Abstract
A systematic investigation has been made on surface defect states of crystallites in the crystallization process of sputtered amorphous silicon films by isothermal annealing. Transmission electron microscopic observations indicate a pronounced vertical columnar structure in the upper part of the films, where the crystallization is delayed. Admittance spectroscopy reveals that two newly generated energy levels with the crystallization are attributed to the crystallites in the lower and upper parts of the films in view of the anisotropic crystallization. These thermally induced changes can be well explained by Si–Si shearing modes at the interfaces of crystallites through the process of crystallization.
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References
J. Werner, W. Jantsch, and H. J. Queisser, Solid State Commun. 42, 415 (1982).
W.B. Jackson, N.M. Johnson, and D. K. Biegelsen, Appl. Phys. Lett. 43, 195 (1983).
J. Werner and M. Peisl, Phys. Rev. B 31, 6881 (1985).
Z. Iqbal and S. Veprek, J. Phys. C.: Solid State Phys. 15, 377–392 (1982).
K.G. Kanellis, J.F. Morhange, and M. Balkanski, Phys. Rev. B 21, 1543 (1980).
R. Tsu, J.G. Hernandez, S.S. Chao, S. C. Lee, and K. Tanaka, Appl. Phys. Lett. 40, 534 (1982).
N.M. Johnson, D.K. Biegelsen, M. D. Moyer, and S. T. Chang, Appl. Phys. Lett. 43, 563 (1983).
P. Danesh, A. Szekeres, and S. Kaschieva, Solid-State Electronics 38, 1179 (1995).
M. Kohyama and R. Yamamoto, Phys. Rev. B 50, 8502 (1994).
M. Kohyama, J. Phys.: Condens. Matter 3, 2193 (1991).
Y. Nakano, J. Sakata, and Y. Taga, unpublished.
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Nakano, Y., Sakata, J. & Taga, Y. Formation process of interface states at grain boundaries in sputtered polycrystalline Si films. Journal of Materials Research 14, 371–376 (1999). https://doi.org/10.1557/JMR.1999.0054
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DOI: https://doi.org/10.1557/JMR.1999.0054