Abstract
Hot hardness has been measured in seven isostructural Be12X compounds: Be12Cr, Be12Mn, Be12V, Be12Mo, Be12Ti, Be12Ta, and Be12Nb. All vacuum-hot-pressed (VHP) materials exhibited similar hardness levels (800 to 1000 kg/mm2) at low temperatures (<600 °C), but sharply diverged at higher temperatures. Most compounds showed a sharp decrease in hardness above about one-half their melting temperatures except for Be12Nb and Be12Ti which maintained strength until higher temperatures. Ductile-brittle transition temperatures (DBTT’s) of 600, 625, 690, 700, 700, and 850 °C were determined for Be12Cr, Be12Mn, Be12V, Be12Mo, Be12Ti, and Be12Nb, respectively. Hot-isostatically-pressed (HIP) and VHP Be12Nb heats both showed comparable behavior, indicating that the temperature required for macroscopic plasticity is not dependent on processing conditions. Differences in slip characteristics were observed between beryllides with similar melting temperatures, but differing DBTT’s. Dislocations were activated on multiple slip systems in Bei2V during compressive deformation at 800 °C. Similar behavior was not observed in Be12Nb until test temperatures above 1000 °C. It is proposed that dislocation mobility may be related to the stability between Be12X and Be17X2 phases. Larger refractory metal atoms such as Nb may form faulted layers related to Be17X2 structures and thereby impede deformation at intermediate temperatures. Smaller atoms such as Cr, Mn, V, and Mo do not form a stable Be17X2 phase and thereby allow enhanced dislocation mobility at these temperatures.
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References
A.J. Stonehouse, R.M. Paine, and WW. Beaver, Mechanical Properties of Intermetallk Compounds, edited by J. H. Westbrook (John Wiley & Sons, New York, 1960), p. 297.
A.J. Stonehouse, Mater. Design Eng., Feb. 1962.
E. A. Aitken and J. P. Smith, Properties of Beryllium Intermetallic Compounds, GEMP-105, General Electric Company, 1961.
J. R. Lewis, J. Metals 13, 357 (1961).
J.R. Lewis, J. Metals 13, 829 (1961).
E.G. Kendall. Ceramic Advanced Technology, Chap. 5, 1965, p. 143.
C. H. Henager, Jr., R. E. Jacobson, and S. M. Bruemmer, Mater. Sci. Eng. A152, 416 (1992).
S. M. Bruemmer, B.W. Arey, and C. H. Henager, Jr., in Intermetallic Matrix Composites II, edited by D.B. Miracle, D. L. Anton, and J. A. Graves (Mater. Res. Soc. Symp. Proc. 273, Pittsburgh. PA, 1992).
S. M. Bruemmer, L. A. Chariot, J. L. Brimhall, C. H. Henager, Jr., and J. P. Hirth, Philos. Mag. A 65–5. 1083 (1992).
S. M. Bruemmer, L. A. Chariot, and J. P. Hirth, unpublished research.
Phase Diagrams of Binary Beryllium Alloys, edited by H. Okamoto and L. Tanner (ASM INTERNATIONAL, Metals Park, OH, 1987).
R. E. Jacobson, High-Temperature Strength and Creep Resistance of Be12Nb and Be17Nb2 Intermetallics, M.S. Thesis, Washington State University, 1991.
A. Kelly and G.W. Groves, Crystallography of Crystal Defects (Addison-Wesley, Reading, MA, 1970), p. 178.
J. P. Hirth and J. Lothe, Theory of Dislocations, 2nd ed. (Krieger, Melbourne, FL, 1992), p. 688.
T.G. Nieh and J. Wadsworth, Scripta Metall. et Mater. 24, 1489 (1990).
R. L. Fleischer and R. D. Field, Development Potential of Advanced Intermetallk Materials, WRDC-TR-90-4046 (Wright Research & Development Center, Wright-Patterson Air Force Base, OH, 1990).
R.L. Fleischer and R.J. Zabala, Metall. Trans. A 20A, 1279 (1989).
G. V. Raynor, Proc. 4th Int. Conf. on Beryllium (The Metals Society, 1977), p. 2/1.
J.L. Brimhall, L. A. Chariot, and S. M. Bruemmer, Mater. Sci. Eng. A152, 76 (1992).
D. Banerjee, L. Jacobson, J. Zindell, and T. E. Mitchell, in High Temperature Ordered Intermetallk Alloys IV, edited by L. A. Johnson, D. P. Pope, and J. O. Stiegler (Mater. Res. Soc. Symp. Proc. 213, Pittsburgh, PA, 1991), p. 397.
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Bruemmer, S.M., Arey, B.W., Brimhall, J.L. et al. Hot-hardness comparisons among isostructural Be12X intermetallic compounds. Journal of Materials Research 8, 1550–1557 (1993). https://doi.org/10.1557/JMR.1993.1550
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DOI: https://doi.org/10.1557/JMR.1993.1550