Bauer I. Kegel T.H. Metzger O.G. Schmidt K. Eberl O. Kienzle and F. Ernst: Vertical correlation of SiGe islands in SiGe/Si superlattices: X-ray diffraction versus transmission electron microscopy. Appl. Phys. Lett. 77 3953 (2000).
V. Thanh Le and V. Yam: Superlattices of self-assembled Ge/Si(001) quantum dots. Appl. Surf. Sci. 212–213 296 (2003).
G. Springholz: Three-dimensional stacking of self-assembled quantum dots in multilayer structures. C. R. Phys. 6 89 (2005).
E. Sutter P. Sutter and L. Vescan: Organization of self-assembled quantum dots in SiGe/Si multilayers: Effect of strain and substrate curvature. Mater. Sci. Eng. B 89 196 (2002).
J. Tersoff C. Teichert and M.G. Lagally: Self-organization in growth of quantum dot superlattices. Phys. Rev. Lett. 76 1675 (1996).
J. Stangl A. Daniel Holý V. T. Roch G. Bauer I. Kegel T.H. Metzger T. Wiebach O.G. Schmidt and K. Eberl: Strain and composition distribution in uncapped SiGe islands from x-ray diffraction. Appl. Phys. Lett. 79 1474 (2001).
A. Hesse J. Stangl Holý V. T. Roch G. Bauer O.G. Schmidt U. Denker and B. Struth: Effect of overgrowth on shape composition and strain of SiGe islands on Si(001). Phys. Rev. B 66 085321 (2002).
T.U. Schulli J. Stangl Z. Zhong R.T. Lechner M. Sztucki T.H. Metzger and G. Bauer: Direct determination of strain and composition profiles in SiGe islands by anomalous x-ray diffraction at high momentum transfer. Phys. Rev. Lett. 90 066105 (2003).
J. Stangl A. Hesse Holý V. Z. Zhong G. Bauer U. Denker and O.G. Schmidt: Effect of overgrowth temperature on shape strain and composition of buried Ge islands deduced from x-ray diffraction. Appl. Phys. Lett. 82 2251 (2003).
O. Kirfel E. Muller D. Grützmacher K. Kern A. Hesse J. Stangl Holý V. and G. Bauer: Shape and composition change of Ge dots due to Si capping. Appl. Surf. Sci. 224 139 (2004).
A.A. Darhuber Holý V. P. Schittenhelm J. Strangl I. Kegel Z. Kovats T.H. Metzger G. Bauer G. Abstreiter and G. Grubel: Structural characterization of self-assembled Ge dot multilayers by x-ray diffraction and reflectivity methods. Physica E 2 789 (1998).
R. Magalhaes-Paniago G. Medeiros-Ribeiro A. Malachias S. Kycia T. Kamins I. and R. Williams S.: Direct evaluation of composition profile strain relaxation and elastic energy of Ge:Si(001) self-assembled islands by anomalous x-ray scattering. Phys. Rev. B 66 245312/1 (2002).
F. Boscherini: X-ray absorption studies of atomic environments in semiconductor nanostructures. Nucl. Instrum.Meth. Phys. Res. B 199 169 (2003).
F. Boscherini G. Capellinin L.D. Gaspare F. Rosei N. Motta and S. Mobilio: Ge-Si intermixing in Ge quantum dots on Si(001) and Si(111). Appl. Phys. Lett. 76 682 (2000).
C.J. Huang D.Z. Li Z. Yu B.W. Cheng J.Z. Yu and Q.M. Wang: Atomic-force-microscopy investigation of the formation and evolution of Ge islands on GexSi1-x strained layers. Appl. Phys. Lett. 77 391 (2000).
M. Cazayous J. Groenen F. Demangeot R. Sirvin M. Caumont T. Remmele M. Albrecht S. Christiansen M. Becker H.P. Strunk and H. Wawra: Strain and composition in self-assembled SiGe islands by Raman spectroscopy. J. Appl. Phys. 91 6772 (2002).
V.O. Yukhymchuk A.M. Yaremko M.Y. Valakh A.V. Novikov E.V. Mozdor P.M. Lytvyn Z.F. Krasilnik Klad’V.P. ko V.M. Dzhagan N. Mestres and J. Pascual: Theoretical and experimental investigations of single- and multilayer structures with SiGe nanoislands. Mater. Sci. Eng. C 23 1027 (2003).
V. Magidson D.V. Regelman R. Beserman and K. Dettmer: Evidence of Si presence in self-assembled Ge islands deposited on a Si(001) substrate. Appl. Phys. Lett. 73 1044 (1998).
M. Floyd Y. Zhang K.P. Driver J. Drucker P.A. Crozier and D.J. Smith: Nanometer-scale composition measurements of Ge/Si islands. Appl. Phys. Lett. 82 1473 (2003).
U. Denker M. Stoffel and O.G. Schmidt: Probing the lateral composition profile of self-assembled islands. Phys. Rev. Lett. 90 196102 (2003).
U. Denker H. Sigg and O.G. Schmidt: Composition of self assembled Ge hut clusters. Mater. Sci. Eng. B 101 89 (2003).
S.K. Sinha E.B. Sirote S. Garoff and H.B. Stanley: X-ray and neutron scattering from rough surfaces. Phys. Rev. B 38 2297 (1988).
V. Holy U. Pietsch and T. Baumbach: High Resolution X-ray Scattering from Thin Films and Multilayers (Springer Berlin Germany 1999) p. 256.
I. Kegel H. Metzger A. Lorke J. Peisl A. Stangl G. Bauer and K. Nordlund: Determination of strain fields and composition of self-organized quantum dots using x-ray diffraction. Phys. Rev. B 63 035318 (2001).
A. Malachias S. Kycia Medeiros-G. Ribeiro Magalhaes-R. Paniago T.I. Kamins and R.S. Williams: 3D composition of epitaxial nanocrystals by anomalous x-ray diffraction: Observation of a Si-rich core in Ge domes on Si(100). Phys. Rev. Lett. 91 176101 (2003).
M. Floyd Y. Zhang K.P. Driver J. Drucker P.A. Crozier and D.J. Smith: Nanometer-scale composition measurements of Ge/Si(100) islands. Appl. Phys. Lett. 82 1473 (2003).
I. Kegel H. Metzger A. Lorke J. Peisl A. Stangl G. Bauer J.M. Garcia and P.M. Petroff: Nanometer-scale resolution of strain and interdiffusion in self-assembled InAs/GaAs quantum dots. Phys. Rev. Lett. 85 1694 (2000).
J.M. Baribeau X. Wu and D.J. Lockwood: JVST B (submitted).
O.G. Schmidt and K. Eberl: Multiple layers of self-asssembled Ge/Si islands: Photoluminescence strain fields material interdiffusion and island formation. Phys. Rev. B. 61 13721 (2000).
O.G. Schmidt U. Denker S. Christiansen and F. Ernst: Composition of self-assembled Ge/Si islands in single and multiple layers. Appl. Phys. Lett. 81 2614 (2002).
U. Denker H. Sigg and O.G. Schmidt: Intermixing in Ge hut cluster islands. Appl. Surf. Sci. 224 127 (2004).
Y. Chen and J. Washburn: Structural transition in large-lattice-mismatch heteroepitaxy. Phys. Rev. Lett. 77 4046 (1996).
T. Ide A. Sakai and K. Shimizu: Nanometer-scale imaging of strain in Ge island on Si(001) surface. Thin Solid Films 357 22 (1999).
P. Raiteri L. Miglio F. Valentinotti and M. Celino: Strain maps at the atomic scale below Ge pyramids and domes on a Si substrate. Appl. Phys. Lett. 80 3736 (2002).
C.J. Huang Y.H. Zuo D.Z. Li B.W. Cheng L.P. Luo J.Z. Yu and Q.M. Wang: Shape evolution of Ge/Si(001) islands induced by strain-driven alloying. Appl. Phys. Lett. 78 3881 (2001).
T.U. Schülli J. Stangl Z. Zhong R.T. Lechner M. Sztucki T.H. Metzger and G. Bauer: Direct determination of strain and composition profiles in SiGe islands by anomalous x-ray diffraction at high momentum transfer. Phys. Rev. Lett. 90 066105 (2003).
H.D. Fuchs C.H. Grein M.I. Alonso and M. Cardona: High-resolution raman spectroscopy of Ge-rich c-Ge1-xSix alloys: Features of the Ge–Ge vibrational modes. Phys. Rev. B 44 13120 (1991).
A.B. Talochkin V.A. Markov A.I. Nikiforov and S.A. Tiis: Optical phonon spectrum of germanium quantum dots. JETP Lett. 70 288 (1999).
A.G. Milekhin A.I. Nikiforov O.P. Pchelyakov S. Schulze and D.R.T. Zahn: Phonons in Ge/Si superlattices with Ge quantum dots. JETP Lett. 73 461 (2001).
B.V. Kamenev H. Grebel L. Tsybeskov T.I. Kamins R.S. Williams J.M. Baribeau and D.J. Lockwood: Polarized raman scattering and localized embedded strain in self-organized Si/Ge nanostructures. Appl. Phys. Lett. 83 5035 (2003).
A.B. Talochkin and S.A. Teys: Optical phonons in Ge quantum dots obtained on Si (111). JETP Lett. 75 264 (2002).
K. Terashima M. Tajima and T. Tatsumi: Near-band-gap photoluminescence of Si1-xGex alloys grown on Si(100) by molecular beam epitaxy. Appl. Phys. Lett. 57 1925 (1990).
J.C. Sturm H. Manoharan L.C. Lenchyshyn M.L.W. Thewalt N.L. Rowell NoëJ.P. l and D.C. Houghton: Well-resolved band-edge photoluminescence of excitons confined in strained Si1-xGex quantum wells. Phys. Rev. Lett. 66 1362 (1991).
D.V. Lang R. People J.C. Bean and A.M. Sergent: Measurement of the band gap of GexSi1-x/Si strained-layer heterostructures. Appl. Phys. Lett. 47 1333 (1985).
X. Xiao C.W. Liu J.C. Sturm L.C. Lenchyshyn M.L.W. Thewalt R.B. Gregory and P. Fejes: Quantum confinement effects in strained silicon-germanium alloy quantum wells. Appl. Phys. Lett. 60 2135 (1992).
D.J. Robbins L.T. Canham S.J. Barnett A.D. Pitt and P. Calcott: Near-band-gap photoluminescence from pseudomorphic Si1-xGex single layers on silicon. J. Appl. Phys. 71 1407 (1992).
D. Dutartre G. Bré mond A. Souifi and T. Benyattou: Excitonic photoluminescence from Si-capped strained Si1-xGex layers. Phys. Rev. B 44 11525 (1991).
N.L. Rowell J.P. Noël D.C. Houghton A. Wang L.C. Lenchyshyn M.L.W. Thewalt and D.D. Perovic: Exciton luminescence in Si1-xGex/Si heterostructures grown by molecular beam epitaxy. J. Appl. Phys. 74 2790 (1993).
J.P. Nöel N.L. Rowell D.C. Houghton and D.D. Perovic: Intense photoluminescence between 1.3 and 1.8 µm from strained Si1-xGex alloys. Appi. Phys. Lett. 57 1037 (1990).
O.G. Schmidt C. Lange K. Eberl O. Kienzle and F. Ernst: Formation of carbon-induced germanium dots. Appl. Phys. Lett. 71 2340 (1997).
S. Fukatsu H. Sunamura Y. Shiraki and S. Komiyama: Suppression of phonon replica in the radiative recombination of an MBE-grown type-ii Ge/Si quantum dot. Thin Solid Films 321 65 (1998).
P. Boucaud V.L. Thanh S. Sauvage D. Debarre D. Bouchier and J.M. Lourtioz: Photoluminescence of self-assembled Ge dots grown by ultra-high-vacuum chemical vapor deposition. Thin Solid Films 336 240 (1998).
M. Goryll L. Vescan and H. Lüth: Morphology and photoluminescence of Ge islands grown on Si(001). Thin Solid Films 336 244 (1998).
O.G. Schmidt C. Lange and K. Eberl: Photoluminescence study of the 2D–3D growth mode changeover for different Ge/Si island phases. Phys. Status Solidi B 215 319 (1999).
O.G. Schmidt C. Lange and K. Eberl: Photoluminescence study of the initial stages of island formation for Ge pyramids/domes and hut clusters on Si(001). Appl. Phys. Lett. 75 1905 (1999).
A. Beyer E. Müller H. Sigg S. Stutz D. Grützmacher O. Leifeld and K. Ensslin: Size control of carbon-induced Ge quantum dots. Appl. Phys. Lett. 77 3218 (2000).
O.G. Schmidt K. Eberl and Y. Rau: Strain and band-edge alignment in single and multiple layers of self-assembled Ge/Si and GeSi/Si islands. Phys. Rev. B 62 16715 (2000).
N. Usami and Y. Shiraki: Optical investigation of modified Stranski–Krastanov growth mode in the stacking of self-assembled Ge islands. Thin Solid Films 369 108 (2000).
F. Gao C.J. Huang D.D. Huang J.P. Li D.Z. Sun M.Y. Kong Y.P. Zeng J.M. Li and L.Y. Lin: Changing the size and shape of Ge island by chemical etching. J. Cryst. Growth 231 17 (2001).
L. Vescan: Ge nanostructures grown by self-assembly; influence of substrate orientation. J. Phys. C 14 8235 (2002).
G.E. Cirlin V.G. Talalaev N.D. Zakharov V.A. Erorov and P. Werner: Room temperature superlinear power dependence of photoluminescence from defect-free Si/Ge quantum dot multilayer strucures. Phys. Status Solidi B 232 R1 (2002).
I. Berbezier A. Ronda and A. Portavoce: SiGe nanostructures: New insights into growth processes. J. Phys. C 14 8283 (2002).
L. Vescan T. Stoica B. Hollander A. Nassiopoulou A. Olzierski I. Raptis and E. Sutter: Self-assembling of Ge on finite Si(001) areas comparable with the island size. Appl. Phys. Lett. 82 3517 (2003).
M. Larsson A. Elfving P.O. Holtz G.V. Hansson and W.X. Ni: Luminescence study of Si/Ge quantum dots. Physica E 16 476 (2003).
A.G. Makarov N.N. Ledentsov A.F. Tsatsal’nikov G.E. Cirlin V.A. Egorov V.M. Usinov N.D. Zakharov and P. Werner: Optical properties of structures with ultradense arrays of Ge QD’s in a Si matrix. Semiconductors 37 210 (2003).
A.V. Novikov D.N. Lobanov A.N. Yablonsky Y.N. Drozdov N.V. Vostokov and Z.F. Krasilnik: Photoluminescence of Ge(Si)/Si(001) self-assembled islands in the near infra-red wavelength range. Physica E 16 467 (2003).
F. Volpi A.R. Peaker I.D. Hawkins M.P. Halsall P.B. Kenway A. Portavoce A. Ronda and I. Berbezier: Hole trapping in self-assembled SiGe quantum nanostructures. Mater. Sci. Eng. B 101 338 (2003).
L.H. Nguyen V. LeThanh D. Debarre V. Yam M. Halbwax M. Kurdi El D. Bouchier P. Rosner M. Becker M. Benamara and H.P. Strunk: Selective epitaxial growth of Ge quantum dots on patterned SiO2/Si(001) surfaces. Appl. Surf. Sci. 224 134 (2004).
V. Yam V. Thanh Le D. Debarre Y. Zheng and D. Bouchier: Kinetics of Si capping process of Ge/Si(001) quantum dots. Appl. Surf. Sci. 224 143 (2004).
W.Y. Chen W.H. Chang A.T. Chou T.M. Hsu P.S. Chen Z. Pei and L.S. Lai: Optical properties of stacked Ge/Si quantum dots with different spacer thickness grown by chemical vapor deposition. Appl. Surf. Sci. 224 148 (2004).
L.H. Nguyen V. Thanh Le D. Debarre V. Yam and D. Bouchier: Selective growth of Ge quantum dots on chemically prepared SiO2/Si(001) surfaces. Mater. Sci. Eng. B 101 199 (2003).
L.H. Nguyen Nguyen-T.K. Duc Le V. Thanh F.A. d’Avitaya and J. Derrien: Growth and optical properties of Ge/Si quantum dots formed on patterned SiO2/Si(001) substrates. Physica E 23 p. 471 (2004).
N.L. Rowell J.P. Noël D.C. Houghton and M. Buchanan: Electroluminescence and photoluminescence from Si1-xGex alloys. Appl. Phys. Lett. 58 957 (1991).
J.P. Nöel N.L. Rowell D.C. Houghton A. Wang and D.D. Perovic: Luminescence origins in molecular beam epitaxial Si1-xGex. Appl. Phys. Lett. 61 690 (1992).
U. Denker M. Stoffel O.G. Schmidt and H. Sigg: Ge hut cluster luminescence below bulk Ge band gap. Appl. Phys. Lett. 82 454 (2003).
P. Boucaud S. Sauvage M. Elkurdi E. Mercier T. Brunhes V.L. Thanh D. Bouchier O. Kermarrec Y. Campidelli and D. Bensahel: Optical recombination from excited states in Ge/Si self-assembled quantum dots. Phys. Rev. B 64 155310 (2001).
B.V. Kamanev J.M. Baribeau D.J. Lockwood and L. Tsybeskov: Optical properties of Stranski–Krastanov grown three-dimensional Si/Si1-xGex nanostructures. Physica E 26 174 (2005).
D.N. Lobanov A.V. Novikov N.V. Vostokov Y.N. Drozdov A.N. Yablonskiy Z.F. Krasilnik M. Stoffel U. Denker and O.G. Schmidt: Growth and photoluminescence of self-assembled islands obtained during the deposition of Ge on a strained SiGe layer. Opt. Mater. 27 818 (2005).
M. Stoffel G.S. Kar U. Denker A. Rastelli H. Sigg and O.G. Schmidt: Shape facet evolution and photoluminescence of Ge islands capped with Si at different temperatures. Physica E 23 421 (2004).
L. Martinelli A. Marzegalli P. Raiteri M. Bollani F. Montalenti L. Miglio D. Chrastina G. Isella and H.v. Känel: Formation of strain-induced Si-rich and Ge-rich nanowires at misfit dislocations in SiGe: A model supported by photoluminescence data. Appl. Phys. Lett. 84 2895 (2004).
P.S. Chen S.W. Lee Y.H. Peng C.W. Liu and M.J. Tsai: Improvement of photoluminescence efficiency in stacked Ge/Si/Ge quantum dots with a thin Si spacer. Phys. Status Solidi 241 3650 (2004).
N.V. Vostokov Z.F. Krasil’nik D.N. Lobanov A.V. Novikov M.V. Shaleev and A.N. Yablonsky: Influence of the germanium deposition rate on the growth and photoluminescence of Ge(Si)/Si(001) self-assembled islands. Phys. Solid State 47 38 (2005).
P.I. Gaiduk A.N. Larsen J.L. Hansen A.V. Mudryj M.P. Samtsov and A.N. Demenschenok: Self-assembly of epitaxially grown Ge/Si quantum dots enhanced by as ion implantation. Appl. Phys. Lett. 79 025 (2001).
L.P. Rokhinson D.C. Tsui J.L. Benton and Y.H. Xie: Infrared and photoluminescence spectroscopy of p-doped self-assembled Ge dots on Si. Appl. Phys. Lett. 75 2413 (1999).
K. Sakamoto H. Matsuhata M.O. Tanner D. Wang and K.L. Wang: Alignment of Ge three-dimensional islands on faceted Si(001) surfaces. Thin Solid Films 321 55 (1998).
F. Liu J. Tersoff and M.G. Lagally: Self-organization of steps in growth of strained films on vicinal substrates. Phys. Rev. Lett. 80 1268 (1998).
J.H. Zhu K. Brunner and G. Abstreiter: Two-dimensional ordering of self-assembled Ge islands on vicinal Si(001) surfaces with regular ripples. Appl. Phys. Lett. 73 620 (1998).
R.V. Kukta and D. Kouris: On the mechanisms of epitaxial island alignment on patterned substrates. J. Appl. Phys. 97 033527 (2005).
Z. Zhong A. Halilovic M. Muhlberger SchäF. ffler and G. Bauer: Ge island formation on stripe-patterned Si(001) substrates. Appl. Phys. Lett. 82 445 (2003).
C.h. Chiu: Stable and uniform arrays of self-assembled nanocrystalline islands. Phys. Rev. B 69 165413 (2004).
Y.H. Xie S.B. Samavedam M. Bulsara T.A. Langdo and E.A. Fitzgerald: Relaxed template for fabricating regularly distributed quantum dot arrays. Appl. Phys. Lett. 71 3567 (1997).
C. Teichert C. Hofer K. Lyutovich M. Bauer and E. Kasper: Interplay of dislocation network and island arrangement in SiGe films grown on Si(001). Thin Solid Films 380 25 (2000).
F. Leroy J. Eymery P. Gentile and F. Fournel: Ordering of Ge quantum dots with buried Si dislocation networks. Appl. Phys. Lett. 80 3078 (2002).
S.Y. Shiryaev E.V. Pedersen F. Jensen J.W. Petersen J.L. Hansen and A.N. Larsen: Dislocation patterning—A new tool for spatial manipulation of Ge islands. Thin Solid Films 294 311 (1997).
B. Voigtlander and N. Theuerkauf: Ordered growth of Ge islands above a misfit dislocation network in a Ge layer on Si(111). Surf. Sci. 461L575 (2000).
D.D. Perovic G.C. Weatherly P.J. Simpson P.J. Schultz T.E. Jackman G.C. Aers NoëJ.P. l and D.C. Houghton: Microvoid formation in low-temperature molecular-beam-epitaxy-grown silicon. Phys. Rev. B 43 14257 (1991).
T.E. Jackman G.C. Aers J.P. McCaffrey D. Britton P. Willtzki P.J. Schultz P.J. Simpson and P. Mascher: Depth profiling of defects in low-temperature MBE-grown silicon in Positron Annihilation Proceedings of the 9th International Conference on Positron Annihilation Materials Science Forum Vol. 105–110 edited by Z. Kajcsos and C. Szeles (Trans Tech Publication Inc. Zurich Switzerland 1992) p. 301.
J.M. Baribeau X. Wu D.J. Lockwood L. Tay and G.I. Sproule: Low temperature Si growth on Si(001): Impurity incorporation and limiting thickness for epitaxy. J. Vac. Sci. Technol. B 22 1479 (2004).
J.M. Baribeau N.L. Rowell and D.J. Lockwood: Progress in the growth and characterization of Ge quantum dots and islands in Group-IV Semiconductor Nanostructures edited by L. Tsybeskov D.J. Lockwood C. Delerue and M. Ichikawa (Mater. Res. Soc. Symp. Proc. 832 Warrendale PA 2005) p. 93.
T.I. Kamins and R.S. Williams: Lithographic positioning of self-assembled Ge islands on Si(001). Appl. Phys. Lett. 71 1201 (1997).
G. Jin J.L. Liu S.G. Thomas Y.H. Luo K.L. Wang and B.Y. Nguyen: Controlled arrangement of self-organized Ge islands on patterned Si (001) substrates. Appl. Phys. Lett. 75 2752 (1999).
T.I. Kamins D.A.A. Ohlberg R.S. Williams W. Zhang and S.Y. Chou: Positioning of self-assembled single-crystal germanium islands by silicon nanoimprinting. Appl. Phys. Lett. 74 1773 (1999).
T. Kitajima B. Liu and S.R. Leone: Two-dimensional periodic alignment of self-assembled Ge islands on patterned Si(001) surfaces. Appl. Phys. Lett. 80 497 (2002).
Z. Zhong A. Halilovic M. Muhlberger F. Schäffler and G. Bauer: Positioning of self-assembled Ge islands on stripe-patterned Si(001) substrates. J. Appl. Phys. 93 6258 (2003).
Z. Zhong A. Halilovic T. Fromherz F. Schäffler and G. Bauer: Two-dimensional periodic positioning of self-assembled Ge islands on prepatterned Si (001) substrates. Appl. Phys. Lett. 82 4779 (2003).
Z. Zhong A. Halilovic H. Lichtenberger F. Schäffler and G. Bauer: Growth of Ge islands on prepatterned Si (001) substrates. Physica E 23 243 (2004).
Z. Zhong and G. Bauer: Site-controlled and size-homogeneous Ge islands on prepatterned Si (001) substrates. Appl. Phys. Lett. 84 1922 (2004).
J.J. Eggleston and P.W. Voorhees: Ordered growth of nanocrystals via a morphological instability. Appl. Phys. Lett. 80 306 (2002).
S.M. Wise and W.C. Johnson: Numerical simulations of pattern-directed phase decomposition in a stressed binary thin film. J. Appl. Phys. 94 889 (2003).
O.G. Schmidt C. Lange K. Eberl O. Kienzle and F. Ernst: Formation of carbon-induced germanium dots. Appl. Phys. Lett. 71 2340 (1997).
O.G. Schmidt S. Schieker K. Eberl O. Kienzle and F. Ernst: Carbon-induced germanium dots: Kinetically-limited islanding process prevents coherent vertical alignment. Appl. Phys. Lett. 73 59 (1998).
O.G. Schmidt C. Lange K. Eberl and O.K.F. Ernst: C-induced Ge dots: A versatile tool to fabricate ultra-small Ge nanostructures. Thin Solid Films 336 248 (1998).
D. Dentel L. Vescan O. Chretien and B. Hollander: Influence of molecular hydrogen on Ge island nucleation on Si(001). J. Appl. Phys. 88 5113 (2000).
Y. Wakayama L.V. Sokolov N. Zakharov P. Werner and U. Gosele: Precise control of size and density of self-assembled Ge dot on Si(100) by carbon-induced strain-engineering. Appl. Surf. Sci. 216 419 (2003).
J.M. Baribeau D.J. Lockwood J. Balle S.J. Rolfe and G.I. Sproule: Si1-x-yGexCy alloy growth by electron cyclotron resonance plasma-assisted Si molecular beam epitaxy. Mater. Sci. Eng. B 89 296 (2002).
J.M. Baribeau D.J. Lockwood J. Balle S.J. Rolfe G.I. Sproule and S. Moisa: Molecular beam epitaxy synthesis of Si1-yCy and Si1-x-yGexCy alloys and Ge islands using an electron cyclotron resonance argon/methane plasma. Thin Solid Films 410 61 (2002).
X. Shao R. Jonczyk M. Dashiell D. Hits B.A. Orner A.S. Khan K. Roe J. Kolodzey P.R. Berger M. Kaba M.A. Barteau and K.M. Unruh: Strain modification in thin Si1-x-yGexCy alloys on (100) Si for formation of high density uniformly sized quantum dots. J. Appl. Phys. 85 578 (1999).
D. Dentel J.L. Bischoff L. Kubler M. Stoffel and G. Castelein: Influence of a pre-deposited carbon submonolayer on the Ge island nucleation on Si(001). J. Appl. Phys. 93 5069 (2003).
O. Leifeld A. Beyer E. Muller D. Grützmacher and K. Kern: Nucleation of Ge quantum dots on the C-alloyed Si(001) surface. Thin Solid Films 380 176 (2000).
A. Sakai and T. Tatsumi: Ge growth on Si using atomic hydrogen as a surfactant. Appl. Phys. Lett. 64 52 (1994).
J.M. Baribeau D.J. Lockwood R.W.G. Syme and H.J. Labbe: Atomic hydrogen assisted growth of Si-Ge heterostructrues on (001) Si in Control of Semiconductor Surfaces and Interfaces edited by S.M. Prokes O.J. Glembocki S.K. Brierley J.M. Gibson and J.M. Woodall (Mater. Res. Soc. Symp. Proc. 448 Pittsburgh PA 1997) p. 113.
A. Portavoce A. Ronda and I. Berbezier: Sb-surfactant mediated growth of Ge nanostructures. Mater. Sci. Eng. B 89 205 (2002).
A. Portavoce F. Volpi A. Ronda P. Gas and I. Berbezier: Sb segregation in Si and SiGe: Effect on the growth of self-organised Ge dots. Thin Solid Films 380 164 (2000).
D.J. Eaglesham F.C. Unterwald and D.C. Jacobson: Growth morphology and the equilibrium shape: The role of “surfactants” in Ge/Si island formation. Phys. Rev. Lett. 70 966 (1993).
T.I. Kamins Medeiros-G. Ribeiro D.A.A. Ohlberg and R.S. Williams: Annealing of phosphorus-doped Ge islands on Si(001). J. Appl. Phys. 95 1562 (2004).
J.M. Baribeau D.C. Houghton T.E. Jackman and J.P. McCaffrey: Molecular-beam-epitaxy growth of Ge on (100) Si. J. Electrochem. Soc. 136 1158 (1989).
H.K. Shin D.J. Lockwood and J.M. Baribeau: Strain in coherentwave SiGe/Si superlattices. Solid State Commun. 114 505 (2000).
Author information
Authors and Affiliations
Corresponding author
Additional information
This paper was selected as the Outstanding Meeting Paper for the 2004 MRS Fall Meeting Symposium F Proceedings, Vol. 832.
Rights and permissions
About this article
Cite this article
Baribeau, J.M., Rowell, N.L. & Lockwood, D.J. Advances in the growth and characterization of Ge quantum dots and islands. Journal of Materials Research 20, 3278–3293 (2005). https://doi.org/10.1557/jmr.2005.0405
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2005.0405