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ZnO-CuO core-shell heterostructure for improving the efficiency of ZnO-based dye-sensitized solar cells

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Abstract

In this work, the integration of ZnO-CuO core-shell nanostructures shows improvement in the conversion efficiency of ZnO-based dye-sensitized solar cells (DSSCs). This is due to CuO acting as a secondary absorption layer that allows the absorption of near-infrared (NIR) light increasing the generated photocurrent in the device, and as a blocking layer that reduces electron-hole recombination. The ZnO core and encapsulating CuO shell are synthesized through chemical vapor deposition (CVD), and thermal oxidation of a Cu seed layer, respectively. The crystallinity of the synthesized ZnO and CuO is analyzed by X-ray diffraction (XRD). Scanning electron microscope (SEM) images show the change in morphology through the steps of Cu seed layer deposition and thermal oxidation of this layer. To determine optical properties of CuO on ZnO nanorods, UV-Vis-NIR photospectrocopy is used. The comparison of conversion efficiency of DSSCs using two different photoelectrodes (i.e. ZnO nanorods versus ZnO-CuO core-shell nanostructure) is performed by I-V measurements.

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References

  1. Martin I. Hoffert, Ken Caldeira, Atul K. Jain, Erik F. Haites, L. D. Danny Harveyk, Seth D. Potter, Michael E. Schlesinger, Stephen H. Schneider, Robert G. Watts, Tom M. L. Wigley, and Donald J. Wuebbles, Nature, 395, 881–884 (1998)

    Article  CAS  Google Scholar 

  2. J. Blanco, S. Malato, P. Fernández-Ibañez, D. Alarcón, W. Gernjak, and M.I. Maldonado, Renew. Sust. Energ. Rev., 13, 1437–1445 (2009)

    Article  CAS  Google Scholar 

  3. Matthew Wrigh, and Ashraf Uddin, Sol. Energ. Mat. Sol. C., 107, 87–111 (2012)

    Article  Google Scholar 

  4. Shufang Zhang, Xudong Yang, Youhei Numata, and Liyuan Han, Energy Environ. Sci., 6, 1443–1464 (2013)

    Article  Google Scholar 

  5. Liyaun Han, Ashraful Islam, Han Chen, Chandrasekharam Malapaka, Barreddi Chiranjeevi, Shufang Zhang, Xudong Yang, and Masatoshi Yanagida, Energy Environ, Sci., 5, 6057–6060 (2012)

    Article  CAS  Google Scholar 

  6. Oana Carp, AlinaTirsoaga, Bogdan Jurca, Ramona Ene, Simona Somacescu, and Adelina Ianculescu, Carbohyd. Polym., 115, 285–293 (2015)

    Article  CAS  Google Scholar 

  7. H. Cao, J. Y. Xu, D. Z. Zhang, S.-H. Chang, S. T. Ho, E. W. Seelig, X. Liu, and R. P. H. Chang, Phys. Rev. Lett., 84, 5584–5587 (2000)

    Article  CAS  Google Scholar 

  8. Dangxin Wu, Qiming Zhang and Meng Tao, Phys. Rev. B, 73, 235206 (2006)

    Article  Google Scholar 

  9. Michael Grä1tzel, Inorg. Chem., 44, 6841-6851 (2005)

    Article  Google Scholar 

  10. Michael Woodhouse and B. A. Parkinson, Chem. Soc. Rev., 38, 197–210 (2009)

    Article  CAS  Google Scholar 

  11. Samantha S. Wilson, Jeffrey P. Bosco, Yulia Tolstova, David 0. Scanlon, Graeme W. Watson and Harry A. Atwater, Energy Environ. Sci., 7, 3606–3610 (2014)

    Article  CAS  Google Scholar 

  12. Phathaitep Raksa, Sanpet Nilphai, Atcharawon Gardchareon, Supab Choopun, Thin Solid Films, 517, 4741–4744 (2009)

    Article  CAS  Google Scholar 

  13. R. Sahay, J. Sundaramurthy, P. Suresh Kumar, V. Thavasi, S. G. Mhaisalkar, S. Ramakrishna J. Solid State Chem., 186, 261–267 (2012)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical and Environmental Engineering, University of California, Riverside, California, 92507, U.S.A.

    Kichang Jung

  2. Materials Science and Engineering Program, University of California, Riverside, California, 92507, U.S.A.

    Taehoon Lim & Alfredo A. Martinez-Morales

  3. Southern California Research Initiative for Solar Energy, University of California, Riverside, California, 92507, U.S.A.

    Kichang Jung, Taehoon Lim, Yaqiong Li & Alfredo A. Martinez-Morales

Authors
  1. Kichang Jung
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  2. Taehoon Lim
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  3. Yaqiong Li
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  4. Alfredo A. Martinez-Morales
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Jung, K., Lim, T., Li, Y. et al. ZnO-CuO core-shell heterostructure for improving the efficiency of ZnO-based dye-sensitized solar cells. MRS Advances 2, 857–862 (2017). https://doi.org/10.1557/adv.2017.247

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  • DOI: https://doi.org/10.1557/adv.2017.247

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