Skip to main content

Advertisement

SpringerLink
Log in

Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell

  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

In this study, we conducted the first energy dispersive x-ray diffraction (EDXRD) experiments on Li/Li1.1V3O8 coin cells discharged to different lithiation levels in order to investigate the phase transitions upon electrochemical reduction. The phase transformation from layered Li-poor α to Li-rich α to defect rock-salt β phase was confirmed with cells of different lithiation stages. No spatial localization of phase formation was observed throughout the cathodes under the conditions of this measurement.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. Sarkar, A. Bhowmik, M. Dixit Bharadwaj and S. Mitra, J. Electrochem. Soc 161, A14 (2014).

    Article  CAS  Google Scholar 

  2. Q. Shi, J. W. Liu, R. Z. Hu, M. Q. Zeng, M. J. Dai and M. Zhu, RSC Adv., 2, 7273 (2012).

    Article  CAS  Google Scholar 

  3. L. A. de Picciotto, K. T. Adendorff, D. C. Liles and M. M. Thackeray, Solid State Ion. 62, 297 (1993).

    Article  Google Scholar 

  4. G. Pistoia, S. Panero, M. Tocci, R. V. Moshtev and V. Manev, Solid State Ion. 13, 311 (1984).

    Article  CAS  Google Scholar 

  5. K. Kirshenbaum, D. C. Bock, C.-Y. Lee, Z. Zhong, K. J. Takeuchi, A. C. Marschilok and E. S. Takeuchi, Science, 347, 149 (2015).

    Article  CAS  Google Scholar 

  6. K. C. Kirshenbaum, D. C. Bock, A. B. Brady, A. C. Marschilok, K. J. Takeuchi and E. S. Takeuchi, Phys. Chem. Chem. Phys. 17, 11204 (2015).

    Article  CAS  Google Scholar 

  7. J. W. Gallaway, M. Menard, B. Hertzberg, Z. Zhong, M. Croft, L. A. Sviridov, D. E. Turney, S. Banerjee, D. A. Steingart and C. K. Erdonmez, J. Electrochem. Soc 162, A162 (2015).

    Article  CAS  Google Scholar 

  8. G. Liang, M. Croft and Z. Zhong, ECS Trans. 50, 293 (2013).

    Article  Google Scholar 

  9. W. A. Paxton, Z. Zhong and T. Tsakalakos, J. Power Sources 275, 429 (2015).

    Article  CAS  Google Scholar 

  10. F. C. Strobridge, B. Orvananos, M. Croft, H.-C. Yu, R. Robert, H. Liu, Z. Zhong, T. Connolley, M. Drakopoulos, K. Thornton and C. P. Grey, Chem. Mater. 27, 2374 (2015).

    Article  CAS  Google Scholar 

  11. A. C. Marschilok, C. P. Schaffer, K. J. Takeuchi and E. S. Takeuchi, J. Compos. Mater. 47, 41 (2013).

    Article  CAS  Google Scholar 

  12. S. Jouanneau, A. Verbaere and D. Guyomard, J. Solid State Chem. 178, 22 (2005).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Materials Science and Chemical Engineering, Stony Brook University, 11794, Stony Brook, NY, USA

    Qing Zhang, Jing Li, Esther S. Takeuchi, Kenneth J. Takeuchi & Amy C. Marschilok

  2. Department of Chemistry, Stony Brook University, 11794, Stony Brook, NY, USA

    Andrea M. Bruck, Esther S. Takeuchi, Kenneth J. Takeuchi & Amy C. Marschilok

  3. Energy Sciences Directorate, Brookhaven National Laboratory, 11973, Upton, NY, USA

    David C. Bock & Esther S. Takeuchi

  4. Center for Functional Nanomaterials, Brookhaven National Laboratory, 11973, Upton, NY, USA

    Eric A. Stach

Authors
  1. Qing Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Andrea M. Bruck
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. David C. Bock
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jing Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Eric A. Stach
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Esther S. Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Kenneth J. Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Amy C. Marschilok
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Esther S. Takeuchi, Kenneth J. Takeuchi or Amy C. Marschilok.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, Q., Bruck, A.M., Bock, D.C. et al. Energy Dispersive X-ray Diffraction (EDXRD) of Li1.1V3O8 Electrochemical Cell. MRS Advances 2, 401–406 (2017). https://doi.org/10.1557/adv.2017.54

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/adv.2017.54

Search

Navigation