Abstract
Ion irradiation on polytetrafluoroethylene (PTFE) has been carried out to improve adhesions to metals and to adhesive cements. Argon ions were irradiated on the polymer, by varying the amount of Ar+ from 1 × 1014 ions/cm2 to 1 × 1017 ions/cm2 at 1 keV, and 4 ml/min of oxygen gas flowed near the polymer surface during the ion irradiation. The wetting angle of water on the PTFE surface was changed from 100° to 70–150°, depending on the ion beam condition. The changes of the wetting angle and effects of Ar+ irradiation in oxygen environment were explained by the changes in surface morphology due to the ion beam irradiation onto PTFE, and formation of a hydrophilic group due to a reaction between the irradiated polymer chain and the blown oxygen. Strongly enhanced adhesion is explained by interlock mechanism, formation of electron acceptor groups on the modified PTFE, and interfacial chemical reactions between the irradiated surface and the deposited materials.
Similar content being viewed by others
References
G. R. Rao and E. H. Lee, J. Mater. Res. 11, 2661 (1996).
O. Puglisi, A. Licciardello, L. Calcagno, and G. Foti, Nucl. Instrum. Methods B19/20, 865 (1987).
J. E. E. Baglin, Nucl. Instrum. Methods B65, 119 (1992).
F. Iacana, M. Garilli, G. Marletta, O. Puglisi, and S. Piganataro, J. Mater. Res. 6, 861 (1991).
J. E. Griffith, Y. Qiu, and T. A. Tombrello, Nucl. Instrum. Methods B198, 607 (1982).
S. Jacobson, B. Jonssen, and B. Sundqvist, Thin Solid Films 107, 89 (1983).
P. A. Ingemarsson, M. P. Keane, and U. Gelius, J. Appl. Phys. 66, 3548 (1989).
I. H. Loh, J. K. Hirvonen, J. R. Martin, P. Revesz, and C. Boyd, in Electronic Packaging Materials Science III, edited by R. Jaccodine, K. A. Jackson, and R. C. Sundahl (Mater. Res. Soc. Symp. Proc. 108, Pittsburgh, PA, 1988), p. 241.
C. J. Sofield, C. J. Woods, C. Wild, J. C. Riviere, and L. S. Welch, in Thin Films and Interfaces II, edited by J. E. E. Baglin, D. R. Campbell, and W. K. Chu (Mater. Res. Soc. Symp. Proc. 25, Elsevier Science Publishing, New York, 1984), p. 197.
P. A. Ingemarsson, T. Eriksson, R. Wappling, and G. Possnert, J. Adhesion Sci. Technol. 3, 503 (1989).
C. A. Chang, J. E. E. Baglin, A. G. Schrott, and K. C. Lin, Appl. Phys. Lett. 51, 103 (1987).
M. C. Wintergill, Nucl. Instrum. Methods B1, 595 (1984).
T. Venkatesan, L. Calcagno, B. S. Ellman, and G. Foti, Ion Beam Modification of Insulators, edited by P. Mazzoldi and G. W. Arnold (Elsevier, New York, 1987), pp. 301–379.
S. K. Koh, S. K. Song, W. K. Choi, H. J. Jung, and S. N. Han, J. Mater. Res. 10, 2390 (1995).
W. K. Choi, S. K. Koh, and H. J. Jung, J. Vac. Sci. Technol. A 14, 2366 (1996).
S. K. Koh, S. C. Park, S. R. Kim, W. K. Choi, H. J. Jung, and K. D. Pae, J. Appl. Polym. Sci., 1913 (1997).
D. Youxian and H. J. Griesser, Polymer 32, 1126 (1987).
D. T. Clark and D. R. Hutton, J. Polym. Sci. A25, 2643 (1987).
S. K. Koh, J. W. Seok, S. C. Choi, W. K. Choi, and H. J. Hung, private communication.
C. R. Ginnard and W. M. Riggs, Anal. Chem. 44, 1310 (1972).
T. J. Fabish and C. B. Duke, J. Appl. Phys. 48, 4256 (1977).
J. M. Burkstrand, J. Appl. Phys. 52, 4795 (1981).
K. Nakamae, S. Tanigawa, and T. Matsumoto, Metallized Plastics 1, edited by K. L. Mittal and J. R. Susko (Plenum Press, New York, 1989), pp. 235–245.
R. C. White, R. Haight, B. D. Silverman, and P. S. Ho, Appl. Phys. Lett. 51, 17 (1987).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Koh, S.K., Seok, J.W., Choi, S.C. et al. Enhancing adhesion between metals or epoxy and polytetrafluoroethylene by ion assisted reaction. Journal of Materials Research 13, 1363–1367 (1998). https://doi.org/10.1557/JMR.1998.0193
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1998.0193