Abstract
Niobium alloys are used in a variety of high-temperature applications ranging from light bulbs to rocket engines and nuclear reactors. The unique physical and chemical properties of these alloys have often dictated that only niobium alloys could fulfill certain application requirements. Compared to other refractory metals, niobium alloys have low density and are very ductile even at cryogenic temperatures. Most niobium alloys are also very resistant to corrosion by acids and liquid alkali metals; however, oxidation resistance at high temperatures is usually catastrophic unless protective coatings are used.
An overview of the commercial high-temperature alloys is presented. Some of the unique properties of these alloys, which require unusual processing methods and equipment, are highlighted. Important physical properties of these alloys are discussed with reference to specific applications. The needs and design restraints of these applications provide valuable insights for those developing other high-temperature materials.
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References
R.G. Frank, “Recent Advances in Columbium Alloys”, Refractory Metal Alloys (Plenum Press, 1968), pp. 325–365.
J.A. Cornie,. “Development of Precipitation Strengthened Columbium Base Alloys,” AFML-TR-71-5, (December, 1971).
T.K. Roche and D.L. Graham, “Development of Oxidation Resistant, High Strength, Columbium Alloys,” AFML-TR-69-344, (January, 1970).
R. Bakish, Conference Proceedings, “Electron Beam Melting and Refining State of the Art 1985,” Library of Congress, ISSN 0740-8706, (November 1985).
R.M. Bonesteel, D.J. Rowcliffe and T.E. Tietz, “Mechanical Properties and Structure of Internally Oxidized Niobium-1% Zirconium Alloy,” TransTIM Vol. 9 Supplement, (1968).
C. C. Wojcik, “Evaluation of Powder Metallurgy Processed Nb-30HF-9W,” MPIF, 1988 International Powder Metallurgy Conference Proceedings, Vol. 19, pp. 187–200.
R. Titran and W. Klopp, “Long Time Creep Behavior of the Niobium Alloy C-103,” NASA TP-1727, (1980).
R. Titran and R. Hall, “High Temperature Creep Behavior of a Columbium Alloy, FS-85,” NASA TN-D-2885, (1965).
R. Titran, “Long-Time Creep Behavior of Nb-lZr Alloy Containing Carbon,” NASA TM-100142, (1986)
C. Wojcik and K. Jordan, Unpublished research, 1992
C. Wojcik and L. Clark, “Design, Analysis, and Testing of Refractory Metal Heat Pipes Using Lithium as the Working Fluid,” AIAA Thermophysics Conference, (June, 1991)
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Wojcik, C.C. Processing, Properties and Applications of High-Temperature Niobium Alloys. MRS Online Proceedings Library 322, 519–530 (1993). https://doi.org/10.1557/PROC-322-519
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DOI: https://doi.org/10.1557/PROC-322-519