Abstract
Photocatalytic titanium dioxide coatings prepared via various processes have been developed for antimicrobial purposes. Among them is arc ion plating, which may provide more advantages than other processes such as high growth rate, strong film adhesion, as well as the ability to obtain anatase phase at a low deposition temperature. This research involves an arc ion plating method to produce TiO2 film on stainless steel. Antimicrobial efficacy is examined as a function of coating parameters. The experimental results show that the deposited film mainly consists of a rutile phase at an initial growth stage, followed by the growth of an anatase phase at a later stage. By increasing oxygen partial pressure, an increased volume of anatase phase is obtained. The volume of anatase phase is found to strongly and positively affect antimicrobial efficiency. Such an arc ion plated TiO2 coating can be potentially served for antimicrobial treatment of medical equipment.











References
H. Morihiro, M. Katsuhisa, H. Sadao, K. Michiyuki I. Seiichis: Improving method of antibacterial performance of copper-containing stainless steel. Japanese Patent No. 08-229107 (1996)
S. Nakamura, N. Ookubo, K. Miyakusu, M. Hasegawa Y. Munesue: Antimicrobial activity and basic properties of “NSSAM-1” antimicrobial ferritic stainless steel. Nisshin Steel Tech. Rep. 76, 48 1997
N. Ookubo, S. Nakamura, M. Yamamoto K. Miyakusu: Antimicrobial activity and basic properties of Antimicrobial stainless steels “NSSAM series”. Nisshin Steel Tech. Rep. 77, 69 1998
S. Suzuki, K. Ishii, N. Hiramatsu K. Miyakusu: Development of NSSAM-4 antimicrobial austenitic stainless steel with excellent formability. Nisshin Steel Tech. Rep. 81, 21 2001
A. Fujishima K. Honda: Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 1972
N. Serpone: Brief introductory remarks on heterogeneous photocatalysis. Sol. Energy Mater. Sol. Cells 38, 369 1995
M.I. Litter: Brief introductory remarks on heterogeneous photocatalysis. Appl. Catal., B-Environ. 23, 89 1999
A. Mills S.L. Hunte: An overview of semiconductor photocatalysis. J. Photochem. Photobiol., A Chem. 108, 1 1997
P. Sawunyama, A. Yasumori K. Okada: The nature of multilayered TiO2-based photocatalytic films prepared by a sol-gel process. Mater. Res. Bull. 33, 795 1998
L. Zang, W. Macyk, C. Lange, W.F. Maier, C. Antonius, D. Meissner H. Kisch: Amorphous microporous titania modified with metal chlorides as photocatalysts for detoxification and charge generation by Visible Light. Chem. Eur. J. 6, 379 2000
P.C. Maness, S. Smolinski, D.M. Blake, Z. Huang, E.J. Wolfrum W.A. Jacoby: Bactericidal activity of photocatalytic TiO2 reaction: toward an understanding of its killing mechanism. Appl. Environ. Microbiol. 65, 4094 1999
C. Wei, W.Y. Lin, Z. Zainal, N.E. Williams, K. Zhu, A.P. Kruzic, R.L. Smith K. Rajeshwar: Bactericidal activity of TiO2 photocatalyst in aqueous media: Toward a solar-assisted water disinfection system. Environ. Sci. Technol. 28, 934 1994
C.C. Trapalisa, P. Keivanidisa, G. Kordasa, M. Zaharescub, M. Crisanb, A. Szatvanyib M. Gartnerb: TiO2(Fe3+) nanostructured thin films with antibacterial properties. Thin Solid Films 433, 186 2003
K. Sunada, Y. Kikuchi, K. Hashimoto A. Fujishima: Bactericidal and detoxification effects of TiO2 thin film photocatalysts. Environ. Sci. Technol. 32, 726 1998
M. Yamagishi, S. Kuriki, P.K. Song Y. Shigesato: Thin film TiO2 photocatalyst deposited by reactive magnetron sputtering. Thin Solid Films 442, 227 2003
T.S. Yang, C.B. Shiu M.S. Wong: Structure and hydrophilicity of titanium oxide films prepared by electron beam evaporation. Surf. Sci. 548, 75 2004
J.T. Chang, C.W. Su J.L. He: Photocatalytic TiO2 film prepared using arc ion plating. Surf. Coat. Technol. 200, 3027 2006
J.T. Chang: Y.F. Lai, and J.L He: Photocatalytic performance of chromium or nitrogen doped arc ion plated-TiO2 films. Surf. Coat. Technol. 200, 1640 2005
JIS Z2801 2000 Antimicrobial products–Test for antimicrobial activity and efficacy.Japanese Industrial Standard (2001)
D. Dumitriu, A.R. Bally, C. Ballif, P. Hones, P.E. Schmid, R. Sanjines, F. Levy V.I. Parvulescu: Photocatalytic degradation of phenol by TiO2 thin films prepared by sputtering. Appl. Catal., B-Environ. 25, 83 2000
P. Zeman S. Takabayashi: Effect of total and oxygen partial pressures on structure of photocatalytic TiO2 films sputtered on unheated substrate. Surf. Coat. Technol. 153, 93 2002
P. Hovsepian D. Popov: Cathode poisoning during reactive arc evaporation of titanium in nitrogen atmosphere. Vacuum 45, 603 1994
ACKNOWLEDGMENTS
The authors would like to express gratitude to Feng Chia University and Taichung Veterans General Hospital (TVGH) under the Feng-Rong Project (TCVGH-FCU-958206), and Miss Liu Mei-Fang, at the Department of Infectious Diseases, TVGH for assistance in antimicrobial testing.
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Chung, C., Lin, H. & He, J. Microstructural effect on the antimicrobial efficacy of arc ion plated TiO2. Journal of Materials Research 22, 3137–3143 (2007). https://doi.org/10.1557/JMR.2007.0388
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DOI: https://doi.org/10.1557/JMR.2007.0388