Abstract
AlN/VN superlattices with different periods were studied using x-ray diffraction and transmission electron microscopy (TEM). A phase transformation of the AlN from an epitaxially stabilized rock-salt structure to a hexagonal wurtzite structure was observed for an AlN layer thickness greater than 4 nm. A structural model is proposed on the basis of TEM results for the orientation of the transformed phase. The VN layer grown on top of the hexagonal AlN was observed to be reoriented compared to that in the stabilized B1-AlN/VN. The VN nucleated by taking the w-AlN(002) plane as its (111) plane instead of the (002) plane.
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References
N.E. Christensen and I. Gorczyca, Phys. Rev. B 50, 4397 (1994).
W. Kohn and L.J. Sham, Phys. Rev. A. 140, 1133 (1965).
M. Ueno, A. Onodera, O. Shimomura, and K. Takemura, Phys. Rev. B 45, 10123 (1992).
Q. Xia, H. Xia, and A.L. Ruoff, J. Appl. Phys. 73, 8198 (1993).
I.W. Kim, A. Madan, M.W. Guruz, V.P. Dravid, and S.A. Barnett, J. Vac. Sci. Technol., A 19, 2069 (2001).
A. Madan, I.W. Kim, and S.A. Barnett (unpublished, 1996).
A. Madan, I.W. Kim, S.C. Cheng, P. Yashar, V.P. Dravid, and S.A. Barnett, Phys. Rev. Lett. 78, 1743 (1997).
I.W. Kim, Q. Li, L.D. Marks, and S.A. Barnett, Appl. Phys. Lett. 78, 892 (2001).
P.B. Mirkarimi, M. Shinn, and S.A. Barnett, J. Vac. Sci. Technol., A 10, 1618 (1992).
H. Schulz and K. Thiemann, Solid State Commun. 23, 815 (1977).
J.W. Edington, Monographs in Practical Electron Microscopy in Material Science, II, Electron Diffraction in the Electron Microscope (Macmillan, London, 1975).
A.K. Jena and M.C. Chaturvedi, Phase Transformations in Materials (Prentice Hall, Englewood Cliffs, NJ, 1992).
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Li, Q., Kim, I.W., Barnett, S.A. et al. Structures of AlN/VN Superlattices with Different AlN Layer Thicknesses. Journal of Materials Research 17, 1224–1231 (2002). https://doi.org/10.1557/JMR.2002.0181
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DOI: https://doi.org/10.1557/JMR.2002.0181