Skip to main content
Log in

Microstructure- and property-controllable NdAlNiCuFe alloys by varying Fe content

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

We report the formation of microstructure- and property-controllable Nd60Al10Ni10Cu20-xFex (0 = x = 20) alloys by varying the content of Fe element. The microstructure of the Nd-based alloy can be changed progressively from a full glassy state into a composite state with nanocrystalline particles in the glassy matrix and, finally, into a nanostructured state, accompanied by variation in magnetic property gradually from paramagnetic to hard magnetic. The role of Fe addition in the control of microstructure and magnetic property is clarified. We expect that the results would have implication in the development of the microstructure- and property-controllable functional materials for various applications.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W.L. Johnson: Bulk glass-forming metallic alloys: Sciences and technology, MRS Bull. 24 (10),24 (1999).

    Google Scholar 

  2. W.H. Wang, C. Dong, C.H. Shek: Bulk metallic glasses, Mater. Sci. Eng. R. 44, 45 (2004).

    Google Scholar 

  3. W.H. Guo, F.F. Chua, C.C. Leung and H.W. Kui: Formation of bulk nanostructured materials by rapid solidification, J. Mater. Res. 15, 1605 (2000).

    CAS  Google Scholar 

  4. W.H. Guo and H.W. Kui: Bulk nanostructured alloy formation with controllable grain size, Acta Mater. 48, 2117 (2000).

    CAS  Google Scholar 

  5. W. Liu and W.L. Johnson: Precipitation of bcc nanocrystals in bulk Mg-Cu-Y amorphous alloys, J. Mater. Res. 11, 2388 (1996).

    CAS  Google Scholar 

  6. W.H. Wang, R.J. Wang, W.T. Yang, D.Q. Zhao and M.X. Pan: Stability of supercooled liquid state of ZrTiCuNiBe bulk metallic glass forming alloy, J. Mater. Res. 17, 1385 (2002).

    CAS  Google Scholar 

  7. W.H. Wang, D.W. He, D.Q. Zhao, Y.S. Yao and M. He: Nanocrystallization in ZrTiCuNiBeC bulk metallic glass under high pressure, Appl. Phys. Lett. 75, 2770 (1999).

    CAS  Google Scholar 

  8. Y. He, C.E. Price and S.J. Poon: Formation of Nd-based metallic glasses, Philos. Mag. Lett. 70, 371 (1994).

    CAS  Google Scholar 

  9. A. Inoue, A. Takeuchi and T. Zhang: Bulk glass forming based on rare earth elements, Metall. Mater. Trans. 29A, 1779 (1998).

    CAS  Google Scholar 

  10. G.J. Fan, W. Löser, S. Roth and J. Eckert: Glass-forming ability of RE–Al–TM alloys (RE = Sm, Y; TM = Fe, Co, Cu), Acta. Mater. 48, 3823 (2000).

    CAS  Google Scholar 

  11. B.C. Wei, W.H. Wang, M.X. Pan, B.S. Han and W.R. Hu: Nd65Al10Fe25-xCox bulk metallic glasses with wide supercooled liquid regions, Phys. Rev. B. 64, 012406 (2001).

    Google Scholar 

  12. Z.F. Zhao, Z. Zhang, P. Wen, M.X. Pan, D.Q. Zhao, Z. Zhang and W.H. Wang: Highly glass forming alloy with very low glass transition temperature, Appl. Phys. Lett. 82, 4699 (2003).

    CAS  Google Scholar 

  13. W.H. Wang, Q. Wei and H.Y. Bai: Enhanced thermal stability and microhardness in metallic glass ZrTiCuNiBe alloys by carbon addition, Appl. Phys. Lett. 71, 58 (1997).

    CAS  Google Scholar 

  14. Z. Bian, R.J. Wang, M.X. Pan, D.Q. Zhao and W.H. Wang: Excellent wave absorption ability of Zr-based bulk metallic glass composites containing carbon nanotubes, Adv. Mater. 15, 616 (2003).

    CAS  Google Scholar 

  15. W.H. Wang, Z. Bian, P. Wen, Y. Zhang and M.X. Pan: Role of addition in formation and properties of Zr-based bulk metallic glasses, Intermetallics 10, 1249 (2002).

    CAS  Google Scholar 

  16. Y. Zhang, D.Q. Zhao and W.H. Wang: Formation ZrNiCuAl bulk metallic glasses with low purity elements, Mater. Trans. 41, 1410 (2000).

    CAS  Google Scholar 

  17. W.H. Wang, R.J. Wang, G.J. Fan and J. Eckert: Formation and properties of Zr-(Ti, Nb)-Cu-Ni-Al bulk metallic glasses, Mater. Trans. 42, 587 (2001).

    CAS  Google Scholar 

  18. Y. Hu, M.X. Pan, L. Liu and W.H. Wang: Synthesis of Fe-based bulk metallic glasses with low purity materials by multi-metalloids addition, Mater. Lett. 57, 2698 (2003).

    CAS  Google Scholar 

  19. W.H. Wang, M.X. Pan, D.Q. Zhao and H.Y. Bai: Enhance soft magnetic properties of FeCoZrMoWB bulk metallic glass by microalloying, J. Phys.: Condens. Matter 16, 3719 (2004).

    CAS  Google Scholar 

  20. Z.G. Zhao, de F.R. Boer and K.H.L. Buschow: Magnetic properties of R6Fe11A13 and R6Fe12A12 compounds with R = Pr, Nd, J. Alloys and Compd. 239, 147 (1996).

    CAS  Google Scholar 

  21. B. Grieb and E. Henig: The ternary NdAlFe system, Z. Metallkede 82, 560 (1991).

    CAS  Google Scholar 

  22. D.Q. Zhao, W.H. Wang: Melting and crystallization of Nd60A110Fe20Co10 bulk metallic glass under high pressure, J. Phys.: Condens. Matter 15, L749 (2003).

    CAS  Google Scholar 

  23. W.H. Wang, L.L. Li, M.X. Pan and R.J. Wang: Characteristics of glass transition and supercooled liquid state of Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass, Phys. Rev. B 63, 052204 (2001).

    Google Scholar 

  24. M. Libera and M. Chen: Phase change erasable optical storage, MRS Bull. 15, 40 (1990).

    CAS  Google Scholar 

  25. H.J. Fecht: Thermodynamic properties of amorphous solids—glass formation and glass transition, Mater. Trans. JIM 36, 777 (1995).

    CAS  Google Scholar 

  26. Z. Zhang, L. Xia, B.C. Wei, D.Q. Zhao, M.X. Pan and W.H. Wang: Structural evolution and property changes in Nd60Al10Fe20Co10 bulk metallic glass during crystallization, Appl. Phys. Lett. 81, 4371 (2002).

    CAS  Google Scholar 

  27. D. Turnbull: Under what conditions can a glass be formed? Contemp. Phys. 10, 473 (1969).

    CAS  Google Scholar 

  28. A.L. Greer: Confusion by design, Nature 366, 303 (1993).

    Google Scholar 

  29. Z.G. Sun, W. Löser, J. Eckert and L. Schultz: Phase separation in Nd60–xYxFe30Al10 melt-spun ribbons, Appl. Phys. Lett. 80, 772 (2002).

    CAS  Google Scholar 

  30. De F.R. Boer, R. Boom, W.C.M. Mattens, A.R. Miedema and A.K. Niessen: Cohesion in Metals (North-Holland, Amsterdam, 1988).

    Google Scholar 

  31. J. Delamare, D. Lemarchand and P.J. Vigier: Structural investigation of the metastable compound A1 in an as-cast Fe–Nd eutectic alloy, J. Alloys Compd. 216, 273 (1994).

    Google Scholar 

  32. V.P. Menushenkov, A.S. Lileev, M.A. Oreshkin and S.A. Zhuravlev: Metastable nanocrystalline A1 phase and coercivity in Fe–Nd alloys, J Magn. Magn. Mater. 203, 149 (1999).

    CAS  Google Scholar 

  33. G.J. Fan, W. Löser, S. Roth, J. Eckert and L. Schultz: Magnetic properties of cast Nd60–xFe20Al10Co10Cux alloys, Appl. Phys. Lett. 75, 2984 (1999).

    CAS  Google Scholar 

  34. M.J. Kramer, O’A.S. Connor, K.W. Dennis, R.W. McCallum, L.H. Lewis, L.D. Tung and N.P. Duong: The origins of coercivity in the amorphous alloy NdFeAl, IEEE Trans. Magn. 37, 2497 (2001).

    CAS  Google Scholar 

  35. I. Betancourt and R. Valenzuela: The role of cluster formation on the magnetic properties of NdAlFe-based magnetic alloys, J. Mater. Res. 27, 427 (2003).

    Google Scholar 

  36. G. Kumar, J. Eckert, S. Roth, W. Stefan, W. Löser and L. Schultz: Structural and magnetic properties of as-cast Nd-(Fe,Co)-Al alloys (Annales de Chimie, Paris, France), 27, 41 (2002).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to W. H. Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhang, Z., Zhao, D.Q. & Wang, W.H. Microstructure- and property-controllable NdAlNiCuFe alloys by varying Fe content. Journal of Materials Research 20, 314–319 (2005). https://doi.org/10.1557/JMR.2005.0038

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2005.0038

Navigation