Skip to main content
Log in

The effect of Hf and Ti additions on microstructure and properties of Cr2Nb–Nb in situ composites

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

The present paper describes the effect of Hf and Ti additions on the microstructures and mechanical properties of two-phase composites based on the Cr2Nb–Nb eutectic. The microstructures of directionally solidified in situ composites containing 50–70% by volume of the Laves phase Cr2Nb which was modified with Hf (7.5–9.2%) and Ti (16.5–26%) are described. Partitioning of Hf and Ti between the two phases is discussed using microprobe and EDS results. The tensile properties at 1100 and 1200 °C are described and compared with those of an analogous niobium silicide-based composite. The Cr2(Nb)–(Nb) composite tensile yield strengths at 1200 °C were increased over that of monolithic Cr2Nb to ∼130 MPa. However, at 1200 °C the yield strengths of the silicide-based composites were approximately twice those of the Cr2(Nb)–(Nb) composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. L. Anton and D. M. Shah, Mater. Sci. Eng. A153, 410–415 (1992).

    Article  CAS  Google Scholar 

  2. D. L. Anton and D. M. Shah, in High-Temperature Ordered Intermetallic Alloys IV, edited by L. A. Johnson, D. A. Pope, and J. O. Stiegler (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), pp. 733–738.

  3. H. J. Goldschmidt and J. A. Brand, J. Less-Comm. Met. 3, 44–61 (1961).

    Article  CAS  Google Scholar 

  4. R. L Fleischer, C. L. Briant, and R. D. Field, in High-Temperature Ordered Intermetallic Alloys IV, edited by L. A. Johnson, D.A. Pope, and J. O. Stiegler (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), pp. 463–474.

  5. B. P. Bewlay, J. A. Sutliff, M. R. Jackson, and H.A. Lipsitt, Acta Metall. Mater. 42 (8), 2869–2878 (1994).

    Article  CAS  Google Scholar 

  6. B. P. Bewlay, H. A. Lipsitt, M. R. Jackson, W. J. Reeder, and J. A. Sutliff, Mater. Sci. Eng. A192/193, 534–543 (1995).

    Article  Google Scholar 

  7. M. Takeyama and C.T. Liu, Mater. Sci. Eng. A132, 61–66 (1991).

    Article  CAS  Google Scholar 

  8. T. Takasugi, S. Hanada, and K. Miyamoto, J. Mater. Res. 8, 3069–3077 (1993).

    Article  CAS  Google Scholar 

  9. M. R. Jackson and K. D. Jones, in Refractory Metals Extraction, Processing and Applications, edited by K. C. Liddell, D.R. Sadoway, and R. G. Bautista (TMS Publications, Warrendale, PA, 1991), pp. 310–320.

    Google Scholar 

  10. B. P. Bewlay and M. R. Jackson unpublished.

  11. M. R. Jackson, D. W. Skelly, and R. G. Rowe Annual Reports, WRDC Contract #F33615-91-C-5613 (1994, 1995).

  12. M. Venkatraman and J. P. Neumann, Bull. Alloy Phase Diagrams 7 (5), 462–466 (1986).

    Article  CAS  Google Scholar 

  13. D.J. Thoma and J. H. Perepezko, in Intermetallic Matrix Composites, edited by D. L. Anton, P. L. Martin, D. B. Miracle, and R. McMeeking (Mater. Res. Soc. Symp. Proc. 194, Pittsburgh, PA, 1990), pp. 105–112.

  14. D.J. Thoma and J. H. Perepezko, Mater. Sci. Eng. A156, 97–108 (1992).

    Article  CAS  Google Scholar 

  15. T. B. Massalski, Binary Alloy Phase Diagrams (ASM INTERNATIONAL, Materials Park, OH, 1991).

    Google Scholar 

  16. D. L. Davidson and K.S. Chan, AFOSR Final Report (April 1995).

  17. K. S. Kumar and D. B. Miracle, Intermetallics 2, 257–274 (1994).

    Article  CAS  Google Scholar 

  18. K.S. Ravichandran, D. B. Miracle, and M. G. Mendiratta, in Intermetallic Matrix Composites III, edited by J. A. Graves, R. R. Bowman, and J.J. Lewandowski (Mater. Res. Soc. Symp. Proc. 350, Pittsburgh, PA, 1994), pp. 249–254.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bewlay, B.P., Jackson, M.R. The effect of Hf and Ti additions on microstructure and properties of Cr2Nb–Nb in situ composites. Journal of Materials Research 11, 1917–1922 (1996). https://doi.org/10.1557/JMR.1996.0242

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.1996.0242

Navigation