Abstract
A stack of five polycarbonate foils, each 1.4 μm thick, was irradiated with 1.3 MeV 4He+ ions to the dose of 1.1 × 1014 cm−2. Ion beam induced polymer degradation, as a function of the particle energy, was studied by UV-VIS and IR spectroscopy of individual foils. In the irradiated foils, a significant reduction of characteristic absorption bands is observed, indicating polymer degradation. Significant increase of the surface polarity, characterized by a polar component of the surface free energy, is also found. Both the degree of the polymer degradation and the surface polarity correlate with the total energy deposited by 4He+ ions in the foils.
Similar content being viewed by others
References
L. Calgano, G. Compagnini, and G. Foti, Nucl. Instrum. Methods Phys. Res., Sect. B 65, 413 (1992).
M. S. Dresselhaus, B. Wasserman, and G. E. Wnek, in Ion Implantation and Ion Beam Processing of Materials, edited by G. K. Hubler, O. W. Holland, C. R. Clayton, and C. W. White (Mater. Res. Soc. Symp. Proc. 27, Elsevier Science Publishing, New York, 1984), p. 413.
V. Švorčík, V. Rybka, R. Endršt, V. Hnatowicz, and J. Kvitek, J. Appl. Polym. Sci. 49, 1939 (1993).
L. Torrisi and G. Foti, J. Mater. Res. 5, 2723 (1990).
V. Švorčík, V. Rybka, O. Jankovskij, V. Hnatowicz, and J. Kvitek, J. Mater. Res. 9, 643 (1994).
R. Ochsner, A. Kluge, S. Zechel-Malonn, L. Gong, and H. Ryssel, Nucl. Instrum. Methods Phys. Res., Sect. B 80/81, 1050 (1993).
V. Švorčík, V. Rybka, P. Seidel, V. Hnatowicz, and J. Kvítek, Mater. Lett. 12, 434 (1992).
J. F. Ziegler, J. P. Biersack, and U. Littmark, in The Stopping and Ranges of Ions in Solids (Pergamon, New York, 1985).
J. P. Biersack and L. G. Haggmark, Nucl. Instrum. Methods Phys. Res., Sect 174, 257 (1980).
T. Feurer, R. Sauerbrez, M. C. Smayling, and B. J. Story, Appl. Phys. A56, 275 (1993).
V. Švorčík, V. Rybka, V. Hnatowicz, and J. Kvítek, Mater. Lett. 19, 329 (1994).
B. Ranby and J. F. Rabek, in Photodegradation, Photooxidation and Photostabilization of Polymers (John Wiley, London, 1975).
V. Švorčík, R. Endršt, V. Rybka, V. Hnatowicz, and F. Černý, J. Electrochem. Soc. 141, 582 (1994).
V. Švorčík, R. Endršt, V. Rybka, V. Hnatowicz, and J. Kvítek, J. Electrochem. Soc. 140, 549 (1993).
M. Lwaki, K. Yabe, A. Fukuda, H. Watanabe, A. Itoh, and M. Takeda, Nucl. Instrum. Methods Phys. Res., Sect. B 80/81, 1080 (1993).
J. Davenas, Nucl. Instrum. Methods Phys. Res., Sect. B 71, 33 (1992).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Švorčik, V., Rybka, V., Miček, I. et al. Study of polycarbonate degradation induced by irradiation with He+ ions. Journal of Materials Research 10, 468–472 (1995). https://doi.org/10.1557/JMR.1995.0468
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1995.0468