Abstract
Nanocrystalline nickel oxide–yttrium-stabilized zirconia (NiO/YSZ) composite powder for the solid oxide fuel cells was prepared by solution combustion through control of pH values and contents of glycine fuel in precursor solution. A strongly acidic precursor solution with appropriate amounts of glycine fuel added increased the specific surface area of the synthesized composite powders. This results from the increased binding of metal ions and glycine under strongly acidic solution (pH = 0.5) conditions. After sintering and reducing treatment of nanocrystalline NiO/YSZ composite, the Ni/YSZ pellet showed an ideal microstructure: fine Ni particles of 3 to 5 μm were distributed uniformly, and fine micropores around Ni metal particles were formed, thus leading to an increase in the triple phase boundary area among gas, Ni and YSZ.
Similar content being viewed by others
References
T. Kawata, N. Sakai, H. Yokohawa, M. Mori, and T. Iwat, J. Electrochem. Soc. 137, 3042 (1990).
K. Equchi, T. Setoguchi, K. Okamoto, and H. Arai, in Proc. 3rd Int. Symp. on Solid Oxide Fuel Cells, edited by S.C. Singhal and H. Iwahara (Electrochemical Society, Pennington, NJ, 1993), p. 494.
S. Murakami, Y. Akiyama, N. Ishida, T. Yasuo, T. Saito, and N. Furukawa, in Proc. 2nd Int. Symp. on Solid Oxide Fuel Cells, edited by F. Grosz, P. Zegers, S.C. Singhal, and O. Yamamoto (Commission of the European Communities, Athens, Greece, 1991), p. 105.a
T. Shirakawa, S. Matsuda, and A. Fukushima, in Proc. 3rd Int. Symp. Solid Oxide Fuel Cells, edited by S.C. Singhal and H. Iwahara (Electrochemical Society, Pennington, NJ, 1993), p. 464.
I.S. Park, S.J. Kim, B.H. Lee, and S. Park, Jpn. J. Appl. Phys. 36, 6427 (1997).
T.V. Anuradha, S. Rangnathan, T. Mimani, and K.C. Patial, Scripta Mater. 44, 2237 (2001).
R. Jose, J. Jameo, A.M. John, R. Divakar, and J. Koshy, J. Mater. Synth. Proc. 8, 1 (2001).
S.R. Jain, K.C. Adiga, and V.R.P Vemeker, Combust. Flame 40, 71 (1981).
Y. Zhang and G.C. Stangle, J. Mater. Res. 9, 1997 (1994).
L.A. Chick, L.R. Pederson, G.D. Maupin, J.L. Bates, L.E. Thomas, and G.J. Exarbos, Mater. Lett. 10, 6 (1990).
R.M. Silverstein and G.C. Bassler, Spectrometric Identification of Organic Compounds, 5th ed. (John Wiley & Sons, New York, 1991), p. 125.
D.N. Sen, I. Mizushima, C. Curran, and J.V. Quagliano, J. Chem. Phys. 77, 211 (1955).
L. Stryer, Biochemistry (H. Freeman, New York, 1988), p. 15.
L.A. Chick, G.D. Maupin, G.L. Graff, L.R. Pederson, D.E. McCready, and J.L. Bates, in Synthesis and Processing of Ceramics: Scien-tific Issues, edited by W.E. Rhine, T.M. Shaw, R.J. Gottschall, and Y. Chen (Mater. Res. Soc. Symp. Proc. 249, Pittsburgh, PA, 1992), p. 159.
T.P. Lockhalt, G. Piro, F. Gagliardi, and L. Zanibelli, U.S. Patent No. 5 261 944 (16 November 1993).
T. Setoguchi, K. Okamoto, K. Equchi, and H. Aria, J. Electro-chem. Soc. 139, 2875 (1992).
F. Michaud, M. Barrio, S. Toscani, D.O. López, J.Ll. Tamarit, V. Agafonov, H. Szwarc, and R. Céolin, Phys. Rev. B 57, 10351 (1998).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kim, SJ., Lee, W., Lee, WJ. et al. Preparation of nanocrystalline nickel oxide–yttria-stabilized zirconia composite powder by solution combustion with ignition of glycine fuel. Journal of Materials Research 16, 3621–3627 (2001). https://doi.org/10.1557/JMR.2001.0496
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.2001.0496