Abstract
Most organosilicate glass (OSG), low dielectric constant (low-κ) films contain Si–R groups, where R is an organic moiety such as −CH3. The organic component is susceptible to the chemically reactive plasmas used to deposit cap layers, etch patterns, and ash photoresist. This study compares a spin-on, mesoporous OSG film with a completely connected pore structure to both its nonmesoporous counterpart and to another low-density OSG film deposited by plasma-enhanced chemical vapor deposition. The results show that the film with connected pores was much more susceptible to integration damage than were the nonmesoporous OSG films.
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Ryan, E.T., Martin, J., Junker, K. et al. Effect of material properties on integration damage in organosilicate glass films. Journal of Materials Research 16, 3335–3338 (2001). https://doi.org/10.1557/JMR.2001.0458
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DOI: https://doi.org/10.1557/JMR.2001.0458