Abstract
In this work, Pt and Pt-Ru nanoparticles were synthesized on both single-walled carbon nanotubes (SWCNTs) and multi-walled carbon nanotubes (MWCNTs). Effects of different nanotube supports on electrocatalytic activity of Pt and Pt-Ru nanoparticles for methanol and ethanol oxidations were investigated using cyclic voltammetry and electrochemical impedance spectroscopy. In comparison to MWCNTs, SWCNT supported Pt and Pt-Ru catalysts demonstrate better electrocatalytic activities in terms of forward peak current density, the ratio of forward peak current density to reverse peak current density, and charge transfer resistance. This study indicates that SWCNTs can serve as effective catalyst supports for both direct methanol and ethanol fuel cells.
This is a preview of subscription content, access via your institution.
References
T. Maiyalagan, B. Viswanathan, and U. V. Varadaraju, Electrochemistry Communications 7, 905 (2005).
Y. H. Lin, X. L. Cui, C. H. Y. Chien, and, M. Wai, Langmuir 21, 11474 (2005).
W. Z. Li, X. Wang, Z. W. Chen, M. Waje, and Y. S. Yan, J. Phys. Chem. B. 110, 15353 (2006).
G. Girishkumar, T. D. Hall, K. Vinodgopal, and P. V. Kamat, J. Phys. Chem. B 110, 107 (2006).
Y. J. Gu and W. T. Wong, Langmuir 22, 11447 (2006).
G. Wu, Y. S. Chen, B. Q. Xu, Electrochemistry Communications 7, 1237(2005).
W. Z. Li, C. H. Liang, W. J. Zhou, J. S. Qiu, Z. H. Zhou, G. Q. Sun, Q. Xin, J. Phys. Chem. B 107, 6292 (2003).
L. F. Dong, R. R. Sanganna Gari, Z. Li, M. M. Craig, and S. F. Hou, Carbon 48, 781 (2010).
K. Koczkur, Q. F. Yi, and A. C. Chen, Adv. Mater. 19, 2648 (2007).
Z. B. Wang, G. P. Yin, Y. Y. Shao, B. Q. Yang, P. F. Shi, and P. X. Feng, Journal of Power Sources 165, 9 (2007).
D. J. Guo, X. P. Qui, L. Q. Chen, W. T. Zhu, Carbon 47, 1680 (2009)
J. H. Kim, H. Y. Ha, I. H. Oh, S. A. Hong, H. N. Kim, and H. I. Lee, Electrochimica Acta 50, 801 (2004).
Z. B. Wang, P. J. Zuo, G. J. Wang, C. Y. Du, and G. P. Yin, J. Phys. Chem. C 112, 6582 (2008).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Raghavendar, R.S.G., Li, Z. & Dong, L. Effects of Different Carbon Nanotube Supported Catalysts on Methanol and Ethanol Electro-Oxidation. MRS Online Proceedings Library 1213, 4 (2009). https://doi.org/10.1557/PROC-1213-T08-17
Received:
Accepted:
Published:
DOI: https://doi.org/10.1557/PROC-1213-T08-17