Skip to main content
Log in

Nuclear Magnetic Resonance Spectroscopy of Geological Materials

  • Earth Materials
  • Published:
MRS Bulletin Aims and scope Submit manuscript

Conclusions

As in some areas of research on technological materials, NMR spectroscopy is beginning to be an important method in studying geological materials. It can provide unique information on local structure that is essential in understanding energies, entropies, and densities of crystalline, amorphous, and liquid phases over the wide ranges of pressures and temperatures found in the Earth. Dynamical information from NMR is beginning to play a major role in understanding mechanisms of diffusion, phase transitions, and viscosity. High-resolution, high-temperature NMR offers especially exciting possibilities for greatly extending our knowledge of mass transport in both liquids and solids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.A. Wilson, NMR Techniques and Applications in Geochemistry and Soil Chemistry (Pergamon, Oxford, 1987).

    Google Scholar 

  2. G. Engelhardt and D. Michel, High-Resolution Solid-State NMR of Silicates and Zeolites (Wiley, New York, 1987).

    Google Scholar 

  3. C.A. Fyfe, Solid State NMR for Chemists (CFC Press, Guelph, 1983).

    Google Scholar 

  4. R.J. Kirkpatrick, T. Dunn, S. Schramm, K.A. Smith, R. Oestrike, and G. Turner, in Structure and Bonding in Noncrystalline Solids, edited by G.E. Wolrafen and A.G. Revesz (Plenum Press, New York, 1986) p. 302.

    Google Scholar 

  5. R.J. Kirkpatrick, in Spectroscopic Methods in Mineralogy and Geology, edited by F.C. Hawthorne (Mineralogical Society of America, Washington, DC) p. 341.

  6. H. Eckert, Ber. Bunsenges Phys. Chem.94 (1990) p. 1062.

    Article  CAS  Google Scholar 

  7. J.F. Stebbins, in Spectroscopic Methods in Mineralogy and Geology, edited by F.C. Hawthorne (Mineralogical Society of America, Washington, DC) p. 405.

  8. J.F. Stebbins, Chem. Rev. 91 (1991) p. 1353.

    Article  CAS  Google Scholar 

  9. J.A. Tossell, J. Non-Cryst. Solids 120 (1990) p. 13.

    Article  CAS  Google Scholar 

  10. R.R. Holmes, Chem. Rev. 90 (1990) p. 17.

    Article  CAS  Google Scholar 

  11. J.F. Stebbins and P. McMillan, Am. Mineral. 74 (1989) p. 965.

    CAS  Google Scholar 

  12. X. Xue, J.F. Stebbins, M. Kanzaki, and R.G. Tronnes, Science 245 (1989) p. 962.

    Article  CAS  Google Scholar 

  13. X. Xue, J.F. Stebbins, M. Kanzaki, P.R. McMillan, and B. Poe, Am. Mineral. 76 (1991) p. 8.

    CAS  Google Scholar 

  14. M. Kanzaki, J.F. Stebbins, and X. Xue, Geophys. Res. Lett. 18 (1990) p. 463.

    Article  Google Scholar 

  15. A.-R. Grimmer, W. Wieker, F. von Lampe, E. Fechner, R. Peter, and G. Molgedey, Z. Chem. 20 (1980) p. 453.

    Article  CAS  Google Scholar 

  16. S. Brawer, Relaxation in Viscous Liquids and Glasses (American Ceramic Society, Columbus, OH, 1985).

    Google Scholar 

  17. C.A. Angell, P.A. Cheeseman, and S. Tamaddon, Bull. Minéral. 106 (1983) p. 87.

    Article  CAS  Google Scholar 

  18. J.F. Stebbins, Nature 351 (1991) p. 638.

    Article  CAS  Google Scholar 

  19. R.K. Sato, P.F. McMillan, P. Dennison, and R. Dupree, J. Phys. Chem. 95 (1991) p. 4484.

    Google Scholar 

  20. R.K. Sato, P.F. McMillan, P. Dennison, and R. Dupree, Phys. Chem. Glasses 32 (1991) p. 149.

    CAS  Google Scholar 

  21. B.C. Bunker, R.J. Kirkpatrick, R.K. Brow, G.L. Turner, and C. Nelson, J. Am. Ceram. Soc. 74 (1991) p. 1430.

    Article  CAS  Google Scholar 

  22. J.F. Stebbins, I. Farnan, and U. Klabunde, J. Am. Ceram. Soc. 11 (1989) p. 2198.

    Article  Google Scholar 

  23. W.-H. Yang, R.J. Kirkpatrick, and D.M. Henderson, Am. Mineral. 71 (1986) p. 712.

    CAS  Google Scholar 

  24. B.L. Sheriff and J.S. Hartman, Can. Mineral. 23 (1985) p. 205.

    Google Scholar 

  25. C.A. Weiss Jr., S.P. Altaner, and R.J. Kirkpatrick, Am. Mineral. 72 (1987) p. 935.

    CAS  Google Scholar 

  26. S. Circone, A. Navrotsky, R.J. Kirkpatrick, and C.M. Graham, Am. Mineral. 76 (1991) p. 1485.

    CAS  Google Scholar 

  27. A. Putnis, E. Salje, S.A.T. Redfern, C.A. Fyfe, and H. Strobl, Phys. Chem. Minerals 14 (1987) p. 446.

    Article  CAS  Google Scholar 

  28. R. Oestrike, W.-H. Yang, R.J. Kirkpatrick, R.L. Hervig, A. Navrotsky, and B. Montez, Geochim. Cosmochim. Acta 51 (1987) p. 2199.

    Article  CAS  Google Scholar 

  29. N.M. Rose and D.K. Bird, J. Petrol. 28 (1987) p. 1193.

    Article  CAS  Google Scholar 

  30. J.J. Papike and T. Zoltai, Am. Mineral. 52 (1967) p. 974.

    Google Scholar 

  31. D.K. Bird and H.C. Helgeson, Am. J. Sci. 280 (1980) p. 907.

    Article  CAS  Google Scholar 

  32. H.C. Helgeson, J.M. Delaney, H.W. Nesbitt, and D.K. Bird, Am. J. Science 278-A (1978) 229 pages.

  33. D. Ill, E.F. Westrum Jr., and E.J. Essene, Geochim. Cosmochim. Acta 44 (1980) p. 61.

    Article  Google Scholar 

  34. J.G. Liou, Am. Mineral. 56 (1972) p. 507.

    Google Scholar 

  35. S. Ghose and T. Tsang, Am. Mineral. 58 (1973) p. 748.

    CAS  Google Scholar 

  36. B.F. Chmelka, K.T. Mueller, A. Pines, J.F. Stebbins, Y. Wu, and J.W. Zwanziger, Nature 339 (1989) p. 42.

    Article  CAS  Google Scholar 

  37. K.T. Mueller, Y. Wu, B.F. Chmelka, J.F. Stebbins, and A. Pines, J. Am. Chem. Soc. 113 (1990) p. 32.

    Article  Google Scholar 

  38. J. Baltisberger, P. Grandinetti, M. Eastman, A. Pines, I. Farnan, and J.F. Stebbins, EOS, Trans. Am. Geophys. Union 72 (1991) p. 572.

    Google Scholar 

  39. J.F. Stebbins and I. Farnan, Science 255 (1992) p. 586.

    Article  CAS  Google Scholar 

  40. R. Dupree, D. Holland, and D.S. Williams, J. Non-Cryst. Solids 81 (1986) p. 185.

    Article  CAS  Google Scholar 

  41. R. Dupree, D. Holland, and M.G. Mortuza, J. Non-Cryst. Solids 116 (1990) p. 148.

    Article  CAS  Google Scholar 

  42. H. Maekawa, T. Maekawa, K. Kawamura, and T. Yokokawa, J. Non-Cryst. Solids 127 (1991) p. 53.

    Article  CAS  Google Scholar 

  43. J.B. Murdoch, J.F. Stebbins, and I.S.E. Carmichael, Am. Mineral. 70 (1985) p. 332.

    CAS  Google Scholar 

  44. M.E. Brandriss and J.F. Stebbins, Geochim. Cosmochim. Acta 52 (1988) p. 2659.

    Article  CAS  Google Scholar 

  45. P.F. McMillan, G.H. Wolf, and B.T. Poe, Chem. Geol. (in press).

  46. B.O. Mysen, J. Geophys. Res. 95 (1990) p. 15733.

    Article  Google Scholar 

  47. P.H. Gaskell, M.C. Eckersley, A.C. Barnes, and P. Chieux, Nature 350 (1991) p. 675.

    Article  CAS  Google Scholar 

  48. E.M. Stolper, Geochim. Cosmochim. Acta 46 (1982) p. 2609.

    Article  CAS  Google Scholar 

  49. S.C. Kohn, R. Dupree, and M.E. Smith, Geochim. Cosmochim. Acta 53 (1989) p. 2925.

    Article  CAS  Google Scholar 

  50. I. Farnan, S.C. Kohn, and R. Dupree, Geochim. Cosmochim. Acta 51 (1987) p. 2869.

    Article  CAS  Google Scholar 

  51. L. Merwin, H. Keppler, and A. Sebald, EOS, Trans. Am. Geophys. Union 72 (1991) p. 573.

    Google Scholar 

  52. W.-H. Yang and R.J. Kirkpatrick, Geochim. Cosmochim. Acta 53 (1989) p. 805.

    Article  CAS  Google Scholar 

  53. D. Massiot, F. Taulelle, and J.P. Coutures, Colloq. Phys 51 (1991) C5–425.

    Google Scholar 

  54. F. Taulelle, J.P. Coutures, D. Massiot, and J.P. Rifflet, Bull. Magn. Reson. 11 (1989) p. 318.

    CAS  Google Scholar 

  55. I. Farnan and J.F. Stebbins, J. Am. Chem. Soc. 112 (1990) p. 32.

    Article  CAS  Google Scholar 

  56. J.F. Stebbins, I. Farnan, and X. Xue, Chem. Geol. (in press).

  57. I. Farnan and J.F. Stebbins, J. Non-Cryst. Solids 124 (1990) p. 207.

    Article  CAS  Google Scholar 

  58. A. Rigamonti, Adv. Phys. 33 (1984) p. 115.

    Article  CAS  Google Scholar 

  59. J.F. Stebbins, I. Farnan, E.H. Williams, and J. Roux, Phys. Chem. Minerals 16 (1989) p. 763.

    Article  CAS  Google Scholar 

Download references

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stebbins, J.F. Nuclear Magnetic Resonance Spectroscopy of Geological Materials. MRS Bulletin 17, 45–52 (1992). https://doi.org/10.1557/S0883769400041282

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/S0883769400041282

Navigation