Abstract
Dendritic growth during charging period is one of the main barriers for the rechargeablity of conventional batteries. Additionally this phenomenon hinders the utilization of high energy density metal candidates by limiting the safety and allowable operating condition for these devices. We address the role of square wave pulse on the growth dynamics of dendrites in the continuum scale and large time periods by formulating an analytical criterion. Our dimension-free analysis permits the application our results to a variety of electrochemical systems in diverse scales.
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Z. Li, J. Huang, B.Y. Liaw, V. Metzler, and J. Zhang. J. Power Sources, 182 (2014).
M.A. Rahman, X. Wang, and C. Wen. J of Appl Electrochem 44.1 (2014)
W. Xu, J. L. Wang, F. Ding, X. L. Chen, E. Nasybutin, Y. H. Zhang, and J. G. Zhang. En & Env Sci, 7,2 (2014).
Kang Xu. Chemical Reviews, 104,10 (2004).
F. Orsini A.D. Pasquier, B. Beaudoin, J.M. Tarascon et al. J. Pow Sources, 76 (1998).
C. Monroe and J. Newman. J. Electrochem Soc 151, 6 (2004).
C. P. Nielsen, H. Bruus. arXiv:1505.07571, 2015.
K.J. Harry, D.T. Hallinan, D.Y. Parkinson, A.A. MacDowell, and N.P. Balsara, Nature materials, 13,1 (2014).
J. Steiger, D. Kramer, and R. Monig. J. Power Sources, 261 (2014).
R. Younesi, G. M. Veith, P. Johansson, K. Edstrom, and T. Vegge: 8, 7 (2015).
R. Khurana, J. Schaefer, L.A. Archer, and G. W. Coates. J. Am Chem Soc (2014).
C. Brissot, M. Rosso, J. N. Chazalviel, and S. Lascaud. J Power Sources, 81 (1999).
I. W. Seong, C. H. Hong, B. K. Kim, and W. Y. Yoon. Journal of Power Sources,178 ,2, (2008).
A. Aryanfar, D. J. Brooks, A. J. Colussi, and M. R. Hoffmann: Phys Chem Chem Phys, 16, 45, (2014).
A. Aryanfar, D.J. Brooks, A. J. Colussi, B. V. Merinov, W. A. Goddard III, and M.R. Hoffmann: Phys Chem Chem Phys, 17,12 (2015).
C. Xu, Z. Ahmad, A. Aryanfar, V.S. Viswanathan, and J. R. Greer. PNAS, 114,1 (2017).
R. Bhattacharyya, B. Key, H. L. Chen, A. S. Best, A. F. Hollenkamp, and C. P. Grey. Nature Mat, 9, 6 (2010).
S. Chandrashekar, N.M. Trease, H.J. Chang, L.S. Du, C.P. Grey, and A. Jerschow: Nat Mat, 11,4 (2012).
M. S. Chandrasekar, and M. Pushpavanam: Electrochimica Acta 53.8: (2008)
Q. Li, S. Tan, L. Li, Y. Lu, and Y. He: Sci Adv, 3,7, (2017)
A. Aryanfar, D. Brooks, B.V. Merinov, W.A. Goddard III, A.J. Colussi, and M.R. Hoffmann: J Phys Chem Lett, 5,10, (2014)
M.Z. Bazant, B.D. Storey, A.A. Kornyshev: Phys Rev Lett, 106,4, (2011).
D. Aurbach, E. Zinigrad, Y. Cohen, and H. Teller: Solid State Ionics, 148, 3, (2002).
D.R. Ely, A. Jana, R.E. García: J Pow Sources, 272, (2014)
M.Z. Mayers, J.W. Kaminski, T.F. Miller III.: J. Phys Chem C, 116,50, (2012).
R.B. Bird, W.E. Stewart and E.N. Lightfoot. john wiley & sons, (1960).
A. J. Bard, L.R. Faulkner: Wiley & Sons, (1980).
P. Bai, J. Li, F.R. Brushett and M.Z. Bazant. En & Env Sci, 9,10, (2016).
C. Brissot, M. Rosso, J. N. Chazalviel, and S. & Lascaud: J Pow Sources, 81(1999).
J. Li, E. Murphy, J. Winnick, and P.A. Kohl: J Pow Sources, 102,1, (2001).
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Aryanfar, A., Brooks, D.J. & Goddard, W.A. Theoretical pulse charge for the optimal inhibition of growing dendrites. MRS Advances 3, 1201–1207 (2018). https://doi.org/10.1557/adv.2018.97
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DOI: https://doi.org/10.1557/adv.2018.97