Skip to main content
Log in

Chromium implantation in silica glass

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Silica glass was implanted with chromium at the energy of 35 and 160 keV and at fluences varying from 1 × 1016 to 11 × 1016 ions cm−2. In a set of chromium-implanted samples significant amounts of carbon were detected. Samples were characterized by x-ray photoelectron spectroscopy, x-ray-excited Auger electron spectroscopy, secondary ion mass spectrometry, and Rutherford backscattering spectrometry. Chromium silicide and chromium oxide compounds were observed; the presence of carbon in the implanted layers induces the further formation of chromium carbide species. Thermodynamic considerations applied to the investigated systems supply indications in agreement with the experimental evidences.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G. W. Arnold and P. Mazzoldi, in Ion Beam Modifications of Insulators, edited by P. Mazzoldi and G. W. Arnold (Elsevier, Amsterdam, 1987), p. 222 and references therein.

  2. R. A. Weeks, in Glasses and Amorphous Materials, edited by J. Zarzycki (VCH, Weinheim, 1991), p. 331 and references therein.

  3. P. Mazzoldi, G. W. Arnold, G. Battaglin, R. Bertoncello, and F. Gonella, Nucl. Instrum. Methods B91, 478 (1994) and references therein.

    Google Scholar 

  4. G. Battaglin, in Modifications Induced by Irradiation of Glasses, edited by P. Mazzoldi (Elsevier, Amsterdam, 1992), p. 11 and references therein.

  5. A. Carnera, P. Mazzoldi, A. Boscolo-Boscoletto, F. Caccavale, R. Bertoncello, G. Granozzi, I. Spagnol, and G. Battaglin, J. Non-Cryst. Solids 125, 293 (1990).

    Article  CAS  Google Scholar 

  6. T. Tagami, K. Oyoshi, and S. Tanaka, in Processing and Characterization of Materials Using Ion Beams, edited by L. E. Rehn, J. Greene, and F. A. Smidt (Mater. Res. Soc. Symp. Proc. 128, Pittsburgh, PA, 1989), p. 519 and in Beam-Solid Interactions: Physical Phenomena, edited by J. A. Knapp, P. Borgesen, and R. A. Zuhr (Mater. Res. Soc. Symp. Proc. 157, Pittsburgh, PA, 1990), p. 149.

    Google Scholar 

  7. G. W. Arnold, R. K. Brow, and D. R. Myers, J. Non-Cryst. Solids 120, 234 (1990).

    Article  CAS  Google Scholar 

  8. K. Oyoshi, T. Tagami, and S. Tanaka, J. Appl. Phys. 68, 3653 (1990).

    Article  CAS  Google Scholar 

  9. H. Hosono, Y. Abe, K. Oyoshi, and S. Tanaka, Phys. Rev. B 43, 1193 (1991).

    Article  Google Scholar 

  10. P. Mazzoldi, A. Carnera, F. Caccavale, M. L. Favaro, A. Boscolo-Boscoletto, G. Granozzi, R. Bertoncello, and G. Battaglin, J. Appl. Phys. 70, 3528 (1991).

    Article  CAS  Google Scholar 

  11. H. Hosono, Nucl. Instrum. Methods B65, 375 (1992).

    Article  CAS  Google Scholar 

  12. G. Battaglin, A. Boscolo-Boscoletto, F. Caccavale, G. De Marchi, P. Mazzoldi, and G. W. Arnold, in Modifications Induced by Irradiation of Glasses, edited by P. Mazzoldi (Elsevier, Amsterdam, 1992), p. 91.

    Book  Google Scholar 

  13. R. H. Magruder III, C. W. White, R. A. Zuhr, Lena Yang, R. Dorsinville, and R. R. Alfano, Nucl. Instrum. Methods B91, 493 (1994) and references therein.

    Google Scholar 

  14. R. Bertoncello, A. Glisenti, G. Granozzi, G. Battaglin, E. Cattaruzza, and P. Mazzoldi, in Materials Modification by Energetic Atoms and Ions, edited by K. S. Grabowski, S. A. Barnett, S. M. Rossnagel, and K. Wasa (Mater. Res. Soc. Symp. Proc. 268, Pittsburgh, PA, 1992), p. 325.

    Google Scholar 

  15. R. Bertoncello, A. Glisenti, G. Granozzi, G. Battaglin, F. Caccavale, E. Cattaruzza, and P. Mazzoldi, J. Non-Cryst. Solids 162, 205 (1993).

    Article  CAS  Google Scholar 

  16. Thermochemical Properties of Inorganic Substances, 2nd ed., edited by O. Knacke, O. Kubaschewski, and K. Hesselmann (Springer-Verlag, Berlin, Heidelberg, 1991).

  17. H. Hosono and R. Weeks, Phys. Rev. B 40, 10543 (1989).

    Article  CAS  Google Scholar 

  18. G. Whichard and R. A. Weeks, J. Non-Cryst. Solids 112, 1 (1989).

    Article  Google Scholar 

  19. H. Hosono, R. A. Weeks, H. Imagawa, and R. A. Zuhr, J. Non-Cryst. Solids 120, 250 (1990).

    Article  CAS  Google Scholar 

  20. R. H. Magruder III, S. H. Morgan, R. A. Weeks, and R. A. Zuhr J. Non-Cryst. Solids 120, 241 (1990).

    Article  Google Scholar 

  21. J. P. Biersack and L. G. Haggmark, Nucl. Instrum. Methods 174, 257 (1980).

    Article  CAS  Google Scholar 

  22. D. Briggs and M. P. Seah, Practical Surface Analysis (J. Wiley & Sons, Chichester, U.K., 1983).

    Google Scholar 

  23. X-ray Photoelectron Spectroscopy Database, version 1.0 (National Institute of Standards and Technology, Gaithersburg, MD 20899, 1989).

  24. J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben, Handbook of X-ray Photoelectron Spectroscopy, edited by J. Chastain (Perkin-Elmer Corp., Eden Prairie, MN, 1992).

    Google Scholar 

  25. M. F. Koenig and J. T. Grant, Surf. Interf. Anal. 7, 217 (1985).

    Article  CAS  Google Scholar 

  26. D. A. Shirley, Phys. Rev. 55, 4709 (1972).

    Article  Google Scholar 

  27. J. J. Yeh and I. Lindau, Atomic Data and Nuclear Data Tables 32, 1 (1985).

    Article  CAS  Google Scholar 

  28. G. Ottaviani, Thin Solid Films 140, 3 (1986).

    Article  CAS  Google Scholar 

  29. P. Wetzel, C. Pirri, J. C. Peruchetti, D. Bolmont, and G. Gewinner, Phys. Rev. B 35, 5880 (1987).

    Article  CAS  Google Scholar 

  30. L. Haderbache, P. Wetzel, C. Pirri, J. C. Peruchetti, D. Bolmont, and G. Gewinner, Surf. Sci. 209, L139 (1989).

    Article  CAS  Google Scholar 

  31. F. Maury and F. Ossola, Thin Solid Films 207, 82 (1992).

    Article  CAS  Google Scholar 

  32. G. D. Sorarù, A. Glisenti, G. Granozzi, F. Babonnea, and J. D. Mackenzie, J. Mater. Sci. 5, 1958 (1990).

    Google Scholar 

  33. P. Mazzoldi, F. Caccavale, E. Cattaruzza, A. Boscolo-Boscoletto, R. Bertoncello, A. Glisenti, G. Battaglin, and C. Gerardi, Nucl. Instrum. Methods B65, 367 (1992).

    CAS  Google Scholar 

  34. R. Bertoncello, F. Trivillin, E. Cattaruzza, P. Mazzoldi, G. W. Arnold, G. Battaglin, and M. Catalano, J. Appl. Phys. 77 (3), 1294 (1995).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cattaruzza, E., Bertoncello, R., Trivillin, F. et al. Chromium implantation in silica glass. Journal of Materials Research 11, 229–235 (1996). https://doi.org/10.1557/JMR.1996.0028

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.1996.0028

Navigation