Skip to main content
Log in

Effect of material properties on integration damage in organosilicate glass films

  • Rapid Communications
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Most organosilicate glass (OSG), low dielectric constant (low-κ) films contain Si–R groups, where R is an organic moiety such as −CH3. The organic component is susceptible to the chemically reactive plasmas used to deposit cap layers, etch patterns, and ash photoresist. This study compares a spin-on, mesoporous OSG film with a completely connected pore structure to both its nonmesoporous counterpart and to another low-density OSG film deposited by plasma-enhanced chemical vapor deposition. The results show that the film with connected pores was much more susceptible to integration damage than were the nonmesoporous OSG films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. M. Morgen, E. T. Ryan, J-H. Zhao, C. Hu, T. Cho, and P. S. Ho, Ann. Rev. Mater. Sci. 30, 645 (2000).

    Article  CAS  Google Scholar 

  2. E. T. Ryan, H-M. Ho, W-L. Wu, P. S. Ho, D. W. Gidley, and J. Drage, IITC Proc. 187 (1999).

    Article  CAS  Google Scholar 

  3. E. T. Ryan, S. Lin, D. Nelsen, J. Wetzel, D. Gidley, and J. Drage, Adv. Metal. Conf. Proc. (2000, in press).

    Google Scholar 

  4. E. Kondoh, M. R. Baklanov, H. Bender, and K. Maex, Electrochem. Solid-State Lett. 1, 224 (1998).

    Google Scholar 

  5. R. K. Iler, The Chemistry of Silica (Wiley, New York, 1979).

    Article  CAS  Google Scholar 

  6. E. T. Ryan, S. Lin, and J. Wetzel (unpublished).

    Google Scholar 

  7. T. C. Chang, P. T. Liu, Y. S. Mor, S. M. Sze, Y. L. Yang, M. S. Feng, F. M. Pan, B. T. Dai, and C. Y. Chang, J. Electrochem. Soc. 146, 3802 (1999).

  8. P. T. Liu, T. C. Chang, Y. S. Mor, and S. M. Sze, Jpn. J. Appl. Phys. 38, 3482 (1999).

    Article  CAS  Google Scholar 

  9. P. T. Liu, T. C. Chang, Y. L. Yang, Y. F. Cheng, and S. M. Sze, IEEE Trans. Elect. Dev. 47, 1733 (2000).

    Article  CAS  Google Scholar 

  10. D. W. Gidley, W. E. Frieze, T. L. Dull, A. F. Yee, H. M. Ho, and E. T. Ryan, Phys. Rev. B 60, R5157 (1999).

    Article  CAS  Google Scholar 

  11. Data provided by the material supplier.

    Article  CAS  Google Scholar 

  12. Unpublished SEMATECH data.

  13. M.P. Siegal, J.M. Phillips., Y-F. Hsieh, and J.H. Marshall., Physica C 172, 282 (1990).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. Todd Ryan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ryan, E.T., Martin, J., Junker, K. et al. Effect of material properties on integration damage in organosilicate glass films. Journal of Materials Research 16, 3335–3338 (2001). https://doi.org/10.1557/JMR.2001.0458

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2001.0458

Navigation