Skip to main content

Advertisement

SpringerLink
Log in

Enhancing performance of microbial fuel cell treating distillery wastewater using carbon supported Nickel-phthalocyanine/MnOx as novel cathode catalyst

  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

Three MFCs with different catalyst incorporated on carbon felt cathode, viz. nickel phthalocyanine-MnOx (NiPc-MnOx) composite (MFC-1), platinum (MFC-2), control MFC with bare carbon felt (MFC-3) were used for treating distillery wastewater. The linear sweep voltammetry studies revealed that a maximum current density of 3.7 Am−2 was achieved for NiPc-MnOx/C catalysed cathode, which is 13-folds higher than that for control cathode (0.27 Am−2). Consequently, MFC-1 demonstrated a power density of 48.8 mWm−2, which was around 3.3-folds higher than the control MFC (14.9 mWm−2) owing to the improved oxidation reduction kinetics in case of NiPc-MnOx/C catalysed cathode. Coulombic efficiency (CE) was enhanced by a margin of about 11 % for MFC-1 (24.8 %) in comparison to MFC-3 (13.4 %). MFC-2 having platinum cathode catalyst exhibited a power density of 61.3 mWm−2, which was slightly higher than that achieved by MFC-2. However, NiPc-MnOx was prepared at 3-fold less cost as compared to platinum. Hence, NiPc-MnOx/C can be used as an alternative to platinum as cathode catalyst in MFC treating distillery wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Md.T. Noori, M.M. Ghangrekar, C.K. Mukherjee, Electrochim. Acta. 228, 513 (2017).

    Article  CAS  Google Scholar 

  2. M. Ghasemi, W.R.W. Daud, S.H.A. Hassan, S.E. Oh, M. Ismail, M. Rahimnejad, J.M. Jahim, J. Alloys Compd. 580, 245 (2013).

    Article  CAS  Google Scholar 

  3. B.R. Tiwari, Md.T. Noori, M.M. Ghangrekar, Int. J. Hydrogen Energy 42, 23085 (2017).

    Article  CAS  Google Scholar 

  4. B.R. Tiwari, Md.T. Noori, M.M. Ghangrekar, Mater. Chem. Phys. 182, 86 (2016).

    Article  CAS  Google Scholar 

  5. B.R. Tiwari, M.M. Ghangrekar, Energy Fuels, 29, 3518 (2015).

    Article  CAS  Google Scholar 

  6. APHA, AWWA, WPCF. Standard methods for examination of water and wastewater, 20th ed. (American Public Health Association. Washington DC, 1998).

    Google Scholar 

  7. B.E. Logan, Microbial Fuel Cells, (Wiley & Sons, Inc., Hoboken, NJ. 2008)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Civil Engineering, Indian Institute of Technology, Kharagpur, 721302, India

    B. R. Tiwari & M. M. Ghangrekar

  2. Department of Agriculture and Food Engineering, Indian Institute of Technology, Kharagpur, 721302, India

    Md. T. Noori

Authors
  1. B. R. Tiwari
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Md. T. Noori
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. M. Ghangrekar
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tiwari, B.R., Noori, M.T. & Ghangrekar, M.M. Enhancing performance of microbial fuel cell treating distillery wastewater using carbon supported Nickel-phthalocyanine/MnOx as novel cathode catalyst. MRS Advances 3, 657–662 (2018). https://doi.org/10.1557/adv.2018.73

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/adv.2018.73

Search

Navigation