Abstract
Results from As K-edge XAFS studies on polysulfone films implanted with 50 KeV As+ in the dose range of 1015 to 1016 ions/cm2 indicate that As reacts chemically with O atoms to form As-(3)O based molecular structures having As-0 bond lengths equal to 1.81±0.02 Å. In comparison to samples implanted in the dose range 1015 to 1016 ions/cm2, the molecular environment surrounding As in polysulfone implanted at 1017 ions/cm2 has additional structure beyond the nearest-neighbor O atoms.
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Acknoledgments
The X23-A2 beamline at Brookhaven National Laboratory is supported in part by the National Institute of Standards and Technology. The NSLS is supported by the Department of Energy under contract DE-AC02-76CH00016.
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Mayanovic, R.A., Feng, Y., Groh, K.W. et al. Local Structure Surrounding Implanted As+ Ions in Polysulfone Films. MRS Online Proceedings Library 321, 113–116 (1993). https://doi.org/10.1557/PROC-321-113
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DOI: https://doi.org/10.1557/PROC-321-113