Abstract
An increasing demand on high energy and power systems has arisen not only with the development of electric vehicle (EV), hybrid electric vehicle (HEV), telecom, and mobile technologies, but also for specific applications such as powering of microelectronic systems. To power those microdevices, an extra variable is added to the equation: a limited footprint area. Three-dimensional (3D) microbatteries are a solution to combine high-density energy and power. In this work, we present the formation of Cu2Sb onto three-dimensionally architectured arrays of Cu current collectors. Sb electrodeposition conditions and annealing post treatment are discussed in light of their influence on the morphology and battery performances. An increase of cycling stability was observed when Sb was fully alloyed with the Cu current collector. A subsequent separator layer was added to the 3D electrode when optimized. Equivalent capacity values are measured for at least 20 cycles. Work is currently devoted to the identification of the causes of capacity fading.
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References
J.W. Long, B. Dunn, D.R. Rolison, H.S. White: Three-dimensional battery architectures. Chem. Rev.1044463 (2004)
H-S. Min, B.Y. Park, L. Taherabadi, C. Wang, Y. Yeh, R. Zaouk, M.J. Madou, B. Dunn: Fabrication and properties of a carbon/polypyrrole three-dimensional microbattery. J. Power Sources178795 (2008)
D. Golodnitsky, V. Yufit, M. Nathan, I. Shechtman, T. Ripenbein, E. Strauss, S. Menkin, E. Peled: Advanced materials for the 3d microbattery. J. Power Sources153281 (2006)
P.L. Taberna, S. Mitra, P. Poizot, P. Simon, J.M. Tarascon: High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications. Nat. Mater.5567 (2006)
R. Nesper: Structure and chemical bonding in zintl-phases containing lithium. Prog. Solid State Chem.201 (1990)
L.Y. Beaulieu, K.W. Eberman, R.L. Turner, L.J. Krause, J.R. Dahn: Colossal reversible volume changes in lithium alloys. Electrochem. Solid-State Lett.4A137 (2001)
J.O. Besenhard, J. Yang, M. Winter: Will advanced lithium-alloy anodes have a chance in lithium-ion batteries≟ J. Power Sources6887 (1997)
A.S. Arico, P. Bruce, B. Scrosati, J.M. Tarascon, W. Van Schalkwijk: Nanostructured materials for advanced energy conversion and storage devices. Nat. Mater.4366 (2005)
M.M. Thackeray, J.T. Vaughey, C.S. Johnson, A.J. Kropf, R. Benedek, L.M.L. Fransson, K. Edstrom: Structural considerations of intermetallic electrodes for lithium batteries. J. Power Sources113124 (2003)
K.D. Kepler, J.T. Vaughey, M.M. Thackeray: LixCu6Sn5 (0 < x < 13): An intermetallic insertion electrode for rechargeable lithium batteries. Electrochem. Solid-State Lett.2307 (1999)
H. Bryngelsson, J. Eskhult, L. Nyholm, K. Edström: Thin films of Cu2Sb and Cu9Sb2 as anode materials in Li-ion batteries. Electrochim. Acta537226 (2008)
M. Nathan, D. Golodnitsky, V. Yufit, E. Strauss, T. Ripenbein, I. Shechtman, S. Menkin, E. Peled: Three-dimensional thin-film Li-ion microbatteries for autonomous mems. J. Microelectromech. Syst.14879 (2005)
J.Y. Song, Y.Y. Wang, C.C. Wan: Review of gel-type polymer electrolytes for lithium-ion batteries. J. Power Sources77183 (1999)
L.M.L. Fransson, J.T. Vaughey, R. Benedek, K. Edstrom, J.O. Thomas, M.M. Thackeray: Phase transitions in lithiated Cu2Sb anodes for lithium batteries: An in situ x-ray diffraction study. Electrochem. Commun.3317 (2001)
M. Morcrette, D. Larcher, J.M. Tarascon, K. Edstrom, J.T. Vaughey, M.M. Thackeray: Influence of electrode microstructure on the reactivity of Cu2Sb with lithium. Electrochim. Acta525339 (2007)
S. Matsuno, M. Noji, T. Kashiwagi, M. Nakayama, M. Wakihar: Construction of the ternary phase diagram for the Li-Cu-Sb system as the anode material for a lithium ion battery. J. Phys. Chem. C1117548 (2007)
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Perre, E., Taberna, P.L., Mazouzi, D. et al. Electrodeposited Cu2Sb as anode material for 3-dimensional Li-ion microbatteries. Journal of Materials Research 25, 1485–1491 (2010). https://doi.org/10.1557/JMR.2010.0190
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DOI: https://doi.org/10.1557/JMR.2010.0190