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Processing of calcium metaphosphate-based glass-ceramic coatings on alumina

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Abstract

Dense, crystalline, glass-ceramic coatings containing calcium metaphosphate and aluminum phosphate were prepared on aluminum oxide substrates by a three-step method. The processing involved glass (40 mol% CaO, 10 mol% Al2O3, 50 mol% P2O5) formation, deposition of a glass particle coating, and heat treatment to sinter the glass and crystallize the phosphates. Sintering and microstructure evolution were influenced by wet coating thickness, heat-treatment temperature, time, and heating rate. Heat treatment for 1 h at 725 °C using a 50 °C/min heating rate was found to give a dense, crack-free coating. The resultant coating microstructure has spherulitic morphology (0.3 μm size) with aluminum phosphate in the center of the spherulite. The hardness of the fully crystallized glass-ceramic coating was ∼5.2 GPa.

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Authors and Affiliations

  1. Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota, 55455-0132, USA

    K. J. Vaidya & L. F. Francis

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  1. K. J. Vaidya
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  2. L. F. Francis
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Vaidya, K.J., Francis, L.F. Processing of calcium metaphosphate-based glass-ceramic coatings on alumina. Journal of Materials Research 11, 100–109 (1996). https://doi.org/10.1557/JMR.1996.0013

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  • DOI: https://doi.org/10.1557/JMR.1996.0013

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