Combustion synthesis of boron nitride powder

Abstract

A combustion synthesis (SHS) process developed in our previous study for the synthesis of Si₃N₄ has been tested for the synthesis of boron nitride (BN) powder. Boron and NaN₃ powders were used as the reactants. In addition to ammonium halides, KHF₂, FeCl₃, NaNH₂, or a mixture of 50 mol% FeCl₃ and 50 mol% NaNH₂ was added to the reactants to examine their catalytic effect. These powders were mixed and pressed into a cylindrical compact. The compact was wrapped up with an igniting agent (i.e., Mg + Fe₃O₄) and the synthesis reaction was triggered by the combustion of the igniting agent. It was found that only those reagents containing both halogen and hydrogen can exert effectively the catalytic effect. The BN powder as-synthesized is mostly in the form of agglomerated fine particles (0.1–1 μm in diameter) and is hexagonal in crystalline structure. Effects of various experimental parameters on the product yield were investigated. A possible reaction mechanism was proposed, which explains the effects of the experimental parameters on the synthesis reaction.