Abstract
In this paper, we report chemical beam epitaxy (CBE) of GaAs, and for the first time, Arion laser-assisted CBE using triethylgallium (TEGa) and tris-dimethylaminoarsenic (TDMAAs), a safer alternative to arsine. Samples grown at substrate temperatures above 490° C show n-type conduction, while those grown at lower temperatures show p-type conduction. An unintentional doping concentration of n∼lx1016 cm-3 with an electron mobility of 5200 cm2/V.s at 300 K and 16000 cm2/V.s at 77 K have been achieved. These are the best results reported for GaAs grown with TDMAAs. Laser-assisted CBE of GaAs is studied in the substrate temperature range of 240-550°C. There are two different substrate-temperature regions for laser-enhanced growth, 265 to 340°C and 340 to 440°C, which are believed to be caused by different TEGa decomposition mechanisms. The laser-assisted growth with TDMAAs, compared to AS4 or AsH3, shows a wider range of growth enhancement at low substrate temperatures.
Similar content being viewed by others
References
C.R. Abernathy, P. W. Wisk, D. A. Bohling, and G. T. Muhr, Appl. Phys. Lett. 60, 2421 (1992).
C. R. Abernathy, P. W. Wisk, S. J. Pearton, F. Ren, D. A. Bohling, and G. T. Muhr, J. Cryst Growth 124, 64 (1992).
T. Koui, I. Suemune, K. Hamaoka, K. Fujii, A. Kishimoto, Y. Honda, and M. Yamanishi, Extended Abstracts of the 1991 International Conference on Solid State Devices and Materials, Yokohama, 408 (1991).
K. Fujii, I. Suemune, and M. Yamanishi, Appl. Phys. Lett. 61, 2577 (1992).
K. Fujii, I. Suemune, T. Koui, and M. Yamanishi, Appl. Phys. Lett. 60, 1498 (1992).
G. Zimmermann, H. Protzmann, T. Marschner, O. Zsebök, W. Stolz, E. O. Göbel, P. Gimmnich, J. Lorberth, T. Filz, P. Kurpas, and W. Richter, J. Cryst. Growth 129, 37 (1993).
Y. Aoyagi, M. Kanazawa, A. Doi, S. Iwai and S. Namba, J. Appl. Phys. 60, 3131 (1986).
V. M. Donnelly, C. W. Tu, J. C. Beggy, V. R. McCrary, M. G. Lamont, T. D. Harris, F. A. Baiochi and R. C. Farrow, Appl. Phys. Lett. 52, 1065 (1988).
H. Sugiura, T. Yamada and R. Iga, Jpn. J. Appl. Phys. 29, L1 (1990).
H. K. Dong, B. W. Liang, M. C. Ho, S. Hung and C. W. Tu, J. Cryst. Growth 124, 181 (1992).
D. E. Hill, J. Appl. Phys. 41, 1815 (1970).
C. Hilsum, Electron Lett. 10, 259 (1974).
G. E. Stillman and C. M. Wolfe, Thin Solid Films 31, 69 (1976).
H. Sugiura, R. Iga, and T. Yamada, J. Cryst. Growth 120, 389 (1992).
T. Yamada, R. Iga and H. Sugiura, Jpn. J. Appl. Phys. 28, L1883 (1989).
R. Robertson Jr, T. H. Chiu, W. T. Tsang, and J. E. Cunningham, J. Appl. Phys. 64, 877 (1988).
B. W. Liang and C. W. Tu, Appl. Phys. Lett. 57, 689 (1990).
T. Martin, and C. R. Whitehouse, J. Cryst. Growth 105, 57 (1990).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dong, H.K., Li, N.Y., Tu, C.W. et al. Chemical Beam Epitaxy (CBE) and Laser-Enhanced CBE of GaAs Using Tris-Dimethylaminoarsenic. MRS Online Proceedings Library 340, 173–179 (1994). https://doi.org/10.1557/PROC-340-173
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-340-173