Abstract
The microhardness of monoclinic ZrO2 single-crystals was measured in different environments: air, water, and toluene. An indentation creep process at room temperature was observed for the measurements in moist media pointing for a water-activated plastic relaxation mechanism. This effect is discussed employing the models previously proposed to explain similar behaviors in ZrO2 and other nonmetallic materials. A possible correlation with the conditions for the nucleation in phase transitions is proposed.
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Pereira, A.S., da Jornada, J.A.H. Environment and time dependent hardness in zirconia. Journal of Materials Research 9, 1059–1062 (1994). https://doi.org/10.1557/JMR.1994.1059
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DOI: https://doi.org/10.1557/JMR.1994.1059