Abstract
The measured room temperature magnetic susceptibility of a bulk sample of buckytubes (buckybundle) is −10.75 × 10−6 emu/g for the magnetic field parallel to the buckybundle axis, which is approximately 1.1 times the perpendicular value and 30 times larger than that of C60. The experimental results are discussed in terms of a graphite-like electronic structure model.
Similar content being viewed by others
References
H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl, and R.E. Smalley, Nature 318, 162 (1985).
R.E. Haufler, J. Conceicao, L.P.F. Chibante, Y. Chai, N.E. Byrne, S. Flanagan, M.M. Haley, S.C. O’Brien, C. Pan, Z. Xiao, W. E. Billups, M. A. Ciufolini, R. H. Hauge, J. L. Margrave, L. J. Wilson, R. F. Curl, and R. E. Smalley, J. Phys. Chem. 94, 8634 (1990).
R. Tycko, R. C. Haddon, G. Dabbagh, S.H. Glarum, D.C. Douglass, and A.M. Mujsce, J. Phys. Chem. 95, 518 (1991).
V. Elser and R. C. Haddon, Nature 325, 793 (1987).
R. C. Haddon, L.F. Schneemeyer, J.V. Waszczak, S.H. Glarum, R. Tycko, G. Dabbagh, A. R. Kortan, A. J. Muller, A. M. Mujsce, M.J. Rosseinsky, S. M. Zahurak, A.V. Makhija, F.A. Thiel, K. Raghavachari, E. Cockayne, and V. Elser, Nature 350, 46 (1991).
A. Pasquarello, M. Schluter, and R. C. Haddon, Science 257, 1660 (1992).
P. W. Fowler, P. Lazzeretti, M. Malagoli, and R. Zanasi, Chem. Phys. Lett. 179, 174 (1991).
T. G. Schmalz, Chem. Phys. Lett. 175, 3 (1990).
R. S. Ruoff, D. Beach, J. Cuomo, T. McGuire, R. L. Whetten, and F. Diederich, J. Phys. Chem. 95, 3457 (1991).
V.P. Dravid, X.W. Lin, Y. Wang, X. K. Wang, A. L. Yee, J. B. Ketterson, and R.P.H. Chang, Science 259, 1601 (1993).
X. K. Wang, X. W. Lin, V. P. Dravid, J. B. Ketterson, and R. P. H. Chang, Appl. Phys. Lett. 62, 1881 (1993).
S. Iijima, Nature 354, 56 (1991).
S. Iijima, T. Ichihashi, and Y. Ando, Nature 356, 776 (1992).
J. W. McClure, The Physics of Semimetals and Narrow-Gap Semiconductors, edited by D.L. Carter and R. T. Bate (Pergamon Press, Oxford, 1971).
J. C. Slonczewski and P. R. Weiss, Phys. Rev. 109, 272 (1958); J. W. McClure, Phys. Rev. 119, 606 (1960).
J.W. Mintmire, B.I. Dunlap, and C.T. White, Phys. Rev. Lett. 68, 631 (1992); K. Hahigaya, Phys. Rev. B 45, 44 (1992).
N. Hamada, S. Sawada, and A. Oshiyama, Phys. Rev. Lett. 68, 1579 (1992).
R. Saito, M. Fujita, G. Dresselhaus, and M.S. Dresselhaus, Appl. Phys. Lett. 60, 2204 (1992).
R. M. White, Quantum Theory of Magnetism, in Springer Series in Solid State St7’ercces(Springer-Verlag, Berlin, Heidelberg, New York, 1983).
R. A. Jishi, M. S. Dresselhaus, and G. Dresselhaus, Phys. Rev. B 48, 11385 (1993).
S. Saito and A. Oshiyama, Phys. Rev. Lett. 66, 2637 (1991).
L. Pauling, i. Chem. Phys. 4, 637 (1936).
H. Ajiki and T. Ando, J. Phys. Soc. Jpn. 62, 2470 (1993).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Wang, X.K., Chang, R., Patashinski, A. et al. Magnetic susceptibility of buckytubes. Journal of Materials Research 9, 1578–1582 (1994). https://doi.org/10.1557/JMR.1994.1578
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/JMR.1994.1578