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Fungi-derived xylindein: effect of purity on optical and electronic properties

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Abstract

We present a study of optical and electronic properties of solutions and films based on the fungi-derived pigment xylindein, extracted from decaying wood and processed without and with a simple purification step (“ethanol wash”). The “post-wash” xylindein solutions exhibited considerably lower absorption in the ultraviolet spectral range and dramatically reduced photoluminescence below 600 nm, due to removal of contaminants most likely to be fungal secondary metabolites. The “post-wash” xylindein-based films were characterized by two orders of magnitude higher charge carrier mobilities as compared to “pre-wash” samples. This underlines the importance of minimizing contaminants that disrupt the conductive xylindein network in xylindein-based electronic devices.

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References

  1. O. Ostroverkhova, Chem. Rev. 116, 13279 (2016).

    Article  CAS  Google Scholar 

  2. M. Irimia-Vladu, Chem. Soc. Rev. 43, 588 (2014).

    Article  CAS  Google Scholar 

  3. M. Irimia-Vladu, E. D. Glowacki, P. A. Troshin, G. Schwabegger, L. Leonat, D. Susarova, O. Krystal, M. Ullah, Y. Kanbur, M. Bodea, V. Razumov, H. Sitter, S. Bauer, and N. S. Sariciftci, Adv. Mater. 24, 375 (2012).

    Article  CAS  Google Scholar 

  4. E. D. Glowacki, G. Voss, L. Leonat, M. Irmia-Vladu, S. Bauer, and N. S. Sariciftci, Isr. J. Chem. 52, 540 (2012).

    Article  CAS  Google Scholar 

  5. M. Dittmann, F. F. Graupner, B. Maerz, S. Oesterling, R. Devivie-Riedle, W. Zinth, M. Engelhard, and W. Luettke, Angew. Chemie — Int. Ed. 53, 591 (2014).

    Article  CAS  Google Scholar 

  6. E. D. Głowacki, M. Irimia-Vladu, S. Bauer, and N. S. Sariciftci, J. Mater. Chem. B 1, 3742 (2013).

    Article  Google Scholar 

  7. G. Giesbers, J. Van Schenck, S. V. Gutierrez, and S. Robinson, MRS Adv. 3, 3459 (2018).

    Article  CAS  Google Scholar 

  8. G. Giesbers, J. Van Schenck, A. Quinn, R. Van Court, S. Vega Gutierrez, S. Robinson, and O. Ostroverkhova, submitted (2019).

  9. D. Benson, I. Karsch-Mizrachi, K. Clark, D. Lipman, J. Ostell, and E. Sayers, Nucleic Acids Res. 40, D48 (2012).

    Article  CAS  Google Scholar 

  10. S. C. Robinson, V. S. Gutierrez, R. A. Cespedes, N. Iroume, N. R. Vorland, A. McClelland, M. Huber, and S. Stanton, J. Coatings Technol. Res. 14, 1107 (2017).

    Article  CAS  Google Scholar 

  11. M. Frisch, G. Trucks, H. Schlegel, G. Scuseria, M. Robb, M. Cheeseman, G. Scalmani, V. Barone, G. Petersson, and H. Nakatsuii, X. Li, M. Caricato, A. V. Marenich, J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, J. V. Ortiz, A. F. Izmaylov, J. L. Sonnenberg, D. Williams-Young, F. Ding, F. Lipparini, F. Egidi, J. Goings, B. Peng, A. Petrone, T. Henderson, D. Ranasinghe, V. G. Zakrzewski, J. Gao, N. Rega, G. Zheng, W. Liang, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, K. Throssell, J. A. Montgomery, Jr., J. E. Peralta, F. Ogliaro, M. J. Bearpark, J. J. Heyd, E. N. Brothers, K. N. Kudin, V. N. Staroverov, T. A. Keith, R. Kobayashi, J. Normand, K. Raghavachari, A. P. Rendell, J. C. Burant, S. S. Iyengar, J. Tomasi, M. Cossi, J. M. Millam, M. Klene, C. Adamo, R. Cammi, J. W. Ochterski, R. L. Martin, K. Morokuma, O. Farkas, J. B. Foresman, and D. J. Fox, Gaussian 16, Wallingford, CT (2016).

  12. J. Day, A. D. Platt, S. Subramanian, J. E. Anthony, and O. Ostroverkhova, J. Appl. Phys. 105, 103703 (2009).

    Article  Google Scholar 

  13. N. Gospodinova and E. Tomšík, Prog. Polym. Sci. 43, 33 (2015).

    Article  CAS  Google Scholar 

  14. R. L. Edwards and N. Kale, Tetrahedron 21, 2095 (1965).

    Article  CAS  Google Scholar 

  15. Y. Saikawa, T. Watanabe, K. Hashimoto, and M. Nakata, Phytochemistry 55, 237 (2000).

    Article  CAS  Google Scholar 

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Giesbers, G., Krueger, T., Van Schenck, J. et al. Fungi-derived xylindein: effect of purity on optical and electronic properties. MRS Advances 4, 1769–1777 (2019). https://doi.org/10.1557/adv.2019.269

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  • DOI: https://doi.org/10.1557/adv.2019.269

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