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Reaction and phase separation mechanisms during synthesis of alloys by thermite type combustion reactions

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Abstract

Combustion of the thermite system is a promising approach for synthesis of alloys (e.g., Co-based) that are widely used in orthopedic applications. This process typically involves formation of two liquids (oxide and metal alloy), followed by their phase separation. The latter is generally believed to be controlled solely by gravity-driven buoyancy. To verify this hypothesis, a fundamental study of phase separation during alloy synthesis was conducted in both normal gravity and microgravity conditions. It was shown that a non-gravity-driven mechanism primarily controls the segregation process. Quenching experiments identified the reaction and phase separation mechanisms in the investigated systems.

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References

  1. Z.A. Munir and U. Anselmi-Tamburini, Mater. Sci. Rep. 3, 277 (1989).

    Article  CAS  Google Scholar 

  2. A. Varma and A.S. Mukasyan, in Powder Metal Technologies and Applications, ASM Handbook (ASM International, Materials Park, OH, 1998), Vol. 7, p. 523.

    Google Scholar 

  3. A. Varma, Sci. Am. 283(2), 58 (2000).

    Article  CAS  Google Scholar 

  4. S.K. Yen and S.W. Hsu, J. Biomed. Mater. Res. 54, 412 (2001).

    Article  CAS  Google Scholar 

  5. B.J. Park and R.S. Lakes, Biomaterials (Plenum Press, New York, 1992).

    Book  Google Scholar 

  6. R.H. Shetty and W.H. Ottersberg, in Encyclopedic Handbook of Biomaterials and Bioengineering (Marcel Dekker, New York, 1995), Part B, p. 509.

    Google Scholar 

  7. A.G. Merzhanov, V.I. Yukhvid, and I.P. Borovinskaya, Dokl. Chem. Phys. 255, 503 (1979).

    Google Scholar 

  8. V.I. Yukhvid, Izv. Akad. Nauk SSSR Met. 6, 61 (1980).

    Google Scholar 

  9. A.M. Bulaev, Combust. Explos. Shock Waves (Engl. Transl.) 28, 395 (1992).

    Article  Google Scholar 

  10. K.G. Shkadinsky, G.V. Shkadinskaya, and B.J. Matkowsky, Combust. Sci. Technol. 115, 229 (1996).

    Article  CAS  Google Scholar 

  11. C. Lau, A.S. Mukasyan, and A. Varma, Proc. Combust. Inst. (2002, in press).

  12. A. Varma, A.S. Rogachev, A.S. Mukasyan, and S. Hwang, Adv. Chem. Eng. 24, 79 (1998).

    Article  CAS  Google Scholar 

  13. A.A. Shiryaev, Int. J. Self-Propag. High-Temp. Synth. 4, 351 (1995).

    CAS  Google Scholar 

  14. A. Varma, B. Li, and A.S. Mukasyan, Adv. Eng. Mater. 4, 482 (2002).

    Article  CAS  Google Scholar 

  15. L.L. Regel, Materials Processing in Space, edited by R.Z. Sagdeev (Consultation Bureau, New York, 1989), p. 68.

    Google Scholar 

  16. Solidification in Gravity, edited by A. Roosz and M. Rettenmayer, Materials Science Forum (Trans Tech, Enfield, NH, 1996), Vols. 215–216.

    Google Scholar 

  17. D. Langbein, in The Effect of Gravity on the Solidification of Immiscible Alloys, Proceedings of an RIT/ESA/SSC Workshop, (European Space Agency, Jarva Krog, Sweden, 1984), p. 3.

    Google Scholar 

  18. A.S. Mukasyan, A. Pelekh, and A. Varma, J. Mater. Synth. Process. 5, 391 (1997).

    CAS  Google Scholar 

  19. PCPDF-WIN software (JCPDS-International Center for Diffraction Data, Newton Square, PA, 1994).

  20. D.B. Miracle and R. Darolia, Intermetallic Compounds, edited by J.H. Westbrook and R.L. Fleischer (John Wiley, Chichester, U.K., 1995), Vol. 2, p. 53.

    Google Scholar 

  21. L. Ratke and S. Diefenbach, Mater. Sci. Eng., R 15, 263 (1995).

    Article  Google Scholar 

  22. J. Legros, A. Sanfeld, and M. Velarde, Fluid Sciences and Materials Science in Space (Springer-Verlag, Berlin, Germany, 1987).

    Google Scholar 

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Correspondence to Arvind Varma.

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Lau, C., Mukasyan, A.S. & Varma, A. Reaction and phase separation mechanisms during synthesis of alloys by thermite type combustion reactions. Journal of Materials Research 18, 121–128 (2003). https://doi.org/10.1557/JMR.2003.0018

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  • DOI: https://doi.org/10.1557/JMR.2003.0018

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