Abstract
The uncertainties inherent to experimental differential scanning calorimetric data are evaluated. A new procedure is developed to perform the kinetic analysis of continuous heating calorimetric data when the heat capacity of the sample changes during the crystallization. The accuracy of isothermal calorimetric data is analyzed in terms of the peak-to-peak noise of the calorimetric signal and base line drift typical of differential scanning calorimetry equipment. Their influence in the evaluation of the kinetic parameter is discussed. An empirical construction of the time-temperature and temperature-heating rate transformation diagrams, grounded on the kinetic parameters, is presented. The method is applied to the kinetic study of the primary crystallization of Te in an amorphous alloy of nominal composition Ga20Te80, obtained by rapid solidification.
Similar content being viewed by others
References
H. J. Borchardt and F. Daniels, J. Am. Chem. Soc. 79, 41 (1957).
E. S. Freeman and B. Carroll, J. Phys. Chem. 62, 394 (1958).
A. W. Coats and J. P. Redfern, Nature 201, 64 (1964).
P. Hugo, S. Wagner, and T. Gnewikiw Thermochim. Acta 225, 143 (1993).
M. T. Clavaguera-Mora, M. D. Baró, S. Suriñach, and N. Clavaguera, J. Mater. Res. 5, 1201 (1990).
S. Suriñach, M. D. Baró, J. A. Diego, N. Clavaguera, and M. T. Clavaguera-Mora, Acta Metall. Mater. 40, 37 (1992).
M. T. Clavaguera-Mora, S. Suriñach, M. D. Barò, and N. Clavaguera, J. Phys. D: Appl. Phys. 25, 803 (1992).
N. Clavaguera, J. Non-Cryst. Solids, 162, 40 (1993).
N. Clavaguera and M. T. Clavaguera-Mora, Mater. Sci. Eng. A179/180, 288 (1994).
C. S. Oh and D. N. Lee, Calphad 16, 317 (1992).
D. Mouani, G. Morgant, and B. Legendre, J. Alloys Comp. 226, 222 (1995).
H. E. Kissinger, Anal. Chem. 29, 1702 (1957).
T. Ozawa, Bull. Chem. Soc. Jpn. 38, 1881 (1965).
G. Fontana, H. Sirkin, M. Rosen, D. Kurlat, and E. Frank, Rev. Brasileira de Fisica 9, 1 (1979).
M. G. Fontana and B. Arcondo, J. Mater. Sci. 30, 734 (1995).
M. Fontana, Master Thesis, Universitat Autonoma de Barcelona, 1995.
U. Köster and U. Herold, in Glassy Metals I, edited by H. J. Güntherodt and H. Beck, Topics Appl. Phys. (Springer, Berlin, 1981), Vol. 46, p. 225.
R. F. Speyer, Thermal Analysis of Materials, (Marcel Dekker, 1994).
R. F. Speyer, J. Mater. Res. 8, 675 (1993).
J. W. Christian, Theory of Transformations in Metals and Alloys, 2nd ed. (Pergamon, Oxford, 1975).
D. W. Henderson, J. Non-Cryst. Solids 30, 301 (1979).
H. S. Chen, J. Non-Cryst. Solids 27, 257 (1978).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Clavaguera, N., Clavaguera-Mora, M.T. & Fontana, M. Accuracy in the experimental calorimetric study of the crystallization kinetics and predictive transformation diagrams: Application to a Ga–Te amorphous alloy. Journal of Materials Research 13, 744–753 (1998). https://doi.org/10.1557/JMR.1998.0094
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1998.0094