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Activated carbon for control of nitrogen oxide emissions

Abstract

Activated carbons were used to selectively remove NOx from simulated flue gas at temperatures between 25 and 125 °C. Processing conditions and physical/chemical characteristics of the carbons which affected NOx adsorption, storage, and release were investigated. Oxygen as a coreactant was necessary to maximize the conversion of NO to NO2 and condensation of NO2 within the pores of the carbons. A NO-to-NO2 conversion mechanism is presented and discussed relative to previous research. A process for selectively removing NOx and concentrating it as NO2 in an alternate process stream is outlined. The purified NO2 stream could be used for chemicals manufacturing.

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References

  1. S. Knott and G. Offen, Environmental Update, 10–23 (Jan. 1993).

  2. H. Bosch and F. Janssen, Catal. Today 2, 369 (1988).

    CAS  Article  Google Scholar 

  3. S.K. Gangwal, G.B. Howe, J.J. Spivey, P.L. Silveston, R.R. Hudgins, and J. G. Metzinger, Environ. Prog. 12, 128 (1993).

    CAS  Article  Google Scholar 

  4. H. Juentgen, K. Knoblauch, E. Richter, and H. J. Juergen, FRG Patent 3,512,168 (1986).

  5. T. Grzybek and H. Papp, Appl. Catal. B, Environ. 1, 271 (1992).

    CAS  Article  Google Scholar 

  6. H. Gutberlet, VGB Kraftwerkstech 68, 287 (1988).

    CAS  Google Scholar 

  7. P. A. Lowe and M. Perlsweig, Proc. Am. Power Conf. 52, 584 (1990).

    CAS  Google Scholar 

  8. F. Radtke, R.A. Koeppel, and A. Baiker, Appl. Catal. A, Gen. 107, L125 (1994).

    CAS  Article  Google Scholar 

  9. W. F. DeGroot, T. H. Osterheld, and G. N. Richards, Carbon 29, 185 (1991).

    CAS  Article  Google Scholar 

  10. H. Hamashita, H. Yamada, and A. Tomita, Appl. Catal. 78, L1 (1991).

    Article  Google Scholar 

  11. J.M. Schwartz and L.D. Schmidt, J. Catal. 148, 22 (1994).

    CAS  Article  Google Scholar 

  12. E. Richter, H-J. Schmidt, and H.G. Schecker, Chem. Eng. Technol. 13, 332 (1990).

    CAS  Article  Google Scholar 

  13. A.M. Rubel, J.M. Stencel, and S.N. Ahmed, Preprints Symposium on Flue Gas Cleanup Processes (ACS, Division of Fuel Chem., Denver, CO, 1993), Vol 38 (2), pp. 726–733.

    Google Scholar 

  14. A.M. Rubel, J.M. Stencel, and S.N. Ahmed, Proceeding of the 1993 AIChE Summer National Meeting (AIChE, Seattle, WA, 1993), Paper no. 77b.

    Google Scholar 

  15. A.M. Rubel, M.L. Stewart, and J.M. Stencel, Preprints Symposium on NOx Reduction (ACS, Division of Petroleum Chem., San Diego, CA 1994), Vol. 39 (1), pp. 137–140.

    Google Scholar 

  16. S. Brunauer, P. H. Emmett, and E. Teller, J.A.M. Chem. Soc. 60, 309 (1938).

    CAS  Article  Google Scholar 

  17. H. Teng and E.M. Suuberg, J. Phys. Chem. 97 478 (1993).

    CAS  Article  Google Scholar 

  18. H. Teng, E.M. Suuberg, J.M. Calo, and P.J. Hall, Proc. 19th Conf. on Carbon (1989), p. 574.

  19. M.N. Rao and O.A. Hougen, Chem. Eng. Prog. 48, 110 (1952).

    CAS  Google Scholar 

  20. P. G. Gray, N. J. Desai, and D. D. Do, in Recent Trends in Chem. Reaction Eng., edited by B.D. Kulkarni, R.A. Mashelkar, and M.M. Sharma (John Wiley Eastern Ltd., 1987), Vol. 1, p. 383.

  21. Z.M. Wang, N. Shindo, Y. Otake, and K. Kaneko, Carbon 32, 515 (1994).

    CAS  Article  Google Scholar 

  22. N. Kakuta, S. Sumiya, and K. Yoshida, Catal. Lett. 11, 71 (1991).

    CAS  Article  Google Scholar 

  23. K. Kaneko and J. Imai, Carbon 26, 954 (1989).

    Article  Google Scholar 

  24. C.U.I. Odenbrand, L.A.H. Andersson, J.G.M. Brandin, and S. Jaras, Catal. Today 4, 155 (1989).

    CAS  Article  Google Scholar 

  25. J.G.M. Brandin, L.A.H. Andersson, and C.U.I. Odenbrand, Catal. Today 4, 187 (1989).

    CAS  Article  Google Scholar 

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Rubel, A.M., Stewart, M.L. & Stencel, J.M. Activated carbon for control of nitrogen oxide emissions. Journal of Materials Research 10, 562–567 (1995). https://doi.org/10.1557/JMR.1995.0562

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  • DOI: https://doi.org/10.1557/JMR.1995.0562