Abstract
Two techniques are described for synthesizing nanometer-sized TiB2 particles by gas-phase combustion reactions of sodium vapor with TiCl4 and BCl3: a low-pressure, low-temperature burner and a high-temperature flow reactor. Both methods produce TiB2 particles that are less than 15 nm in diameter. The combustion by-product, NaCl, is efficiently removed from the TiB2 by water washing or vacuum sublimation. Material collected from the low-temperature burner and annealed at 1000 °C consists of loosely agglomerated particles 20 to 100 nm in size. Washed material from the high-temperature flow reactor consists of necked agglomerates of 3 to 15 nm particles. A thermodynamic analysis of the Ti/B/Cl/Na system indicates that near 100% yields of TiB2 are possible with appropriate reactant concentrations, pressures, and temperatures.
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Axelbaum, R.L., DuFaux, D.P., Frey, C.A. et al. Gas-phase combustion synthesis of titanium boride (TiB2) nanocrystallites. Journal of Materials Research 11, 948–954 (1996). https://doi.org/10.1557/JMR.1996.0119
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DOI: https://doi.org/10.1557/JMR.1996.0119