Abstract
We have measured polarization-dependent Fe K-edge XAFS spectra from an epitaxially-grown Al/Fe/Al/ZnSe/GaAs(001) sample using synchrotron radiation. The Fourier-transformed XAFS spectra were fit up to four coordination shells simultaneously using theoretical spectra generated with FEFF 6. Our results reveal a small tetragonal distortion of the bcc α-Fe film lattice towards a contraction in the film growth direction (c=2.863 Å and a=2.874 Å; bulk α=2.867 Å). The anomalous tetragonal distortion is consistent with a model involving substantial interdifussion of Fe and Al, leading to Fe1-xAlx alloy formation localized in the interface regions.
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Robert, M.A., Carlos, G.J. & Gary, P.A. Investigations on Fe Lattice Strain Relaxation in the Al/Fe/Al Trilayer. MRS Online Proceedings Library 437, 27–32 (1996). https://doi.org/10.1557/PROC-437-27
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DOI: https://doi.org/10.1557/PROC-437-27