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Synthesis of carbon nitride nanocrystals on Co/Ni-covered substrate by nitrogen-atom-beam-assisted pulsed laser ablation

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Abstract

Carbon nitride nanocrystals were synthesized on Co/Ni-covered Si(100) wafers using a nitrogen-atom-beam-assisted pulsed laser ablation deposition method. Transmission electron miscroscopy, x-ray diffraction, and Raman spectroscopy showed that as-deposited films were constructed primarily from nanometer-sized β-C3N4 and CNx crystallites. The co-catalyzation by the cobalt and nickel in the synthesis process is considered to play an important role in the formation of nanocrystalline β-C3N4. The reasons for the formation of carbon nitride nanocrystals were analyzed.

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References

  1. A.Y. Liu and M.L. Cohen, Science 245, 841 (1989).

    Article  CAS  Google Scholar 

  2. A.Y. Liu and M.L. Cohen, Phys. Rev. B 41, 10727 (1990).

    Article  CAS  Google Scholar 

  3. Y.F. Zhang, Z.H. Zhou, and H.L. Li, Appl. Phys. Lett. 68, 634 (1996).

    Article  CAS  Google Scholar 

  4. T.Y. Yen and C.P. Chou, Appl. Phys. Lett. 67, 2801 (1995).

    Article  CAS  Google Scholar 

  5. K. Ogata, J.F.D. Chubaci, and F. Fujimoto, J. Appl. Phys. 76, 3791 (1994).

    Article  CAS  Google Scholar 

  6. X.M. He, S. Li, W.Z. Li, and H.D. Li, J. Mater. Res. 12, 1595 (1997).

    Article  CAS  Google Scholar 

  7. R. Kaltofen, T. Sebald, and G. Weise, Thin Solid Films 290–291, 112 (1996).

    Article  Google Scholar 

  8. D. Li, Y.W. Chung, M.S. Wong, and W.D. Sproul, Tribology 1, 87 (1995).

    CAS  Google Scholar 

  9. K.M. Yu, M.L. Cohen, E.E. Haller, W.L. Hansen, A.Y. Liu, and I.C. Wu, Phys. Rev. B 49, 5034 (1994).

    Article  CAS  Google Scholar 

  10. Z.M. Ren, Y.C. Du, Z.F. Ying, Y.X. Qiu, X.X. Xiong, J.D. Wu, and F.M. Li, Appl. Phys. Lett. 65, 1361 (1994).

    Article  CAS  Google Scholar 

  11. N. Xu, Y.C. Du, Z.F. Ying, Z.M. Ren, F.M. Li, J. Lin, Y.Z. Ren, and X.F. Zhong, J. Phys. D: Appl. Phys. 30, 1370 (1997).

    Article  CAS  Google Scholar 

  12. P.N. Wang, N. Xu, Z.F. Ying, X.T. Ying, Z.P. Liu, and W.D. Yang, Thin Solid Films 382, 34 (2001).

    Article  CAS  Google Scholar 

  13. C. Niu, Y.Z. Lu, and C.M. Lieber, Science 261, 334 (1993).

    Article  CAS  Google Scholar 

  14. N. Xu, Y.C. Du, Z.F. Ying, and F.M. Li, Appl. Phys. Lett. 69, 1364 (1996).

    Article  CAS  Google Scholar 

  15. N. Xu, Y.C. Du, Z.F. Ying, Z.M. Ren, and F.M. Li, Rev. Sci. Instrum. 68, 2994 (1997).

    Article  CAS  Google Scholar 

  16. C. Ronning, H. Felderman, R. Merk, H. Hofsass, P. Reinke, and J.U. Thiele, Phys. Rev. B 58, 2207 (1998).

    Article  CAS  Google Scholar 

  17. A.K. Sharma and J. Narayan, Int. Mater. Rev. 42, 137(1997).

    Article  CAS  Google Scholar 

  18. D.W. Wu, W. Fan, H.X. Guo, M.B. He, X.Q. Meng, and X.J. Fan, Solid State Commun. 103, 193 (1997).

    Article  CAS  Google Scholar 

  19. J.L. He and W.L. Chang, Surf. Coat. Technol. 99, 184 (1998).

    Article  Google Scholar 

  20. F. Tuinstra and J.L. Koenig, J. Chem. Phys. 53, 1126 (1970).

    Article  CAS  Google Scholar 

  21. J.H. Kaufman, S. Metin, and D.D. Saperstein, Phys. Rev. B 39, 13053 (1989).

    Article  CAS  Google Scholar 

  22. M.Y. Chen, D. Li, X. Lin, V.P. Dravid, Y.W. Chung, M.S. Wong, and W.D. Sproul, J. Vac. Sci. Technol. A 11, 521(1993)

    Article  CAS  Google Scholar 

  23. L.H. Robins, J. Mater. Res. 5, 2456 (1990).

    Article  CAS  Google Scholar 

  24. J. Widany, F. Weich, T. Kohler, D. Porezag, and T. Frauenheim, Diamond Relat. Mater. 5, 1031 (1996).

    Article  CAS  Google Scholar 

  25. M. Wixam, J. Am. Ceram. Soc. 73, 1973 (1990).

    Article  Google Scholar 

  26. T.Y. Yen and C.P. Chou, Solid State Commun. 95, 281 (1995).

    Article  CAS  Google Scholar 

  27. B.S. Elman, M.S. Dresselhaus, G. Dresselhaus, E.W. Maby, and H. Mazurek, Phys. Rev. B 24, 1027 (1981).

    Article  CAS  Google Scholar 

  28. Y.F. Lu, Z.M. Ren, T.C. Chong, B.A. Cheong, S.I. Pang, J.P. Wang, and K. Li, J. Appl. Phys. 86, 4954 (1999).

    Article  CAS  Google Scholar 

  29. A.M. Rao, E. Richter, S. Bandow, B. Chase, P.C. Eklund, K.A. Wiliams, S. Fang, K.R. Subbaswamy, M. Menon, A. Thess, R.E. Smalley, G. Dresselhaus, and M.S. Dresselhaus, Science 275, 187 (1997).

    Article  CAS  Google Scholar 

  30. M. Yudasaka, T. Komatsu, T. Ichihashi, Y. Achiba, and S. Iijima, J. Phys. Chem. B 102, 4892 (1998).

    Article  CAS  Google Scholar 

  31. Y. Sato and M. Kamo, Surf. Coat. Technol. 39/40, 199 (1989).

    Google Scholar 

  32. D.P. Yu, X.S. Sun, C.S. Lee, I. Bello, S.T. Lee, H.D. Gu, K.M. Leung, G.W. Zhou, Z.F. Dong, and Z. Zhang, Appl. Phys. Lett. 72, 1966 (1998).

    Article  CAS  Google Scholar 

  33. H. Tojima, T. Okamoto, A. Yamada, M. Konagai, and K. Takahashi, J. Crystal Growth 138, 408 (1994).

    Article  CAS  Google Scholar 

  34. H.L. Chang, C.H. Lin, and C.T. Kuo, Thin Solid Films 420, 219 (2002).

    Article  Google Scholar 

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Xu, N., Lin, H., Li, L. et al. Synthesis of carbon nitride nanocrystals on Co/Ni-covered substrate by nitrogen-atom-beam-assisted pulsed laser ablation. Journal of Materials Research 18, 2552–2555 (2003). https://doi.org/10.1557/JMR.2003.0357

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  • DOI: https://doi.org/10.1557/JMR.2003.0357

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