Conclusions
As in some areas of research on technological materials, NMR spectroscopy is beginning to be an important method in studying geological materials. It can provide unique information on local structure that is essential in understanding energies, entropies, and densities of crystalline, amorphous, and liquid phases over the wide ranges of pressures and temperatures found in the Earth. Dynamical information from NMR is beginning to play a major role in understanding mechanisms of diffusion, phase transitions, and viscosity. High-resolution, high-temperature NMR offers especially exciting possibilities for greatly extending our knowledge of mass transport in both liquids and solids.
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References
M.A. Wilson, NMR Techniques and Applications in Geochemistry and Soil Chemistry (Pergamon, Oxford, 1987).
G. Engelhardt and D. Michel, High-Resolution Solid-State NMR of Silicates and Zeolites (Wiley, New York, 1987).
C.A. Fyfe, Solid State NMR for Chemists (CFC Press, Guelph, 1983).
R.J. Kirkpatrick, T. Dunn, S. Schramm, K.A. Smith, R. Oestrike, and G. Turner, in Structure and Bonding in Noncrystalline Solids, edited by G.E. Wolrafen and A.G. Revesz (Plenum Press, New York, 1986) p. 302.
R.J. Kirkpatrick, in Spectroscopic Methods in Mineralogy and Geology, edited by F.C. Hawthorne (Mineralogical Society of America, Washington, DC) p. 341.
H. Eckert, Ber. Bunsenges Phys. Chem.94 (1990) p. 1062.
J.F. Stebbins, in Spectroscopic Methods in Mineralogy and Geology, edited by F.C. Hawthorne (Mineralogical Society of America, Washington, DC) p. 405.
J.F. Stebbins, Chem. Rev. 91 (1991) p. 1353.
J.A. Tossell, J. Non-Cryst. Solids 120 (1990) p. 13.
R.R. Holmes, Chem. Rev. 90 (1990) p. 17.
J.F. Stebbins and P. McMillan, Am. Mineral. 74 (1989) p. 965.
X. Xue, J.F. Stebbins, M. Kanzaki, and R.G. Tronnes, Science 245 (1989) p. 962.
X. Xue, J.F. Stebbins, M. Kanzaki, P.R. McMillan, and B. Poe, Am. Mineral. 76 (1991) p. 8.
M. Kanzaki, J.F. Stebbins, and X. Xue, Geophys. Res. Lett. 18 (1990) p. 463.
A.-R. Grimmer, W. Wieker, F. von Lampe, E. Fechner, R. Peter, and G. Molgedey, Z. Chem. 20 (1980) p. 453.
S. Brawer, Relaxation in Viscous Liquids and Glasses (American Ceramic Society, Columbus, OH, 1985).
C.A. Angell, P.A. Cheeseman, and S. Tamaddon, Bull. Minéral. 106 (1983) p. 87.
J.F. Stebbins, Nature 351 (1991) p. 638.
R.K. Sato, P.F. McMillan, P. Dennison, and R. Dupree, J. Phys. Chem. 95 (1991) p. 4484.
R.K. Sato, P.F. McMillan, P. Dennison, and R. Dupree, Phys. Chem. Glasses 32 (1991) p. 149.
B.C. Bunker, R.J. Kirkpatrick, R.K. Brow, G.L. Turner, and C. Nelson, J. Am. Ceram. Soc. 74 (1991) p. 1430.
J.F. Stebbins, I. Farnan, and U. Klabunde, J. Am. Ceram. Soc. 11 (1989) p. 2198.
W.-H. Yang, R.J. Kirkpatrick, and D.M. Henderson, Am. Mineral. 71 (1986) p. 712.
B.L. Sheriff and J.S. Hartman, Can. Mineral. 23 (1985) p. 205.
C.A. Weiss Jr., S.P. Altaner, and R.J. Kirkpatrick, Am. Mineral. 72 (1987) p. 935.
S. Circone, A. Navrotsky, R.J. Kirkpatrick, and C.M. Graham, Am. Mineral. 76 (1991) p. 1485.
A. Putnis, E. Salje, S.A.T. Redfern, C.A. Fyfe, and H. Strobl, Phys. Chem. Minerals 14 (1987) p. 446.
R. Oestrike, W.-H. Yang, R.J. Kirkpatrick, R.L. Hervig, A. Navrotsky, and B. Montez, Geochim. Cosmochim. Acta 51 (1987) p. 2199.
N.M. Rose and D.K. Bird, J. Petrol. 28 (1987) p. 1193.
J.J. Papike and T. Zoltai, Am. Mineral. 52 (1967) p. 974.
D.K. Bird and H.C. Helgeson, Am. J. Sci. 280 (1980) p. 907.
H.C. Helgeson, J.M. Delaney, H.W. Nesbitt, and D.K. Bird, Am. J. Science 278-A (1978) 229 pages.
D. Ill, E.F. Westrum Jr., and E.J. Essene, Geochim. Cosmochim. Acta 44 (1980) p. 61.
J.G. Liou, Am. Mineral. 56 (1972) p. 507.
S. Ghose and T. Tsang, Am. Mineral. 58 (1973) p. 748.
B.F. Chmelka, K.T. Mueller, A. Pines, J.F. Stebbins, Y. Wu, and J.W. Zwanziger, Nature 339 (1989) p. 42.
K.T. Mueller, Y. Wu, B.F. Chmelka, J.F. Stebbins, and A. Pines, J. Am. Chem. Soc. 113 (1990) p. 32.
J. Baltisberger, P. Grandinetti, M. Eastman, A. Pines, I. Farnan, and J.F. Stebbins, EOS, Trans. Am. Geophys. Union 72 (1991) p. 572.
J.F. Stebbins and I. Farnan, Science 255 (1992) p. 586.
R. Dupree, D. Holland, and D.S. Williams, J. Non-Cryst. Solids 81 (1986) p. 185.
R. Dupree, D. Holland, and M.G. Mortuza, J. Non-Cryst. Solids 116 (1990) p. 148.
H. Maekawa, T. Maekawa, K. Kawamura, and T. Yokokawa, J. Non-Cryst. Solids 127 (1991) p. 53.
J.B. Murdoch, J.F. Stebbins, and I.S.E. Carmichael, Am. Mineral. 70 (1985) p. 332.
M.E. Brandriss and J.F. Stebbins, Geochim. Cosmochim. Acta 52 (1988) p. 2659.
P.F. McMillan, G.H. Wolf, and B.T. Poe, Chem. Geol. (in press).
B.O. Mysen, J. Geophys. Res. 95 (1990) p. 15733.
P.H. Gaskell, M.C. Eckersley, A.C. Barnes, and P. Chieux, Nature 350 (1991) p. 675.
E.M. Stolper, Geochim. Cosmochim. Acta 46 (1982) p. 2609.
S.C. Kohn, R. Dupree, and M.E. Smith, Geochim. Cosmochim. Acta 53 (1989) p. 2925.
I. Farnan, S.C. Kohn, and R. Dupree, Geochim. Cosmochim. Acta 51 (1987) p. 2869.
L. Merwin, H. Keppler, and A. Sebald, EOS, Trans. Am. Geophys. Union 72 (1991) p. 573.
W.-H. Yang and R.J. Kirkpatrick, Geochim. Cosmochim. Acta 53 (1989) p. 805.
D. Massiot, F. Taulelle, and J.P. Coutures, Colloq. Phys 51 (1991) C5–425.
F. Taulelle, J.P. Coutures, D. Massiot, and J.P. Rifflet, Bull. Magn. Reson. 11 (1989) p. 318.
I. Farnan and J.F. Stebbins, J. Am. Chem. Soc. 112 (1990) p. 32.
J.F. Stebbins, I. Farnan, and X. Xue, Chem. Geol. (in press).
I. Farnan and J.F. Stebbins, J. Non-Cryst. Solids 124 (1990) p. 207.
A. Rigamonti, Adv. Phys. 33 (1984) p. 115.
J.F. Stebbins, I. Farnan, E.H. Williams, and J. Roux, Phys. Chem. Minerals 16 (1989) p. 763.
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Stebbins, J.F. Nuclear Magnetic Resonance Spectroscopy of Geological Materials. MRS Bulletin 17, 45–52 (1992). https://doi.org/10.1557/S0883769400041282
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DOI: https://doi.org/10.1557/S0883769400041282