Abstract
Mg has 7.6 mass% of high gravimetric hydrogen density, an abundance of resources and inexpensive price compared with other functional materials. Owing to these merits, it has been the major subject of hydrogen storage study. However, it is unsuitable for practical application due to thermodynamic stability and slow kinetics of Mg hydride. Therefore, many ways such as fabrication of nanocrystalline or addition of catalyst have been proposed to solve the problems of Mg hydride system. Copper and aluminum are inexpensive and can obtain easily as well as Mg. Each eutectic alloy could be produced by sintering process and observed improvement of reaction with hydrogen. Mg2Cu laminate, one phase of Mg-Cu eutectic alloy, could also be produced by cold-rolling process, and it showed reversible reaction with hydrogen, at this study.
Similar content being viewed by others
References
Z.X. Guo C. Shang K.F. Aguey-Zinsou, J. Eur. Ceram. Soc., 28(2008), 1467–1473
Anders Andreasen, Int. J. Hydrogen Energy, 33(2008), 7489–7497
K. Zeng T. Klassen W. Oelerich R. Bormann Int. J. Hydrogen Energy, 24(1999), 989–1004
M. Dornheim S. Doppiu G. Barkhordarian U. Boesenbeerg T. Klassen O. Gutfleisch and R. Bormann Scripta Mater., 56(2007), 841–846
I.P. Jain Chhagan Lal, Ankur Jain, Int. J. Hydrogen Energy, xxx (2009), 1–12
J.J. Reilly R.H. Wiswall Inorg. Chem., 7(1968), 2254–2256
Y. Ikeda T. Ohmori Int. J. Hydrogen Energy, 34(2009), 5439–5443
C.W. Hsu S.L. Lee R.R. Jeng J.C. Lin Int. J. Hydrogen Energy, 32(2007), 4907–4911
I. Saita L. Li K. Saito T. Akiyama J. Alloys Comp., 356-357(2003), 490–493
J.C. Crivello T. Nobuki S. Kato M. Abe T. Kuji J. Alloys Comp., 446-447(2007), 157–161
J.J. Reilly R.H. Wiswall Inorg. Chem., 6(1967), 2220–2223
C. Nishimura M. Komaki M. Amano J. Alloys Comp., 293-295(1999), 329–333
Thaddeus. B. Massalski H. Okamoto P.R. Subramanian Linda Kacprzak, Binary alloy phase diagrams, vol. 1, ASM international(1990), 169–171
Thaddeus. B. Massalski H. Okamoto P.R. Subramanian Linda Kacprzak, Binary alloy phase diagrams, vol. 2, ASM international(1990), 1433–1435
L. Zhang Z.Y. Cao Y.B. Liu G.H. Su L.R. Cheng Mater. Sci. Eng. A, 508(2009), 129–133
W.L.E. Wong M. Gupta Comp. Sci. Tech., 67(2007), 1541–1552
N. Takeichi K. Tanaka H. Tanaka T.T. Ueda Y. Kamiya M. Tsukahara H. Miyamura S. Kikuchi J. Alloys Comp., 446-447(2007), 543–548
S. Yoshimura Y. Narisawa Y. Watanabe M. tsunoda M. Takahashi J. Magn. Magn. Mater., 312(2007), 176–180
P. Dantzer Mater. Sci. Eng. A, 329-331(2002), 313–320
Q.A. Zang H.Y. Wu Mater. Chem. Phys. 94(2005), 69–72
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shin, H., Eto, Y., Hiroyuki, T.T. et al. Hydrogenation and Dehydrogenation Properties of Mg-Cu, Mg-Al Eutectic Alloy. MRS Online Proceedings Library 1216, 822 (2009). https://doi.org/10.1557/PROC-1216-W08-22
Received:
Accepted:
Published:
DOI: https://doi.org/10.1557/PROC-1216-W08-22