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Structure and Optical Property of Polymers Obtained by Solid-State Polymerization of a Tetraacetylene Compound

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Abstract

The polydiacetylene having diacetylenic substituents has been prepared by γ-ray irradiated solid-state polymerization of 15, 17, 19, 21-hexatriacontatetrayne. It has been found that the polymer can be converted into the di(polydiacetylene), i.e., a new type of the fused-ring polymer of conjugated 10π-electron system, by the subsequent heat-treatment in the solid-state.

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Authors and Affiliations

  1. Research Institute for Polymers and Textiles, 1-1-4 Higashi, Tsukuba, Ibaraki 305, Japan

    Shuji Okada, Hiro Matsuda, Atsushi Masaki & Hachiro Nakanishi

  2. National Chemical Laboratory for Industry, 1-1-5 Higashi, Tsukuba, Ibaraki 305, Japan

    Kikuko Hayamizu

Authors
  1. Shuji Okada
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  2. Hiro Matsuda
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  3. Atsushi Masaki
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  4. Hachiro Nakanishi
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  5. Kikuko Hayamizu
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Okada, S., Matsuda, H., Masaki, A. et al. Structure and Optical Property of Polymers Obtained by Solid-State Polymerization of a Tetraacetylene Compound. MRS Online Proceedings Library 214, 29–34 (1990). https://doi.org/10.1557/PROC-214-29

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  • DOI: https://doi.org/10.1557/PROC-214-29

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