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Synthesis of functional ceramic materials from aqueous solutions

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Abstract

Methods for synthesizing ceramic materials from aqueous solutions at ordinary temperature and pressure are advantageous because of the applicability to making films with wide areas and/or complicated shapes with no requirement of vacuum or high temperature, and because of lower cost. Powder of ZrO2 or LnMeO3 (Ln = La, Nd; Me = Cr, Mn, Fe, Co) perovskite was dissolved in hydrofluoric acid and a solution of fluoro-complex ions was obtained. Boric acid was added to the solution, the fluoride ions were consumed by the formation of BF4 -, and then the fluoro-complex ions were hydrolyzed to ZrO2 or LnMeO3 in order to increase the amount of fluoride ions. A number of synthesized particles of ZrO2 or LnMeO3 were observed on the substrates in scanning electron microscope images.

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Authors and Affiliations

  1. Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida, Sakyo-ku, Kyoto-shi, 606-01, Japan

    Takeshi Yao

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  1. Takeshi Yao
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Yao, T. Synthesis of functional ceramic materials from aqueous solutions. Journal of Materials Research 13, 1091–1098 (1998). https://doi.org/10.1557/JMR.1998.0150

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  • DOI: https://doi.org/10.1557/JMR.1998.0150

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