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Formation of BaPbO3-x and BaPb1/3Bi2/3O3-x from Ba(COO)2·0.5H2O and Pb(COO)2 oxalates

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Abstract

This paper reports a way to obtain BaPbO3-x and BaPb1/3Bi2/3O3-x perovskite-type compounds. The method is based on the initial preparation of Ba(COO)2·0.5H2O and Pb(COO)2·oxalates, and the subsequent calcination of the equimolar physical mixture of these oxalates until the desired compounds BaPbO3-x and BaPb1/3Bi2/3O3-x are formed. To obtain BaPb1/3Bi2/3O3-x, the oxide Bi2O3 is added to the mixture of oxalates and calcined together with them. The temperature for the formation of BaPbO3-x and BaPb1/3Bi2/3O3-x was estimated to be 850°C. These final compounds prepared by calcination were composed of a single phase and exhibited monoclinic crystal structure. The thermal decomposition of the Pb(COO)2 oxalate and the formation of BaPbO3-x and BaPb1/3Bi2/3O3-x were investigated by X-ray powder diffraction (XRPD) and differential thermal analysis (DTA).

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Authors and Affiliations

  1. The City University of New York, Borough of Manhattan Community College, 199 Chambers St., New York, NY, 10007, U.S.A.

    Barys Korzun & Joel Hernandez

  2. Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus, 19 P. Brovki, Minsk, 220072, Belarus

    Alena Fadzeyeva

Authors
  1. Barys Korzun
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  2. Alena Fadzeyeva
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  3. Joel Hernandez
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Korzun, B., Fadzeyeva, A. & Hernandez, J. Formation of BaPbO3-x and BaPb1/3Bi2/3O3-x from Ba(COO)2·0.5H2O and Pb(COO)2 oxalates. MRS Advances 5, 2647–2658 (2020). https://doi.org/10.1557/adv.2020.322

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