Abstract
In this work a hypothesis to explain the alkaline hydrolysis degradation process of calcium aluminate cement concrete (CACC) is presented. The hypothesis is based on x-ray diffraction (XRD) data of some samples taken from real Spanish CACC structures. The identification from XRD data of a hydrated alkaline aluminate could serve as a guide to differentiate both processes of normal carbonation and alkaline hydrolysis.
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References
A. Neville, High Alumina Cement Concrete (The Construction Press, Great Britain, 1975).
G. Rehm, Zement-Kalk-Gips 17 (3), March (1964).
Ministers für Landesplanung, Wohnungsbau und offentliche arbeiten NordrheinWestfalen, Verwendung von Tonerdeschmelzzement. Publication IIB2-2323, No. 179/62, Ministerialblatt NRW, issue A15 (95), 1413 (1962).
S. C. C. Bate, Report on the failure of roof beams at Sir John Cass’s Foundation and Red Coat Church of England Secondary School, Stepney, BRE CP 58, 18 (1974).
Department of Education and Science, Report on the collapse of the roof of the assembly hall of the Camden School for Girls (H.M.S.O., London, BRE, 16 1973).
F. M. Lea, Trans. Soc. Chem. Ind. 59, 18 (1940).
P. Stiglitz, Silicates Industriels, 93 (1972).
C. M. George, Mater. Constr. 701, 201 (1976).
C. del Olmo, Revista Iberoamericana de Corrosión y Protección, April, 201 (1976).
T. Vázquez, F. Triviño, and A. Ruiz de Gauna, Monography at the Eduardo Torroja Institute, IccET, No. 334 (1976).
ITEC, Recomendaciones para el reconocimiento sistemático y la diagnosis rápida de viguetas construídas con cemento aluminoso, Generalitat de Cataluña (1991).
V. Seguí, private conference, Curso de Reparación de Obras de Hormigón, Bilbao, Spain, January (1992).
T. Vázquez, F. Triviño, and A. Ruiz de Gauna, Mater. Constr. 157, 43 (1975).
T. Vázquez, F. Triviño, and A. Ruiz de Gauna, Mater. Constr. 158, 5 (1975).
M. Pérez, T. Vázquez, and F. Triviño, Cem. Concr. Res. 13, 759 (1983).
M. Pérez, T. Vázquez, and F. Triviño, Cem. Concr. Res. 14, 1 (1984).
M. Pérez and F. Triviño, Cem. Concr. Res. 14, 161 (1984).
M. Pérez, F. Triviño, and C. Andrade, Mater. Constr. 182, 46 (1981).
E. Raask, in Proc. Int. Symp. on the Carbonation of Concrete. Cem Concr. Association, Slough, UK (1976).
R. D. Blenkinsop, B. R. Currell, H. G. Midgley, and J. R. Parsonage, Cem. Concr. Res. 15, 276 (1985).
M. Duriez, in Traité de Matériaux de Construction (Editions du Moniteur des Travaux Publics, Paris, 1957).
Anon, New Civil Engineer., 10 February (1974).
A. G. Elliot and R. H. Robert, J. Am. Ceram. Soc. 58, 497 (1975).
R. S. Barneyback and S. Diamond, Cem. Concr. Res. 11, 279 (1981).
S. Diamond, Cem. Concr. Res. 11, 383 (1981).
M. T. Gaztañaga, S. Goñi, and J. L. Sagrera, Solid State Ionics 63–65, 797 (1993).
S. Goñi, M. T. Gaztañaga, and J. L. Sagrera, J. Mater. Res. 9, 1533 (1994).
S. Chinchón, Jornades tecniques sobre el ciment aluminós i els seus prefabricats, Collegi d’Aparelladors i Arquitectes Técnics de Barcelona (April 1991).
H. P. Rooksby, in Oxides and Hydroxides of Aluminum and Iron (Mineralogical Society, London, 1961), p. 354.
R. Schoen and E. C. Roberson, Am. Miner. 55, 43 (1970).
R. A. Van Nordstrand, W. P. Hettinger, and C. D. Keith, Nature (London) 177, 713 (1956).
D. Papée, R. Tertian, and R. Biais, Bull. Soc. Chim. Fr., 1301 (1958).
H. Saalfeld and O. Jarchoma. Neus Jahrb. Mineral. Abhandl 109, 185 (1986).
B. J. Linsen, Physical and Chemical Aspects of Adsorbents and Catalysts (Academic Press, London, 1970).
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Goñi, S., Andrade, C., Sagrera, J.L. et al. A new insight on alkaline hydrolysis of calcium aluminate cement concrete: Part I. Fundamentals. Journal of Materials Research 11, 1748–1754 (1996). https://doi.org/10.1557/JMR.1996.0219
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DOI: https://doi.org/10.1557/JMR.1996.0219