Abstract
Planar thin films of dye-doped silica were prepared by sol-gel synthesis. The optical properties of the films were characterized by transmittance measurements in the visible-infrared range and by photoluminescence. Micropatterns whose feature size was on the order of 2.4 μm, were imprinted on the film surface by a simple soft lithography approach. An optical microscope interfaced to a charge-coupled device camera was used to image the imprinted patterns and to analyze the patterned films photoluminescence. A sensitive spectral narrowing of the emission, which occurred only in micropatterned films, was attributed to the lateral confinement of the luminescence due to the micrometer-scale modulation of refractive index produced by the embossing procedure.
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S. Toyoda, N. Ooba, M. Hikita, T. Kurihara, and S. Imamura, Thin Solid Films 370, 311 (2000).
X. Orignac, B. Barbieri, X.M. Du, R.M. Almeida, O. McCarthy, and E. Yeatman, Optical Mater. 12, 1 (1999).
P. Innocenzi, A. Martucci, M. Guglielmi, L. Armelao, S. Pelli, G.C. Righini, and G.C. Battaglin, J. Non-Cryst. Solids 259, 182 (1999).
J.T. Remillard, J.R. Jones, B.D. Poindexter, C.K. Narula, and W.H. Weber, Appl. Optics 38, 5306 (1999).
Y. Ren, P. Mormile, L. Petti, and G.H. Cross, Sens. Actuators B 75, 76 (2001).
K.M. Chen, A.W. Sparks, H-C. Luan, D.R. Lim, K. Wada, and L.C. Kimerling, Appl. Phys. Lett. 75, 24 (1999).
D. Blanc and S. Pelissier, Thin Solid Films 384, 251 (2001).
J. Livage and D. Ganguli, Solar Energy Mater. Solar Cells 68, 365 (2000).
Q.Y. Zhang and Z.H. Jiang, Mater. Chem. Phys. 69, 95 (2001).
D. Lo, S.K. Lam, C. Ye, and K.S. Lam, Opt. Commun. 156, 316 (1998).
R. Reisfeld, Opt. Mater. 16, 1 (2001).
S.K. Lam, X.L. Zhu, and D. Lo, Appl. Phys. B 68, 1151 (1999).
Y. Xia and G.M. Whitesides, Angew. Chem. Int. Ed. 37, 550 (1998).
D.A. Doshi, N.K. Huesing, M. Lu, H. Fan, Y. Lu, K. Simmons-Potter, B.G. Potter, Jr., A.J. Hurd, and C.J. Brinker, Science 290, 107 (2000).
J. Eang, X. Sun, L. Chen, and S. Chou, Appl. Phys. Lett. 75, 2767 (1999).
P. Yang, G. Wirnsberger, H.C. Huang, S.R. Cordero, M.D. McGehee, B. Scott, T. Deng, G.M. Whitesides, B.F. Chmelka, S.K. Buratto, and G.D. Stucky, Science 287, 465 (2000).
R. Reisfeld, E. Yariv, and H. Minti, Opt. Mater. 8, 31 (1997).
T. Kawase, D.J. Pinner, R.H. Friend, and T. Shimoda, Synth. Met. 111, 583 (2000).
A.N. Safonov, M. Jory, B.J. Matterson, J.M. Lupton, M.G. Salt, J.A.E. Wasey, W.L. Bernes, and I.D.W. Samuel, Synth. Met. 116, 145 (2001).
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Arena, A., Patanè, S., Saitta, G. et al. Preparation, characterization, and micropatterning of laser-dye-doped sol-gel films. Journal of Materials Research 17, 2095–2098 (2002). https://doi.org/10.1557/JMR.2002.0309
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DOI: https://doi.org/10.1557/JMR.2002.0309