Abstract
Four samples of TiO2 ultrafine particles (UFP) were obtained through different processes. The structure of TiO2 ultrafine particles and the factors influencing the structure were investigated with Raman spectroscopy, Fourier transform infrared (FTIR) spectroscopy, and x-ray diffraction (XRD). Both Raman spectra and x-ray diffractograms show the similar regularity of the phase transformation among the four samples. The observed bimodal lineshape-structure in the Raman spectra is attributed to the intragrain and grain-boundary components of TiO2 UFP. The crystal structure of TiO2 UFP is found to be distorted by the surface structure such as OH and OCH2CH3 groups coordinated on the surface of TiO2 UFP.
Similar content being viewed by others
References
U. Herr, J. Jing, R. Birringer, U. Gonser, and H. Gleiter, Appl. Phys. Lett. 50, 472 (1987).
C. Kormann, D.W. Bahnemann, and M.R. Hoffmann, J. Phys. Chem. 92, 5196 (1988).
R. Campostrini, G. Carturan, L. Palmisano, M. Schiavello, and A. Scalafani, Mater. Chem. Phys. 38, 277 (1994).
E. Haro-Poniatowski, R. Rodriguez-Talavera, M. De La Cruz Hevedia, O. Cano-Corona, and R. Arroyo-Murillo, J. Mater. Res. 9, 2102 (1994).
M. H. Suhail, G. Monan Rao, and S. Mohan, J. Appl. Phys. 71, 1421 (1992).
G. X. Yang, H. R. Zhuang, and P. Biswas, Nanostruct. Mater. 7 (6), 675 (1996).
C.A. Melendres, A. Narayanasamy, V.A. Maroni, and R.W. Siegel, J. Mater. Res. 4, 1246 (1989).
H. Komazawa, H. Otsuki, and E. Sada, J. Mater. Sci. Lett. 12, 839 (1993).
D. C. Hague and M. J. Mayo, J. Am. Ceram. Soc. 77 (7), 1957 (1994).
J. C. Parker and R. W. Siegel, J. Mater. Res. 5, 1246 (1990).
T. Ohsaka, S. Yamaoka, and O. Shimomura, Solid State Commun. 30, 345 (1979).
K. Tanaka and J. M. White, J. Phys. Chem. 86, 4708 (1982).
M. Primet, P. Pichat, and M. V. Mathieu, J. Phys. Chem. 75, 1216 (1971).
R. J. Capwell, F. Spagnolo, and M. A. Desena, Appl. Spectrosc. 26 (5), 537 (1972).
J. H. Hang, L. Gao, J. Y. Chen, and D. S. Yan, J. Inorg. Mater. 11 (1), 51 (1996).
W. T.Pawlewicz, G. J. Exarhos, and W.E. Conaway, Appl. Opt. 22 (12), 1837 (1983).
K. Nakanshi and P. H. Solomon, Infrared Absorption Spectroscopy, 2nd ed. (Holden-Day, Inc., 500 Sansome Street, San Francisco, Ca, 1977) p. 14.
R. W. Adams, R. L. Martion, and G. Winter, Aust. J. Chem. 20, 773 (1967).
S. Doeuff, M. Henry, C. Sanchez, and J. Livage, J. Non-Cryst. Solids 89, 206 (1987).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed. (John Wiley & Sons Inc., New York, 1986), p. 230.
T. Mütschele and R. Kirchheleim, Scripta Metall. 21, 1101 (1987).
J. F. Meng, G. T. Zou, Q. L. Cui, X. Li, J. X. Tang, and M. Y. Zhuo, Acta Physica Sinica 42 (12), 2014 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zhu, Y., Liu, T. & Ding, C. Structural characterization of TiO2 ultrafine particles. Journal of Materials Research 14, 442–446 (1999). https://doi.org/10.1557/JMR.1999.0063
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1999.0063