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The oxygen deficiency effect of VO2 thin films prepared by laser ablation

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Abstract

Vanadium dioxide thin films (VO2) have been deposited by laser ablation. The temperature dependence of resistivity and temperature coefficient of resistance (TCR) for each deposition condition were investigated. It was clarified that the TCR at room temperature (RT) can be optimized by controlling the oxygen pressure introduced during deposition as the deposition parameter. In the result, larger TCR’s at RT were observed for the oxygen deficient condition of VO2 than for oxygen-richer samples. Obtained TCR values were 0.072/K and 0.045/K at 25°C for VO2 thin films deposited onto R-cut sapphire and SiO2/Si, respectively.

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References

  1. K. Kosuge, J. Phys. Chem. Solids 28, 1613 (1967).

    Article  CAS  Google Scholar 

  2. J. F. DeNatale, P. J. Hood, and A. B. Harker, J. Appl. Phys. 66, 5844 (1989).

    Article  CAS  Google Scholar 

  3. E. E. Chain, J. Vac. Sci. Technol. A 4, 432 (1986).

    Article  CAS  Google Scholar 

  4. K. D. Rogers, J. A. Coath, and M. C. Lovell, J. Appl. Phys. 70, 1412 (1991).

    Article  CAS  Google Scholar 

  5. F. C. Case, J. Vac. Sci. Technol. A 7, 1194 (1989).

    Article  CAS  Google Scholar 

  6. D. P. Partlow, S. R. Gurkovich, K. C. Radford, and L. J. Denes, J. Appl. Phys. 70, 443 (1991).

    Article  CAS  Google Scholar 

  7. E. Kusano and J. A. Theil, J. Vac. Sci. Technol. A 7, 1314 (1989).

    Article  CAS  Google Scholar 

  8. S. E. Nikitin, I. A. Khakhaev, F. A. Chudnovskiǐ, and E. B. Shadrin, Phys. Solid State 35, 1393 (1993).

    Google Scholar 

  9. C. H. Griffiths and H. K. Eastwood, J. Appl. Phys. 45, 2201 (1974).

    Article  CAS  Google Scholar 

  10. H. Jerominek, F. Picard, and D. Vincent, Optical Eng. 32, 2092 (1993).

    Article  CAS  Google Scholar 

  11. F. C. Case, J. Vac. Sci. Technol. A 2, 1509 (1984).

    Article  CAS  Google Scholar 

  12. C. B. Greenberg, Thin Solid Films 110, 73 (1983).

    Article  CAS  Google Scholar 

  13. L. A. Ladd and W. Paul, Solid State Commun. 7, 425 (1969).

    Article  CAS  Google Scholar 

  14. M. Borek, F. Qian, V. Nagabushnam, and R. K. Singh, Appl. Phys. Lett. 63, 3288 (1993).

    Article  CAS  Google Scholar 

  15. D. H. Kim and H. S. Kwok, Appl. Phys. Lett. 65, 3188 (1994).

    Article  CAS  Google Scholar 

  16. F. Théobald, R. Cabala, and J. Bernard, J. Solid State Chem. 17, 431 (1976).

    Article  Google Scholar 

  17. D. Adler, in Solid State Physics, edited by F. Seitz, D. Turnbull, and H. Ehrenreich (Academic Press, New York, 1968), Vol. 21, p. 1.

  18. M. Fukuma, S. Zembutsu, and S. Miyazawa, Appl. Opt. 22, 265 (1983).

    Article  CAS  Google Scholar 

  19. C. C. Y. Kwan, C. H. Griffiths, and H. K. Eastwood, Appl. Phys. Lett. 20, 93 (1972).

    Article  CAS  Google Scholar 

  20. H. Futaki and M. Aoki, Jpn. J. Appl. Phys. 8, 1008 (1969).

    Article  CAS  Google Scholar 

  21. R. L. Remke, R. M. Walser, and R. W. Bené, Thin Solid Films 61, 73 (1979).

    Article  CAS  Google Scholar 

  22. G. A. Nyberg and R. A. Buhrman, J. Vac. Sci. Technol. A 2, 301 (1984).

    Article  Google Scholar 

  23. J. B. Macchesney and H. J. Guggenheim, J. Phys. Chem. Solids 30, 225 (1969).

    Article  CAS  Google Scholar 

  24. J. B. Goodenough, J. Solid State Chem. 3, 490 (1971).

    Article  CAS  Google Scholar 

  25. A. Zylbersztejn and N. F. Mott, Phys. Rev. B 11, 4383 (1975).

    Article  CAS  Google Scholar 

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Nagashima, M., Wada, H. The oxygen deficiency effect of VO2 thin films prepared by laser ablation. Journal of Materials Research 12, 416–422 (1997). https://doi.org/10.1557/JMR.1997.0061

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  • DOI: https://doi.org/10.1557/JMR.1997.0061

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