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Intercalation of Rhodamine 6G and Oxazine 4 into Oriented Clay Films and Their Alignment

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Abstract

The cationic dyes rhodamine 6G (R6G) and oxazine 4 (Ox4) were intercalated into oriented lithium hectorite (LiHT, a synthetic fluor-mica) films by ion-exchange, and their orientation was studied by x-ray and polarized spectroscopy. Orientation of dyes was determined by basal spacing obtained by x-ray diffraction data, showing that angles of the long axis were 60° for R6G and 47° for Ox4 against the layer. Polarized ultraviolet-visible spectroscopy showed that the high-order H-aggregate of R6G and Ox4 were oriented at 64° and 52° against layers, respectively; other states of dyes were oriented at much lower angles. The interlayer distance was mostly determined by dimensions of the high-order H-aggregate.

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Authors and Affiliations

  1. Advanced Materials Laboratory (AML), National Institute for Materials Science, 1-1 Namiki, 305-0044, Tsukuba, Ibaraki, Japan

    Guangming Chen, Nobuo Iyi, Taketoshi Fujita & Kenji Kitamura

  2. Research Center for Advanced Waste and Emission Management (ResCWE), Nagoya University, 464-8603, Furo-cho, Chikusa-ku, Nagoya, Japan

    Ryo Sasai

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  1. Guangming Chen
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  2. Nobuo Iyi
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  4. Taketoshi Fujita
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Correspondence to Nobuo Iyi.

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Chen, G., Iyi, N., Sasai, R. et al. Intercalation of Rhodamine 6G and Oxazine 4 into Oriented Clay Films and Their Alignment. Journal of Materials Research 17, 1035–1040 (2002). https://doi.org/10.1557/JMR.2002.0153

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  • DOI: https://doi.org/10.1557/JMR.2002.0153

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