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Aqueous Alteration of Nuclear Waste Glasses and Metal Package Components

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Abstract

Based on all data currently available, immobilization of potentially hazardous radionuclides in borosilicate glass will result in a product of good chemical durability. Appropriately selected metal alloy containers can also prevent any degradation of the waste glass for an appreciable length of time. Burial of the waste glass products, as part of a multibarrier isolation system within a geologic environment, will provide an effective system, not simply to store high-level radioactive waste, but also to permanently dispose of it.

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References

  1. G.G. Wicks, in Treatise on Materials Science and Technology, Glass IV 26, edited by M. Tomozawa and R.H. Doremus (Academic Press, Orlando, FL, 1985) p. 57.

  2. G.G. Wicks and D.F. Bickford, High Level Radioactive Waste—Doing Something About It, DP-1777 (Savannah River Laboratory, Aiken, SC, 1989).

    Google Scholar 

  3. D.R. Uhlmann, in Ceramic and Glass Radioactive Waste Forms, CONF-770102, (Energy Research and Development Administration, 1977) p. 121.

    Google Scholar 

  4. J.E. Mendel, A Review of Leaching Test Methods and the Leachability of Various Solid Media Containing Radioactive Wastes, BNWL-1765 (Pacific Northwest Laboratory, Richland, WA, 1973).

    Book  Google Scholar 

  5. G.G. Wicks, J. Non-Cryst. Solids 84 (1986) p. 241.

    Article  CAS  Google Scholar 

  6. G.G. Wicks, in Corrosion of Glass, Ceramics, and Ceramic Superconductors, edited by D.E Clark and B.K. Zoitos (Noyes Publications, Park Ridge, NJ, 1992) p. 218.

  7. D.E. Clark, C.G. Pantano, and L.L. Hench, Corrosion of Glass (Magazines for Industry Inc., New York, 1979).

    Google Scholar 

  8. G.G. Wicks and M.A. Molecke, in Advances in Ceramics: Nuclear Waste Management II, edited by D.E. Clark, W.B. White, and A.J. Machiels (Am. Ceram. Soc. Symp. Proc. 20, Westerville, OH, 1986) p. 657.

    CAS  Google Scholar 

  9. G.G. Wicks and M.A. Molecke, presented at the Environmental and Waste Management Issues in the Ceramic Industry Symposium, American Ceramic Society, April 19–22, 1993, Cincinnati, OH, to be published in proceedings (1993).

    Google Scholar 

  10. Testing of High-Level Waste Forms Under Repository Conditions, edited by T. McMenamin, Proceedings of Workshop in Cadarache, France, October 17–21, 1988, EUR 12017 EN, Commission of the European Communities (1989).

    Google Scholar 

  11. Testing of High-Level Waste Forms and Package Components, edited by T. McMenamin, Proceedings of Workshop in Corsendonk, Belgium, October 10–17, 1992, Commission of the European Communities, in press (1993).

    Google Scholar 

  12. M.S. Jercinovic, S. Kaser, and R.C. Ewing, in Testing of High-Level Waste Forms Under Repository Conditions, EUR 12017 EN, edited by T. McMenamin, Commission of the European Communities Workshop Proc. (1989) p. 183.

  13. E. Vernaz and N. Godon, in Testing of High-Level Waste Forms Under Repository Conditions, EUR 12017 EN, edited by T. McMenamin, Commission of the European Communities Workshop Proc. (1989) p. 81.

  14. A.B. Harker, J.F. Flintoff, and D.G. Howitt, in Testing of High-Level Waste Forms Under Repository Conditions, EUR 12017 EN, edited by T. McMenamin, Commission of the European Communities Workshop Proc. (1989) p. 152.

  15. G.G. Wicks, A.R. Lodding, P.B. Macedo, and D.E. Clark, in Scientific Basis for Nuclear Waste Management XV, edited by C.G. Sombret (Mater. Res. Soc. Symp. Proc. 257, Pittsburgh, PA, 1992) p. 119.

    Article  CAS  Google Scholar 

  16. J.A. Tacca and G.G. Wicks, in Ceramic Transactions: Nuclear Waste Management III, edited by G.B. Mellinger (Am. Ceram. Soc. Symp. Proc. 9, Westerville, OH, 1990) p. 271.

    CAS  Google Scholar 

  17. D.E Clark, presented at the Workshop on Testing of High-Level Waste Forms and Package Components, Corsendonk, Belgium, October 10–17, 1992, Commission of the European Communities, to be published (1993).

    Google Scholar 

  18. A.R. Lodding, E.U. Engstrom, D.E. Clark, and G.G. Wicks, in Ceramic Transactions: Nuclear Waste Management III, edited by G.B. Mellinger (Am. Ceram. Soc. Symp. Proc. 9, Westerville, OH, 1990) p. 317.

    CAS  Google Scholar 

  19. A.R. Lodding, D.E. Clark, E.U. Engström, H. Odelius, M. Schumacher, G.G. Wicks, and B.K. Zoitos, in Ceramics Today—Tomorrow’s Ceramics, edited by P. Vincenzini (Elsevier, New York, 1991) p. 3121.

  20. A.R. Lodding, presented at the Workshop on Testing of High-Level Waste Forms and Package Components, Corsendonk, Belgium, October 10–17, 1992, Commission of the European Communities, in press (1993).

    Google Scholar 

  21. R.E. Sassoon, M. Gong, M. Brandys, M. Adel-Hadadi, A. Barkatt, and P.B. Macedo, in Ceramic Transactions: Nuclear Waste Management III, edited by G.B. Mellinger (Am. Ceram. Soc. Symp. Proc. 9, Westerville, OH, 1990) p. 307.

    CAS  Google Scholar 

  22. M. Brandys, M. Gong, R.E. Sassoon, A. Barkatt, and P.B. Macedo, in Ceramic Transactions: Nuclear Waste Management III, edited by G.B. Mellinger (Am. Ceram. Soc. Symp. Proc. 9, Westerville, OH, 1990) p. 287.

    CAS  Google Scholar 

  23. R.M. Wallace and G.G. Wicks, in Scientific-Basis for Nuclear Waste Management VI, edited by D.C. Brookins (Mater. Res. Soc. Symp. Proc. 15, Elsevier, New York, 1983) p. 23.

    CAS  Google Scholar 

  24. C. Pescatore and A.J. Machiels, in Advances in Ceramics, edited by G.G. Wicks and W.A. Ross (Am. Ceram. Soc. Symp. Proc. 8, American Ceramic Society, Columbus, OH, 1984) p. 508.

    CAS  Google Scholar 

  25. P.L. Chambre, C.H. Kang, W.W.L. Lee, and T.H. Pigford, in Scientific Basis for Nuclear Waste Management XI, edited by M.J. Apted and R.E. Westerman (Mater. Res. Soc. Symp. Proc. 112, Pittsburgh, PA, 1987) p. 285.

    Article  Google Scholar 

  26. B. Grambow and D.M. Strachan, in Scientific Basis for Nuclear Waste Management XI, edited by M.J. Apted and R.E. Westerman (Mater. Res. Soc. Symp. Proc. 112, Pittsburgh, PA, 1987) p. 713.

    Article  Google Scholar 

  27. M.J. Plodinec, C.M. Jantzen, and G.G. Wicks, in Advances in Ceramics, G.G. Wicks and W.A. Ross (Am. Ceram. Soc. Symp. Proc. 8, American Ceramic Society, Columbus, OH, 1984) p. 491.

    CAS  Google Scholar 

  28. N.R. Sorensen and M.A. Molecke, presented at the Workshop on Testing of High-Level Waste Forms and Package Components, Corsendonk, Belgium, October 10–17, 1992, Commission of the European Communities, in press (1993).

    Google Scholar 

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Wicks, G.G., Lodding, A.R. & Molecke, M.A. Aqueous Alteration of Nuclear Waste Glasses and Metal Package Components. MRS Bulletin 18, 32–39 (1993). https://doi.org/10.1557/S0883769400038008

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