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Slowing Down of Molecular Reorientations in [Ni(NH3)6](N03)2

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Abstract

Quasielastic neutron scattering measurements of [Ni(NH3)6](N03)2 were made with two different resolutions of ca. 140 and 30 μeV. The following suggestions are analyzed:

1. The NH3 rotational diffusion model is more adequate than NH3 120° jump model.

2. Some NH3 groups slow down whereas some rotate rapidly.

3. There exists an additional QNS component close to the phase II/phase III transition.

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Authors and Affiliations

  1. Institutt for energiteknikk, Kjeller, Norway

    Tormod Riste & Kaare Otnes

  2. H.Niewodniczański Institute of Nuclear Physics, Kraków, Poland

    Jerzy A. Janik, Jacek Mayer & Jan Krawczyk

  3. Faculty of Chemistry, Jagiellonian University, Kraków, Poland

    Janina M. Janik & Teresa Stanek

Authors
  1. Jerzy A. Janik
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  2. Jacek Mayer
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  3. Jan Krawczyk
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  4. Tormod Riste
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  5. Kaare Otnes
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  6. Janina M. Janik
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  7. Teresa Stanek
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Janik, J.A., Mayer, J., Krawczyk, J. et al. Slowing Down of Molecular Reorientations in [Ni(NH3)6](N03)2. MRS Online Proceedings Library 376, 769–774 (1994). https://doi.org/10.1557/PROC-376-769

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  • DOI: https://doi.org/10.1557/PROC-376-769

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