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Aqueous Surface Chemistry and Corrosion of Minerals

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Conclusions

The interactions of solutes with mineral surfaces are central to models of natural mineral corrosion rates and for predictions about the migration rates of contaminants in groundwater. Because of the scale of geologic processes, these predictions must span many decades and potentially large variations in natural chemistry. If these predictions are to gain credibility, details of the reactions must be confirmed at a fine scale. With new methods of surface analysis, important assumptions in the models can be independently verified. The results so far have often confirmed longheld opinions about the control of mineral dissolution and growth, such as the importance of surface microtopography, and have uncovered wholly new phenomena, as well.

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References

  1. J.I. Drever, The Geochemistry of Natural Waters, 2nd ed. (Prentice-Hall, 1988) p. 269.

  2. V. Pye, and J. Kelley, Chapter 1 in Groundwater Contamination (National Academy Press, Washington, DC, 1984).

    Google Scholar 

  3. L.G.J. Fokkink, PhD thesis, Wageningen University, 1987.

  4. G.A. Parks, in Reviews in Mineralogy #23: Mineral-Water Interface Geochemistry; edited by M.F. Hochella and A.F. White (Mineralogical Society of America, Washington, DC, 1991), p. 133–175; J.A. Davis, and J.A. and D.B. Kent, ibid., p. 177–260.

    Google Scholar 

  5. V.S. Tripathi, PhD thesis, Stanford University, 1983.

  6. R.G. Wilkens, The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes (Allyn and Bacon, Boston, 1974) p. 81.

    Google Scholar 

  7. A. Blum and A.C. Lasaga, Nature331 (1988) p. 431.

    Article  CAS  Google Scholar 

  8. W.H. Casey, J. Colloid Interf. Sci.146 (1991) p. 586.

    Article  CAS  Google Scholar 

  9. G.E. Brown, in Reviews in Mineralogy #5: Orthosilicates, edited by P. Ribbe (Mineralogical Society of America, Washington, DC, 1982), p. 275.

    Chapter  Google Scholar 

  10. J. Burgess, Ions in Solution (John Wiley, New York, 1988) p. 40.

    Google Scholar 

  11. W.H. Casey and H.R. Westrich, Nature355 (1992) p. 157.

    Article  CAS  Google Scholar 

  12. W.H. Casey, H.R. Westrich, G.W. Arnold, and J.E. Banfield, Geochim. Cosmochim. Acta53 (1989) p. 821.

    Article  CAS  Google Scholar 

  13. J.-C. Petit, J.-C. Dran, and G. Delia Mea, Nature344 (1990) p. 621.

    Article  CAS  Google Scholar 

  14. R. Hellmann, C.M. Eggleston, M.F. Hochella, and D.A. Crerar, Geochim. Cosmochim. Acta54 (1990) p. 1267.

    Article  CAS  Google Scholar 

  15. J.F. Banfield, D.R. Veblen, and B.F. Jones, Contrib. Mineral. Petrol.106 (1990) p. 110.

    Article  CAS  Google Scholar 

  16. I.J. Muir, G.M. Bancroft, and H.W. Nesbitt, Geochim. Cosmochim. Acta53 (1988) p. 1235.

    Article  Google Scholar 

  17. M.F. Hochella Jr., in Reviews in Mineralogy #23: Mineral-Water Interface Geochemistry, edited by M.F. Hochella and A.F. White (Mineralogical Society of America, Washington, DC, 1990) p. 87.

    Chapter  Google Scholar 

  18. G.E. Brown, in Reviews in Mineralogy #23: Mineral-Water Interface Geochemistry, edited by M.F. Hochella and A.F. White (Mineralogical Society of America, Washington, DC, 1990) p. 309.

    Chapter  Google Scholar 

  19. K.F. Hayes, A.L. Roe, G.E. Brown, K.O. Hodgson, J.O. Leckie, and G.A. Parks, Science238 (1987) p. 783.

    Article  CAS  Google Scholar 

  20. C.M. Eggleston, M.F. Hochella Jr., and G.A. Parks (1990) Geological Society of America Abst. with Programs, A292.

  21. P.A. Johnsson, C.M. Eggleston, and M.E. Hochella Jr., American Mineral.76 (1991) p. 1443.

    Google Scholar 

  22. A.J. Gratz, S. Manne, and P.K. Hansma, Science251 (1991) p. 1343.

    Article  CAS  Google Scholar 

  23. P.E. Hillner, A.J. Gratz, S. Manne, and P.K. Hansma, Geology (1992) (submitted).

  24. M.F. Hochella Jr., C.M. Eggleston, V.B. Elings, and M. Thompson, American Mineral.75 (1990) p. 723.

    CAS  Google Scholar 

  25. H. Hartman, G. Sposito, A. Yang, S. Manne, S.A.C. Gould, and P.K. Hansma, Clays Clay Minerals38 (1990) p. 337.

    Article  CAS  Google Scholar 

  26. H. Lindgreen, J. Garnaes, P.L. Hansen, F. Besenbacher, E. Laegsgaard, I. Stensgaard, S.A. Gould, and P.K. Hansma, American Mineral.76 (1991) p. 1218.

    CAS  Google Scholar 

  27. A.L. Weisenhorn, J.E. MacDougall, S.A. Gould, S.D. Cox, W.S. Wise, J. Massie, P. Maivald, V.B. Elings, G.D. Stucky, and P.K. Hansma, Science247 (1990) p. 1330.

    Article  CAS  Google Scholar 

  28. C.M. Eggleston, and M.F. Hochella Jr., Geochim. Cosmochim. Acta54 (1990) p. 1511.

    Article  CAS  Google Scholar 

  29. C.M. Eggleston, and M.F. Hochella Jr., Science254 (1991) p. 983.

    Article  CAS  Google Scholar 

Download references

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Casey, W.H., Eggleston, C., Johnsson, P.A. et al. Aqueous Surface Chemistry and Corrosion of Minerals. MRS Bulletin 17, 23–29 (1992). https://doi.org/10.1557/S0883769400041245

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